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Guidelines for Rheological Characterization of Polyamide Melts (IUPAC Technical Report)

Published/Copyright: September 1, 2009
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Guidelines for Rheological Characterization of Polyamide Melts (IUPAC Technical Report)

by Dick J. Dijkstra

Pure and Applied Chemistry, 2009

Vol. 81, No. 2, pp. 339–349

Most producers of polyamide have their own characterization methods to study the rheological properties of polyamide 6 (PA6). However, the measured rheological properties depend strongly on the sample preparation method, humidity regulation, and time-temperature history during the measurement, not to mention the kind of rheometer being used. This investigation is the result of an IUPAC project initiated by the Subcommittee on Structure and Properties of Commercial Polymers (project 2004-009-1-400). Members of several industrial organizations, universities, and institutes cooperated, with the aim of formulating a guideline to measure reproducible rheological properties of PA6. The results of the investigation show the changes in molecular weight during different kinds of rheological measurements due to hydrolysis and amidization reactions. A guideline is introduced that can be used to make comparable rheological measurements on PA6.

http://dx.doi.org/10.1351/PAC-REP-08-07-22

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Page last modified 28 April 2009.

Copyright © 2003-2009 International Union of Pure and Applied Chemistry.

Questions regarding the website, please contact edit.ci@iupac.org

_

Guidelines for Rheological Characterization of Polyamide Melts (IUPAC Technical Report)

by Dick J. Dijkstra

Pure and Applied Chemistry, 2009

Vol. 81, No. 2, pp. 339–349

Most producers of polyamide have their own characterization methods to study the rheological properties of polyamide 6 (PA6). However, the measured rheological properties depend strongly on the sample preparation method, humidity regulation, and time-temperature history during the measurement, not to mention the kind of rheometer being used. This investigation is the result of an IUPAC project initiated by the Subcommittee on Structure and Properties of Commercial Polymers (project 2004-009-1-400). Members of several industrial organizations, universities, and institutes cooperated, with the aim of formulating a guideline to measure reproducible rheological properties of PA6. The results of the investigation show the changes in molecular weight during different kinds of rheological measurements due to hydrolysis and amidization reactions. A guideline is introduced that can be used to make comparable rheological measurements on PA6.

http://dx.doi.org/10.1351/PAC-REP-08-07-22

_

Page last modified 28 April 2009.

Copyright © 2003-2009 International Union of Pure and Applied Chemistry.

Questions regarding the website, please contact edit.ci@iupac.org

Published Online: 2009-09-01
Published in Print: 2009-06

© 2014 by Walter de Gruyter GmbH & Co.

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  1. Masthead
  2. From the Editor
  3. Contents
  4. Moving Ahead with the International Year of Chemistry
  5. What Is “Materials Chemistry?”
  6. Beyond the Book
  7. Scientific Method: Can It Help Promote the Public Appreciation of Science?
  8. IUPAC President Publicizes the International Year of Chemistry
  9. L’Oréal-UNESCO Awards Bestowed Upon Five Exceptional Women Scientists
  10. Javier Garcia Martinez Named a Young Global Leader
  11. Deliang Chen Takes the Helm at ICSU
  12. Postgraduate Course in Polymer Science
  13. Toward a Comprehensive Definition of Oxidation State
  14. IUPAC International Chemical Identifier–InChI Update
  15. Humic-Metal Binding Constants Database
  16. Provisional Recommendations
  17. Immunological Effects of Mercury (IUPAC Technical Report)
  18. Teaching High-Temperature Materials Chemistry at University (IUPAC Technical Report)
  19. Guidelines for Rheological Characterization of Polyamide Melts (IUPAC Technical Report)
  20. Dispersity in Polymer Science (IUPAC Recommendations 2009)
  21. Countercurrent Chromatography in Analytical Chemistry (IUPAC Technical Report)
  22. A Global Science Gateway
  23. Interactions of Soil Minerals with Organic Components and Microorganisms
  24. Biotechnology for the Sustainability of Human Society
  25. From Molecular Understanding to Innovative Applications of Humic Materials
  26. D.I. Mendeleev and the Problems of Sustainable Development
  27. Mendeleev and Natural Resources
  28. Challenges in Organic and Bioorganic Chemistry
  29. Biological Surfaces and Interfaces
  30. Heteroatom Chemistry
  31. Philosophy of Chemistry
  32. Advanced Materials
  33. Thermodynamics
  34. Crop Protection Chemistry in Latin America
  35. Mark Your Calendar
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