Home Physical Sciences By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study
Article
Licensed
Unlicensed Requires Authentication

By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study

  • Naouel Babakhouya , Souad Benammar , Adh’ya-Eddine Hamitouche , Amel Boudjemaa ORCID logo EMAIL logo , Mohamed-Zine Messaoud-Boureghda and Khaldoun Bachari
Published/Copyright: April 29, 2024
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Chemical Product and Process Modeling
From the journal Chemical Product and Process Modeling Volume 19 Issue 2

Abstract

Algerian Eucalyptus Leaves (AEL), a natural biodegradable adsorbent abundantly available, was used for the removal of methylene blue (MB) dye. The AEL properties for the removal of MB were investigated under different conditions by varying the AEL amount, MB concentration, pH of the solution and the reaction temperature. Scanning electron microscopy (SEM) and infrared spectroscopy (FTIR) techniques have been used to characterize AEL biosorbent. Experimental results showed that the adsorption of MB dye at the concentration of 50 mg L−1 reached to 91 % at pH 10 with a stirring speed of 200 rpm and after 180 min of reaction time. The experimental data were analyzed using the linear forms of different kinetic models (pseudo-first order kinetic model, pseudo-second order kinetic model, and intra-particle diffusion models). The results demonstrated that the adsorption kinetics of MB was consistent with the pseudo-second order model with R 2 value of 0.9969. The isotherm models Langmuir, Freundlich, Dubinin, Elovich, Brunaut Emmet Teller and Temkin models were also investigated to describe the adsorption equilibrium. The results show that the AEL adsorption is in accordance with Temkin isotherm. The thermodynamic study revealed that the adsorption is spontaneous and exothermic. Therefore, as a cheap green adsorbent with high MB adsorption performance, AEL is expected to become one of the best candidate materials for future industrial wastewater treatment.

Keywords: Eucalyptus leaves; valorisation; adsorption; dye removal; isotherm models; thermodynamic
Corresponding author: Amel Boudjemaa, Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques, BP 384, Siège ex-Pasna Zone Industrielle, Bou-Ismail CP, Tipaza 42004, Algeria, E-mail:

Funding source: General Directorate for Scientific Research and Technological Development DGRSDT (Algeria)

  1. Research ethics: Not applicable.

  2. Author contributions: Naouel Babakhouya: Conceptualization, Methodology, Writing – original draft. Souad Benammar: Visualization, Investigation, Methodology, – review & editing. Adh’ya-Eddine Hamitouche: Visualization, Investigation, Methodology, – review & editing. Kkaldoun Bachari: Review & Editing. Messaoud-Boureghda Mohamed-Zine: Review & Editing. Amel Boudjemaa: Conceptualization, Writing – review & editing. All the authors commented on previous versions of the manuscript, read and improved the final manuscript.

  3. Competing interests: The authors declare no competing interests.

  4. Research funding: This work is supported by the General Directorate for Scientific Research and Technological Development DGRSDT (Algeria).

  5. Data availability: All data generated or analyzed during this study are included in the published article.

References

1. Lellis, B, Fávaro-Polonio, CZ, Pamphile, JA, Polonio, JC. Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnol Res Innovat 2019;3:275–90. https://doi.org/10.1016/j.biori.2019.09.001.Search in Google Scholar

2. Kadrivelu, K, Kavipriya, M, Karthika, C, Radhika, M, Vennilamani, N, Pattabhi, S. Adsorption study of Methylene Blue on biomaterial using cactus. Bioresour Technol 2003;87:129–32. https://doi.org/10.1016/s0960-8524(02)00201-8.Search in Google Scholar PubMed

3. Jain, AK, Gupta, VK, Bhatnagar, A, Suhas. Utilization of industrial waste products as adsorbents for the removal of dyes. J Hazard Mater 2003;101:31–42. https://doi.org/10.1016/s0304-3894(03)00146-8.Search in Google Scholar PubMed

