Application of Sinusoidal Function and a 25–1 Fractional Factorial Array in the Kinetics and Optimization Study of Gmelina Seed Oil Modified Alkyd Resin Synthesis
-
Chigozie F. Uzoh
and
Okechukwu D. Onukwuli
Abstract
An overnight dry hard alkyd resin has been designed from non-drying gmelina seed oil (GSO). The study was enhanced through pseudo combined array (PCA) and a dynamic data processor (DDP). The GSO modified alkyd resin was synthesized through a two stage alcoholysis-esterification method using glycerol, phthalic and maleic anhydride. The DDP was designed for the conversion of the GSO acid functional group in the alkyd reactor on the basis of the third order kinetic model and sinusoidal function. Models describing the molecular properties (conversion, viscosity and molecular weight average) in terms of the process parameters were derived from multiple regression by integrating a 25–1 fractional factorial array (FFA) in a central composite design (CCD) implemented with design expert. The fatty acid profile of the raw GSO was determined using GC-MS while structural elucidation of the raw GSO, chemically modified GSO and GSO based alkyd resins were determined using FTIR spectrometry. The synthesized alkyds show very good physic-chemico-mechanical properties. Specifically, the drying schedule shows that the GSO alkyd resin achieved a dry hard time of 8.3 h in presence of nano-ZnO pigment. The designed kinetic model was able to track the trajectory of the reaction motion such that the molecular properties falls within specification. The Optimum responses of 89.66 % conversion, viscosity of 293 cP and molecular weight average of 5,481 predicted, fall within the range suggested from the kinetic model. Correspondent experiments conducted with the predicted optimum conditions were in reasonable agreement with the predicted values.
References
1. Sankh K, Ashalatha M. Preliminary phytochemical study of Gambhari (Gmelina arborea) fruit. Int Ayurvedic Med J 2015;3(2):275–9.Search in Google Scholar
2. Oguwike FN, Offor CC. The effects of aqueous leaf extract of Gmelina Arborea on the haematological and biochemical profile of Albino Rats. IOSR J Dent Med Sci 2013;9(1):54–7.10.9790/0853-0915457Search in Google Scholar
3. Ingole SN. Study of floral epidermal features in Gmelina arborea Roxb. Int Res J Sci Eng 2013;1(3):85–9.Search in Google Scholar
4. Sanjay B. Non-conventional seed oils as potential feedstocks for future biodiesel industries: a brief review. Res J Chem Sci 2013;3(5):99–103.Search in Google Scholar
5. Sanjay B, Barua P, Deka DC. Gmelina arborea and Tabernaemontana divaricata seed oils as non-edible feedstocks for biodiesel production. Int J Chem Tech Res CODEN (USA) 2014;6(2):1440–5.Search in Google Scholar
6. Sanjay B, Deka DC, Deka DC. Composition of biodiesel from Gmelina arborea seed oil. Adv Appl Sci Res 2012;3(5):2745–53.Search in Google Scholar
7. Oseni MI, Ette AO, Nnuka EE. Rheology of Gmelina and rubber seeds oil lubricants. J Novel Appl Sci 2013;2(4):1143–9.Search in Google Scholar
8. Uzoh CF, Nwabanne OD. Characterization, kinetics and statistical screening analysis of gmelina seed oil extraction process. Mater Renew Sustain Energy 2014;3(38):1–12.10.1007/s40243-014-0038-1Search in Google Scholar
9. Boruah M, Gogoi P, Adhikari B, Dolui SK. Preparation of jatropha curcas oil based alkyd resin suitable for surface coating. Prog Org Coat 2012;74:596–602.10.1016/j.porgcoat.2012.02.007Search in Google Scholar
10. http://www.dainet.de/fnr/ctvo/paint/2_workshop/ull.doc (23.04.2014)Search in Google Scholar
11. Issam AM, Cheun CY. A study of the effect of palm oil on the properties of a new alkyd resin. Malaysian Polym J 2009;4:42–9.Search in Google Scholar
12. Uzoh CF, Onukwuli OD, Odera RS, Ofochebe S. Optimization of polyesterification process for production of palm oil modified alkyd resin using response surface methodology. J Environ Chem Eng 2013;1:777–85.10.1016/j.jece.2013.07.021Search in Google Scholar
13. Uzoh CF, Onukwuli OD, Nwabanne JT, Odera SR. Studies on copra oil self-cured ester as a sustainable material for surface coatings. J Chinese Adv Mater Soc 2015. DOI: 10.1080/22243682.2015.1040835.Search in Google Scholar
14. Islam MR, Beg MD, Jamari SS. Alkyd based resin from non-drying oil. Procedia Eng 2013;90(2014):78–88.10.1016/j.proeng.2014.11.818Search in Google Scholar
15. Islam MR, Beg MD, Jamari SS. The effects of increasing unsaturation in palm oil and incorporation of carbon nanotubes on resinous properties. Int J Chem Nucl Mater Metall Eng 2015;9(3):499–504.Search in Google Scholar
