Esterified lignin coating as water vapor and oxygen barrier for fiber-based packaging
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Eva-Lena Hult
,
Klaus Koivu
Abstract
Lignin, esterified with palmitic and lauric acid chloride, has been studied for the application as coating on fiber-based packaging material. The aim was to improve the barrier properties against water vapor and oxygen of paperboard. The esterification was followed by Fourier transform infrared spectroscopy, 31P nuclear magnetic resonance spectroscopy, and gel permeation chromatography measurements. The lignin esters were applied on paperboard and formed a continuous film. The moisture barrier property of the coated paperboards was characterized by the water vapor transmission rate (WVTR). A significant decrease in WVTR was observed, for example, 40 g m-2 (for 24 h) for a paperboard coated with 10.4 g m-2 hardwood kraft lignin palmitate. The contact angle of water on the lignin ester coatings was high and stable. For all paperboard samples coated with lignin esters, a significant decrease in oxygen transmission rate was observed. Accordingly, lignin palmitate and laurate have a high potential as a barrier materials in packaging applications.
The study is part of the two LigniVal projects in the Tekes BioRefine program. Funding to the VTT/Industrial consortium (Tekes, Stora Enso Oyj, UPM-Kymmene Oyj, Metsäliitto Group, Myllykoski Oyj) and VTT/University consortium (Tekes, Metso Power Oy, Oy Metsä-Botnia Ab, Stora Enso Oyj, Roal Oy) is acknowledged.
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©2013 by Walter de Gruyter Berlin Boston
Articles in the same Issue
- Masthead
- Masthead
- Original Articles
- Multi-step degradation method for β-O-4 linkages in lignins: γ-TTSA method. Part 3. Degradation of milled wood lignin (MWL) from Eucalyptus globulus
- Evaluation of selective extraction methods for recovery of polyphenols from pine
- Isocyanate-treated cellulose pulp and its effect on the alkali resistance and performance of fiber cement composites
- Hemicelluloses extraction from giant bamboo (Bambusa balcooa Roxburgh) prior to kraft or soda-AQ pulping and its effect on pulp physical properties
- Effect of hydrothermal treatment intensity on the formation of degradation products from birchwood
- Short-time ultrasonication treatment in enzymatic hydrolysis of biomass
- Esterified lignin coating as water vapor and oxygen barrier for fiber-based packaging
- Storage-induced emissions from different wood species
- Determination of cohesive laws in wood bonded joints under mode I loading using the DCB test
- Production of furans from hemicellulosic saccharides in biphasic reaction systems
- Chemistry and water-repelling properties of phenyl-incorporating wood composites
- Comparison of results obtained by static 3- and 4-point bending and flexural vibration tests on solid wood, MDF, and 5-plywood
- Delamination detection in a 90-year-old glulam block with scanning dry point-contact ultrasound
- Short Notes
- Microbial xylitol production from culm of Sasa kurilensis using the yeast Candida magnoliae
- Determination of lignin content in kraft black liquors by capillary zone electrophoresis (CZE)
- Meetings
- Meetings
Articles in the same Issue
- Masthead
- Masthead
- Original Articles
- Multi-step degradation method for β-O-4 linkages in lignins: γ-TTSA method. Part 3. Degradation of milled wood lignin (MWL) from Eucalyptus globulus
- Evaluation of selective extraction methods for recovery of polyphenols from pine
- Isocyanate-treated cellulose pulp and its effect on the alkali resistance and performance of fiber cement composites
- Hemicelluloses extraction from giant bamboo (Bambusa balcooa Roxburgh) prior to kraft or soda-AQ pulping and its effect on pulp physical properties
- Effect of hydrothermal treatment intensity on the formation of degradation products from birchwood
- Short-time ultrasonication treatment in enzymatic hydrolysis of biomass
- Esterified lignin coating as water vapor and oxygen barrier for fiber-based packaging
- Storage-induced emissions from different wood species
- Determination of cohesive laws in wood bonded joints under mode I loading using the DCB test
- Production of furans from hemicellulosic saccharides in biphasic reaction systems
- Chemistry and water-repelling properties of phenyl-incorporating wood composites
- Comparison of results obtained by static 3- and 4-point bending and flexural vibration tests on solid wood, MDF, and 5-plywood
- Delamination detection in a 90-year-old glulam block with scanning dry point-contact ultrasound
- Short Notes
- Microbial xylitol production from culm of Sasa kurilensis using the yeast Candida magnoliae
- Determination of lignin content in kraft black liquors by capillary zone electrophoresis (CZE)
- Meetings
- Meetings