4. Waliullah, RM, Rehan, AI, Awual, E, Rasee, AI, Sheikh, MC, Salman, MS, et al.. Optimization of toxic dye removal from contaminated water using chitosan-grafted novel nanocomposite adsorbent. J Mol Liq 2023;388:122763. https://doi.org/10.1016/j.molliq.2023.122763.Search in Google Scholar

5. Dutta, BK. Principles of mass transfer and separation processes, 1st ed. New Delhi, India: Prentice Hall of India; 2007:609–77 pp. Chapter 12.Search in Google Scholar

6. Galamboš, M, Suchánek, P, Rosskopfová, O. Sorption of anthropogenic radionuclides on natural and synthetic inorganic sorbents. J Radioanal Nucl Chem 2012;293:613–33. https://doi.org/10.1007/s10967-012-1717-y.Search in Google Scholar

7. Gopinath, KP, Vo, DV, Prakash, DG, Joseph, A, Viswanathan, S, Arun, J. Environmental applications of carbon-based materials. Environ Chem Lett 2021;19:557–82. https://doi.org/10.1007/s10311-020-01084-9.Search in Google Scholar

8. Samsami, SH, Mohamadizaniani, M, Sarrafzadeh, M-H, Rene, ER, Firoozbahr, M. Recent advances in the treatment of dye-containing wastewater from textile industries: overview and perspectives. Process Saf Environ Protect J 2020;143:138–63. https://doi.org/10.1016/j.psep.2020.05.034.Search in Google Scholar

9. Choy, KK, McKay, G, Porter, JF. Sorption of acid dyes from effluents using activated carbon. Resour Conserv Recycl 1999;27:57–71. https://doi.org/10.1016/s0921-3449(98)00085-8.Search in Google Scholar

10. Faria, PCC, Orfao, JJM, Pereira, MFR. Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Res 2004;38:2043–52. https://doi.org/10.1016/j.watres.2004.01.034.Search in Google Scholar PubMed

11. Gomez, V, Larrechi, MS, Callao, MP. Kinetic and adsorption study of acid dye removal using activated carbon. Chemosphere 2007;69:1151–8. https://doi.org/10.1016/j.chemosphere.2007.03.076.Search in Google Scholar PubMed

12. Kennedy, LJ, Ijaya, JJ, Sekaran, G, Kayalvizhi, K. Equilibrium, kinetic and thermodynamic studies on the adsorption of m-cresol onto micro- and mesoporous carbon. J Hazard Mater 2007;149:134–43. https://doi.org/10.1016/j.jhazmat.2007.03.061.Search in Google Scholar PubMed

13. Kannan, N, Sundaram, MM. Adsorption of Congo red on various activated carbons. A comparative study. Water, Air, Soil Pollut. 2002;138:289–305. https://doi.org/10.1023/a:1015551413378.10.1023/A:1015551413378Search in Google Scholar

14. Salman, MS, Sheikh, MC, Hasan, MM, Hasan, MN, Kubra, KT, Rehan, AI, et al.. Chitosan-coated cotton fiber composite for efficient toxic dye encapsulation from aqueous media. Appl Surf Sci 2023;622:157008. https://doi.org/10.1016/j.apsusc.2023.157008.Search in Google Scholar

15. Kacha, S, Derriche, Z. Equilibrium and kinetics of color removal from dye solutions with bentonite and polyaluminum hydroxide. Water Environ Res 2003;75:15–20. https://doi.org/10.2175/106143003x140782.Search in Google Scholar PubMed

16. Shahrokhi-Shahraki, R, Benally, C, El-Din, MG, Park, J. High efficiency removal of heavy metals using tire-derived activated. carbon vs commercial activated carbon: insights into the adsorption mechanisms. Chemosphere 2021;264:128455. https://doi.org/10.1016/j.chemosphere.2020.128455.Search in Google Scholar PubMed

17. Ghosh, S, Malloum, A, Bornman, C, Othmani, A, Osagie, C, Esfahani, ZK, et al.. Novel green adsorbents for removal of aniline from industrial effluents: a review. J Mol Liq 2022;345:118167. https://doi.org/10.1016/j.molliq.2021.118167.Search in Google Scholar