16. Hamza KT. Design for vehicle structural crashworthiness via crash mode matching [Doctoral Research]. Department of Mechanical Engineering, University of Michigan; 2008.10.1115/DETC2009-87072Search in Google Scholar
17. Montgomery DC. The statistician, Part 2, vol. 48, 1999:159–77.10.1111/1467-9884.00179Search in Google Scholar
18. Odetoye TE, Ogunniyi DS, Olatunji GA. Improving Jatropha curcas Linnaeus oil alkyd drying properties. Prog Org Coat 2012;73:374–81.10.1016/j.porgcoat.2011.11.016Search in Google Scholar
19. Fujita H, Kishimoto A. Interpretation of viscosity data for concentrated polymer solutions. J Chem Phys 1961;34:393–8.10.1063/1.1700962Search in Google Scholar
20. Montgomery DC. Design and analysis of experiments, 5th ed. New York: Wiley, 2001.Search in Google Scholar
21. Ajemba RO, Onukwuli OD. Response surface optimization of palm oil bleaching using hydrochloric acid activated Ukpor clay. European J Sci Res 2012;82(3):325–35.Search in Google Scholar
22. Silva GF, Camargo FL, Ferreira ALO. Application of response surface methodology for optimization of biodiesel production by transesterification of soybean oil with ethanol. Fuel Process Technol 2010;92(3):407–13.10.1016/j.fuproc.2010.10.002Search in Google Scholar
23. Patton TC. Alkyd resin technology. NY: John Wiley & Sons, 1962.Search in Google Scholar
24. López T, Hernández H, Alvarez J. Robust nonlinear estimation of alkyd reactors with discrete-delayed measurements. ADCHEM2000 Congress, Pisa, Italy, 2000.10.1016/S1474-6670(17)38567-1Search in Google Scholar
25. Kirk-Othmer. Encyclopedia of chemical technology, 2nd ed, vol. 1. New York: Interscience Publishers, 1966:851–82.Search in Google Scholar
26. Marshall GL. European Polym J 1986;22:217–30.10.1016/0014-3057(86)90092-3Search in Google Scholar
27. Okon DE, Ibanga OI. Comparative study on the kinetics of the preparation of melon seed and cottonseed oils based biopolymers. American J Polym Sci 2014;4(1):7–15. DOI: 10.5923/j.ajps.20140401.02.Search in Google Scholar
28. Silva GF, Camargo FL, Ferreira AL. Application of response surface methodology for optimization of biodiesel production by transesterification of soybean oil with ethanol. Fuel Process Technol 2011;92:407–13.10.1016/j.fuproc.2010.10.002Search in Google Scholar
29. Freedman B, Butterfield RO, Pryde EH. Variables affecting the yields of fatty esters from transesterified vegetable oils. J American Oil Chem 687 Soc (AOCS) 1984;61:450–503.10.1007/BF02541649Search in Google Scholar
30. Encinar JM, Gonzalez JF, Rodriguez JJ, Tejedox A. Biodiesel fuels from vegetable oil: transesterification of Cynara Ardunculus L. oils with ethanol. J Energy Fuels 2002;16(2):443–50.10.1021/ef010174hSearch in Google Scholar
31. Nanvaee AA, Yahya R, Gan SN. Cleaner production through using by-product palm stearin to synthesis alkyd resin for coating applications. J Cleaner Prod 2013;54:307–14.10.1016/j.jclepro.2013.04.027Search in Google Scholar
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Articles in the same Issue
- Application of Sinusoidal Function and a 25–1 Fractional Factorial Array in the Kinetics and Optimization Study of Gmelina Seed Oil Modified Alkyd Resin Synthesis
- Fuzzy Multivariable Control Strategy Applied to a Refrigeration System
- Mass Transfer Parameters and Modeling of Hot Air Drying Kinetics of Dill Leaves
- Catalytic Sol Assisted Dense Pd/γ-Al2O3 Membrane using Modified Electroless Plating: Effect of Process on Surface Morphology
- Temperature and Concentration Dependence of Viscosity of Binary Mixtures of PEG-1000 + water
- Analysis of a Nonlinear Model of Heat Transfer Through a Rectangular Fin: Exact Solutions and Their Multiplicity
Articles in the same Issue
- Application of Sinusoidal Function and a 25–1 Fractional Factorial Array in the Kinetics and Optimization Study of Gmelina Seed Oil Modified Alkyd Resin Synthesis
- Fuzzy Multivariable Control Strategy Applied to a Refrigeration System
- Mass Transfer Parameters and Modeling of Hot Air Drying Kinetics of Dill Leaves
- Catalytic Sol Assisted Dense Pd/γ-Al2O3 Membrane using Modified Electroless Plating: Effect of Process on Surface Morphology
- Temperature and Concentration Dependence of Viscosity of Binary Mixtures of PEG-1000 + water
- Analysis of a Nonlinear Model of Heat Transfer Through a Rectangular Fin: Exact Solutions and Their Multiplicity