18. Inyinbor, AA, Adekola, FA, Olatunji, GA. Adsorption of rhodamine B dye from aqueous solution on Irvingia gabonensis biomass: kinetics and thermodynamics studies. S Afr J Chem 2015;68:115–25. https://doi.org/10.17159/0379-4350/2015/v68a17.Search in Google Scholar

19. Hashem, A, El-Khiraigy, K. Bioadsorption of Pb (II) onto Anethum graveolens from contaminated wastewater: equilibrium and kinetic studies. J Environ Protect 2013;4:108–19. https://doi.org/10.4236/jep.2013.41012.Search in Google Scholar

20. Benammar, S, Haffas, M, Hamitouche, A, Boudjemaa, A, Bachari, K. Relevance of Anethum graveolens to remove rhodamine B in aqueous solution: characterization, kinetic and isotherm study. React Kinet Mech Catal 2023;136:465–90. https://doi.org/10.1007/s11144-022-02324-5.Search in Google Scholar

21. Hamitouche, A, Benammar, S, Haffas, M, Boudjemaa, A, Bachari, K. Biosorption of methyl violet from aqueous solution using Algerian biomass. Desalination Water Treat 2016;57:15862–72. https://doi.org/10.1080/19443994.2015.1077476.Search in Google Scholar

22. Dahri, MK, Kooh, MRR, Lim, LB. Application of Casuarina equisetifolia needle for the removal of methylene blue and malachite green dyes from aqueous solution. Alex Eng J 2015;54:1253–63. https://doi.org/10.1016/j.aej.2015.07.005.Search in Google Scholar

23. Han, R, Zou, W, Yu, W, Cheng, S, Wang, Y, Shi, J. Biosorption of methylene blue from aqueous solution by fallen phoenix tree’s leaves. J Hazard Mater 2007;141:156–62. https://doi.org/10.1016/j.jhazmat.2006.06.107.Search in Google Scholar PubMed

24. Deniz, F, Saygideger, SD. Removal of Basic Red 46 dye from aqueous solution by pine tree leaves. Bioresour Technol 2010;101:5137–43. https://doi.org/10.1016/j.biortech.2010.02.004.Search in Google Scholar PubMed

25. Bestani, B, Benderdouche, N, Benstaali, B, Belhakem, M, Addou, A. Methylene blue and iodine adsorption onto an activated desert plant. Bioresour Technol 2008;99:8441–4. https://doi.org/10.1016/j.biortech.2008.02.053.Search in Google Scholar PubMed

26. Ponnusami, V, Gunasekar, V, Srivastava, SN. Kinetics of methylene blue removal from aqueous solution using gulmohar (Delonix regia) plant leaf powder: multivariate regression analysis. J Hazard Mater 2009;169:119–27. https://doi.org/10.1016/j.jhazmat.2009.03.066.Search in Google Scholar PubMed

27. Behloul, S, Hamitouche, A, Haffas, M, Boudjemaa, A, Benammar, S, Sehailia, M, et al.. Removal of methyl violet dye by a low-cost waste (Ajuga pseudo-iva): kinetic and equilibrium isotherm study. Can J Chem Eng 2018;96:2282–91. https://doi.org/10.1002/cjce.23313.Search in Google Scholar

28. Mishra, S, Cheng, L, Maiti, A. The utilization of agro-biomass/byproducts for effective bio-removal of dyes from dyeing wastewater: a comprehensive review. J Environ Chem Eng 2021;9:104901. https://doi.org/10.1016/j.jece.2020.104901.Search in Google Scholar

29. Kubra, K, T, Salman, M, S, Hasan, MN. Enhanced toxic dye removal from wastewater using biodegradable polymeric natural adsorbent. J Mol Liq 2021;328:115468. https://doi.org/10.1016/j.molliq.2021.115468.Search in Google Scholar

30. Ogunlalu, O, Oyekunle, IP, Iwuozor, KO, Aderibigbe, AD, Emenike, EC. Trends in the mitigation of heavy metal ions from aqueous solutions using unmodified and chemically-modified agricultural waste adsorbents. Curr Res Green Sustainable Chem 2021;4:100188. https://doi.org/10.1016/j.crgsc.2021.100188.Search in Google Scholar

31. Aziam, R, Chiban, M, Eddaoudi, H, Soudani, A, Zerbet, M, Sinan, F. Kinetic modeling, equilibrium isotherm and thermodynamic studies on a batch adsorption of anionic dye onto eco-friendly dried Carpobrotus edulis plant. Eur Phys J Spec Top 2017;226:977–92. https://doi.org/10.1140/epjst/e2016-60256-x.Search in Google Scholar

32. Bagotia, N, Sharma, AK, Kumar, S. A review on modified sugarcane bagasse biosorbent for removal of dyes. Chemosphere 2021;268:129309. https://doi.org/10.1016/j.chemosphere.2020.129309.Search in Google Scholar PubMed

33. Patil, S, Renukdas, S, Patel, N. Removal of methylene blue, a basic dye from aqueous solutions by adsorption using teak tree (Tectona grandis) bark powder. Int J Environ Sci 2011;1:711–26.Search in Google Scholar

34. Esan, OS, Abiola, ON, Owoyomi, O, Christopher, OA, Osundiya, MO. Adsorption of brilliant green onto Luffa cylindrical sponge: equilibrium, kinetics, and thermodynamic studies. ISRN Phys Chem 2014;2014:1–12. https://doi.org/10.1155/2014/743532.Search in Google Scholar

35. Azam, M, Wabaidur, SM, Khan, MR, Al-Resayes, SI, Islam, MS. Heavy metal ions removal from aqueous solutions by treated ajwa date pits: kinetic, isotherm, and thermodynamic approach. Polymers 2022;14:914. https://doi.org/10.3390/polym14050914.Search in Google Scholar PubMed PubMed Central

36. Alqadami, AA, Wabaidur, M, Jeon, BH, Khan, MA. Co-hydrothermal valorization of food waste: process optimization, characterization, and water decolorization application. Biomass Convers Biorefin 2023;1–12. https://doi.org/10.1007/s13399-022-03711-7.Search in Google Scholar

37. Botrel, BMC, Magriotis, ZM, Saczk, AA, Coelho, SM, De Sales, PF. Removal of methylene blue by orange and uvaia seeds. J Adv Agric 2015;3:237–53.10.24297/jaa.v3i3.6568Search in Google Scholar

38. Bhattacharyya, KG, Sharma, A. Adsorption of Pb (II) from aqueous solution by Azadirachta indica (Neem) leaf powder. J Hazard Mater 2004;113:97–109. https://doi.org/10.1016/j.jhazmat.2004.05.034.Search in Google Scholar PubMed

39. Munagapati, VS, Wen, JC, Pan, CL, Gutha, Y, Wen, JH. Enhanced adsorption performance of Reactive Red 120 azo dye from aqueous solution using quaternary amine modified orange peel powder. J Mol Liq 2019;285:375–85. https://doi.org/10.1016/j.molliq.2019.04.081.Search in Google Scholar

40. Kenawy, ER, Ghfar, AA, Wabaidur, SM, Khan, MA, Siddiqui, MR, Alothman, ZA, et al.. Cetyltrimethylammonium bromide intercalated and branched polyhydroxystyrene functionalized montmorillonite clay to sequester cationic dyes. J Environ Manag 2018;219:285–29. https://doi.org/10.1016/j.jenvman.2018.04.121.Search in Google Scholar PubMed

41. Lagergren, S. Zurtheorie der sogenannten adsorption gelosterstoffe, Kungliga Svenska Veten-skapsakademiens. Handlingar 1898;24:1–39.Search in Google Scholar

42. Ho, YS, McKay, G. Pseudo-second order model for sorption processes. Process Biochem 1999;34:451–65. https://doi.org/10.1016/s0032-9592(98)00112-5.Search in Google Scholar

43. Doğan, M, Abak, H, Alkan, M. Adsorption of methylene blue onto hazelnut shell: kinetics, mechanism and activation parameters. J Hazard Mater 2009;164:172–81. https://doi.org/10.1016/j.jhazmat.2008.07.155.Search in Google Scholar PubMed

44. Srivastava, VC, Swamy, MM, Mall, ID, Prasad, B, Mishra, IM. Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics. Colloids Surf, A 2006;272:89–104. https://doi.org/10.1016/j.colsurfa.2005.07.016.Search in Google Scholar

45. Sidiras, D, Batzias, F, Schroeder, E, Ranjan, R, Tsapatsis, M. Dye adsorption on autohydrolyzed pine sawdust in batch and fixed-bed systems. Chem Eng J 2011;171:883–96. https://doi.org/10.1016/j.cej.2011.04.029.Search in Google Scholar

46. Mohan, S, Karthikeyan, J. Removal of lignin and tannin color from aqueous solution by adsorption on to activated carbon solution by adsorption on to activated charcoal. Environ Pollut 1997;97:183–7. https://doi.org/10.1016/s0269-7491(97)00025-0.Search in Google Scholar PubMed

47. Tsai, WT, Chang, YM, Lai, CW, Lo, CC. Adsorption of basic dyes in aqueous solution by clay adsorbent from regenerated bleaching earth Applied. Clay Sci 2005;29:149–54. https://doi.org/10.1016/j.clay.2004.10.004.Search in Google Scholar

48. Piccin, JS, Dotto, GL, Pinto, LA. Adsorption isotherms and thermochemical data of FD&C red N° 40 binding by. Braz J Chem Eng 2011;28:295–304. https://doi.org/10.1590/s0104-66322011000200014.Search in Google Scholar

49. Dada, AO, Olalekan, AP, Olatunya, AM. Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR J Appl Chem 2012;3:38–45. https://doi.org/10.9790/5736-0313845.Search in Google Scholar

50. Sawalha, MF, Peralta-Videa, JR, Romero-González, J, Duarte-Gardea, M, Gardea-Torresdey, JL. Thermodynamic and isotherm studies of the biosorption of Cu (II), Pb (II), and Zn (II) by leaves of saltbush (Atriplex canescens). J Chem Therm 2007;39:488–92. https://doi.org/10.1016/j.jct.2006.07.020.Search in Google Scholar

51. Hamdaoui, O, Naffrechoux, E. Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. J Hazard Mater 2007;147:381–94. https://doi.org/10.1016/j.jhazmat.2007.01.021.Search in Google Scholar PubMed

52. Foo, KY, Hameed, BH. Insights into the modeling of adsorption isotherm systems. Chem Eng J 2010;156:2–10. https://doi.org/10.1016/j.cej.2009.09.013.Search in Google Scholar

53. Farouq, R, Yousef, NS. Equilibrium and kinetics studies of adsorption of copper (II) ions on natural biosorbent. Int J Chem Eng Appl 2015;6:319. https://doi.org/10.7763/ijcea.2015.v6.503.Search in Google Scholar

54. Myszka, DG. Kinetic, equilibrium, and thermodynamic analysis of macromolecular interactions with BIACORE. Methods Enzymol 2000;323:325–40. https://doi.org/10.1016/s0076-6879(00)23372-7.Search in Google Scholar PubMed

55. El Haddad, M, Slimani, R, Mamouni, R, Elantri, S, Lazar, S. Removal of two textile dyes from aqueous solutions onto calcined bones. J Assoc Arab Univ Basic Appl Sci 2013;14:51–9. https://doi.org/10.1016/j.jaubas.2013.03.002.Search in Google Scholar

56. Chakir, A, Bessiere, J, El Kacemi, K, Marouf, B. A comparative study of the removal of trivalent chromium from aqueous solutions by bentonite and expanded perlite. J Hazard Mater 2002;95:29–46. https://doi.org/10.1016/s0304-3894(01)00382-x.Search in Google Scholar PubMed

57. Önal, Y, Akmil-Basar, C, Sarici, ÖÇ. Elucidation of the naproxen sodium adsorption onto activated carbon prepared from waste apricot: kinetic, equilibrium and thermodynamic characterization. J Hazard Mater 2007;148:727–34. https://doi.org/10.1016/j.jhazmat.2007.03.037.Search in Google Scholar PubMed

58. Fasfous, II, Radwan, ES, Dawoud, JN. Kinetics, equilibrium and thermody-namics of the sorption of tetrabromobisphenol A on multiwalled carbon nanotubes. Appl Surf Sci 2010;256:7246–52. https://doi.org/10.1016/j.apsusc.2010.05.059.Search in Google Scholar

59. Maire, E, Fazekas, A, Salvo, L, Dendievel, R, Youssef, S, Cloetens, P, et al.. X-ray tomography applied to the characterization of cellular materials. Related finite element modeling problems. Compos Sci Technol 2003;635:2431–43.10.1016/S0266-3538(03)00276-8Search in Google Scholar

60. Kumar, A, Sreenivasa, CG, Dharmendra, BV, Manohara, V. Mechanical properties evaluation of eucalyptus fiber reinforced epoxy composites. J Mater Environ Sci 2015;6:1400–10.Search in Google Scholar

61. Khan, MA, Wabaidur, SM, Siddiqui, MR, Alqadami, AA, Khan, AH. Silico-manganese fumes waste encapsulated cryogenic alginate beads for aqueous environment de-colorization. J Clean Prod 2020;244:118867. https://doi.org/10.1016/j.jclepro.2019.118867.Search in Google Scholar

62. De Oliveira Brito, SM, Andrade, MC, Soaresa, LF, De Azevedo, RP. Brazil nut shells as a new biosorbent to remove methylene blue and indigo carmine from aqueous solutions. J Hazard Mater 2010;174:84–92. https://doi.org/10.1016/j.jhazmat.2009.09.020.Search in Google Scholar PubMed

63. Ertaş, M, Acemioğlu, B, Alma, MH, Usta, M. Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust. J Hazard Mater 2010;183:421–7. https://doi.org/10.1016/j.jhazmat.2010.07.041.Search in Google Scholar PubMed

64. Djilali, Y, Elandaloussi, EH, Aziz, A, De Menorval, LC. Alkaline treatment of timber sawdust: a straightforward route toward effective low-cost adsorbent for the enhanced removal of basic dyes from aqueous solutions. J Saudi Chem Soc 2016;20:S241–9. https://doi.org/10.1016/j.jscs.2012.10.013.Search in Google Scholar

65. Kavitha, D, Namasivayam, C. Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresour Technol 2007;98:14–21. https://doi.org/10.1016/j.biortech.2005.12.008.Search in Google Scholar PubMed

66. Ghaedi, M, Heidarpour, S, Kokhdan, SN, Sahraie, R, Daneshfar, A, Brazesh, B. Comparison of silver and palladium nanoparticles loaded on activated carbon for efficient removal of Methylene blue: kinetic and isotherm study of removal process. Powder Technol 2012;228:18–25. https://doi.org/10.1016/j.powtec.2012.04.030.Search in Google Scholar

67. Senthil Kumar, P, Sivaranjanee, R, Vinothini, U, Raghavi, M, Rajasekar, K, Ramakrishnan, K. Adsorption of dye onto raw and surface modified tamarind seeds: isotherms, process design, kinetics and mechanism. Desalination Water Treat 2014;52:2620–33. https://doi.org/10.1080/19443994.2013.792016.Search in Google Scholar

68. Fu, J, Chen, Z, Wang, M, Liu, S, Zhang, J, Han, R, et al.. Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 2015;259:53–61. https://doi.org/10.1016/j.cej.2014.07.101.Search in Google Scholar

69. Zhang, LL, Zaoui, A, Sekkal, W. Adsorption efficiency of highly methylene blue dye concentrations with multilayer chitosan-modified clays for a precise nanofiltration performance of polluted water. J Water Process Eng 2024;57:104651. https://doi.org/10.1016/j.jwpe.2023.104651.Search in Google Scholar

70. Nandi, BK, Goswami, A, Purkait, MK. Removal of cationic dyes from aqueous solutions by kaolin: kinetic and equilibrium studies. Appl Clay Sci 2009;42:583. https://doi.org/10.1016/j.clay.2008.03.015.Search in Google Scholar

71. Gorden, M, Murad, BJ, Altemimi, A. External mass transfer during the adsorption of various pollutants onto activated carbon. Water Res 1986;20:435–42. https://doi.org/10.1016/0043-1354(86)90190-9.Search in Google Scholar

72. Gorden, M, EL Geundi, M, Nassar, MM. Pore-diffusion during the adsorption of dyes onto bagasse pith. Process Saf Environ Protect 1996;1:277–88.10.1205/095758296528635Search in Google Scholar

73. Hamitouche, A, Haffas, M, Boudjemaa, A, Benammar, S, Sehailia, M, Bachari, K. Efficient biosorption of methylene blue, malachite green and methyl violet organic pollutants on biomass derived from Anethum graveolens: an eco-benign approach for wastewater treatment. Desalination Water Treat 2017;5:225–36. https://doi.org/10.5004/dwt.2017.20615.Search in Google Scholar

74. Gupta, H, Gogate, PR. Intensified removal of copper from waste water using activated water-melon based adsorbent in the presence of ultrasound. Ultrason Sonochem 2016;30:113–22. https://doi.org/10.1016/j.ultsonch.2015.11.016.Search in Google Scholar PubMed

75. Sinha, I, Das, R, Student, B. Removal of hexa-valent chromium from industrial wastes using sugar cane bagasse as bio-adsorbent: thermodynamic and kinetic studies. Int J Eng Sci 2016;6:7762.Search in Google Scholar

76. Abel, UA, Habor, GR, Oseribho, OI. Adsorption studies of oil spill clean-up using coconut coir activated carbon (CCAC). Am J Chem Eng 2020;8:36–47. https://doi.org/10.11648/j.ajche.20200802.11.Search in Google Scholar

77. Mukoko, T, Mupa, M, Guyo, U, Dziike, F. Preparation of rice hull activated carbon for the removal of selected pharmaceutical waste compounds in hospital effluent. J Environ Anal Toxicol 2015;S7:008. https://doi.org/10.4172/2161-0525.s7-008.Search in Google Scholar

78. Cabrita, I, Ruiz, B, Mestre, AS, Fonseca, MI, Carvalho, AP, Ania, CO. Removal of an analgesic using activated carbons prepared from urban and industrial residues. Chem Eng J 2010;163:249–55. https://doi.org/10.1016/j.cej.2010.07.058.Search in Google Scholar

79. Labied, R, Benturki, O, Hamitouche, A, Donnot, A. Adsorption of hexavalent chromium by activated carbon obtained from a waste lignocellulosic material (Ziziphus jujuba cores): kinetic, equilibrium, and thermodynamic study. Adsorpt Sci Technol 2018;36:1–34.10.1177/0263617417750739Search in Google Scholar

80. Dusart, O, Bouabane, H, Mazet, M. Adsorption sur charbon actif d’acides aminés dans l’eau : détermination de paramètres d’équilibre par différentes équations. J Chim Phys 1991;88:259–70. https://doi.org/10.1051/jcp/1991880259.Search in Google Scholar

81. Ferreira, RC, Couto, OMJr, Carvalho, KQ, Arroyo, PA, Barros, M. Effect of solution pH on the removal of paracetamol by activated of dende coconut mesocarp. Chem Biochem Eng Q 2015;29:47–53. https://doi.org/10.15255/cabeq.2014.2115.Search in Google Scholar

82. Singh, D. Studies of the adsorption thermodynamics of oxamymyl on fly ash. Adsorpt Sci Technol 2000;18:742–8.10.1260/0263617001493783Search in Google Scholar

83. Kara, A, Demirbel, E, Tekin, N, Osman, B, Besirli, N. Magnetic vinylphenyl boronic acid microparticles for Cr (VI) adsorption: kinetic, isotherm and thermodynamic studies. J Hazard Mater 2015;286:612–23. https://doi.org/10.1016/j.jhazmat.2014.12.011.Search in Google Scholar PubMed

84. Al-Khateeb, LA, Almotiry, S, Salam, MA. Adsorption of pharmaceutical pollutants onto graphene nanoplatelets. Chem Eng J 2014;248:191–9. https://doi.org/10.1016/j.cej.2014.03.023.Search in Google Scholar

85. Silva, EK, Borges, SV, da Costa, JM, Queiroz, F. Thermodynamic properties, kinetics and adsorption mechanisms of Swiss cheese bioaroma powder. Powder Technol 2015;272:181–8. https://doi.org/10.1016/j.powtec.2014.12.002.Search in Google Scholar

86. Purkait, MK, Maiti, A, Das Gupta, S, De, S. Removal of Congo red using activated carbon and its regeneration. J Hazard Mater 2007;145:287–95. https://doi.org/10.1016/j.jhazmat.2006.11.021.Search in Google Scholar PubMed

87. Dey, S, Bhagat, P, Mohanta, J, Dey, B. Methylene blue removal using eucalyptus leaves: a low-cost protocol towards environmental sustainability. Eur J Adv Chem Res 2022;3:1–11. https://doi.org/10.24018/ejchem.2022.3.1.82.Search in Google Scholar
Received: 2023-03-14
Accepted: 2024-03-01
Published Online: 2024-04-29

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. CPPM special issue in honor of Professor Faïçal Larachi
  4. Research Articles
  5. Predicting buoyant jet characteristics: a machine learning approach
  6. Insights into the bubble formation dynamics in converging shape microchannels using CLSVOF method
  7. Comparison of different CFD approaches for the simulation of developing free surface two-phase flow in straight and bent pipes
  8. A new approach to model the fluid dynamics in sandwich packings
  9. Effect of novel mixed impeller on local bubble size and flow regime transition in pilot scale gas-liquid stirred tank reactor
  10. Quantitative structure-electrochemistry relationship modeling of a series of anticancer agents using MLR and ANN approaches
  11. Extractive desulfurization of crude petroleum oil and liquid fuels using trihexyl tetradecyl phosphonium bis(2-ethylhexyl) phosphate ionic liquid
  12. CFD-aided contraction-expansion static mixer design for oil-in-water emulsification
  13. Liquid-liquid flow pattern and mass transfer in a rotating millimeter channel reactor
  14. By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study
https://doi.org/10.1515/cppm-2023-0023
Keywords for this article
Eucalyptus leaves; valorisation; adsorption; dye removal; isotherm models; thermodynamic

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. CPPM special issue in honor of Professor Faïçal Larachi
  4. Research Articles
  5. Predicting buoyant jet characteristics: a machine learning approach
  6. Insights into the bubble formation dynamics in converging shape microchannels using CLSVOF method
  7. Comparison of different CFD approaches for the simulation of developing free surface two-phase flow in straight and bent pipes
  8. A new approach to model the fluid dynamics in sandwich packings
  9. Effect of novel mixed impeller on local bubble size and flow regime transition in pilot scale gas-liquid stirred tank reactor
  10. Quantitative structure-electrochemistry relationship modeling of a series of anticancer agents using MLR and ANN approaches
  11. Extractive desulfurization of crude petroleum oil and liquid fuels using trihexyl tetradecyl phosphonium bis(2-ethylhexyl) phosphate ionic liquid
  12. CFD-aided contraction-expansion static mixer design for oil-in-water emulsification
  13. Liquid-liquid flow pattern and mass transfer in a rotating millimeter channel reactor
  14. By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 31.12.2025 from https://www.degruyterbrill.com/document/doi/10.1515/cppm-2023-0023/html?lang=en
Scroll to top button