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New Publications from the American Chemical Society and the American Institute of Physics

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Chemistry International -- Newsmagazine for IUPAC
From the journal Chemistry International -- Newsmagazine for IUPAC Volume 22 Issue 5

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New Publications from the American Chemical Society and the American Institute of Physics

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Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry, Halogen Species: Supplement VIII. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry, by R. Atkinson, D. L. Baulch, R. A. Cox, R. F. Hampson Jr., J. A. Kerr (Chairman), M. J. Rossi, and J. Troe. USD 55.00. Published in the Journal of Physical and Chemical Reference Data, Vol. 29, No. 2, pp. 167—266, 2000, by the American Chemical Society (1155 Sixteenth Street, N.W., Washington, DC 20036-9976) and the American Institute of Physics (Suite 1NO1, 2 Huntington Quadrangle, Melville, NY 11747-4502) for the National Institute of Standards and Technology [S0047-2689(00)00302-0].

This paper updates and extends part of the previous database of critical evaluations of the kinetics and photochemistry of gas-phase chemical reactions of neutral species involved in atmospheric chemistry [J. Phys. Chem. Ref. Data 9, 295 (1980); 11, 327 (1982); 13, 1259 (1984); 18, 881 (1989); 21, 1125 (1992); 26, 521 (1997); 26, 1329 (1997); 28, 191 (1999)].

The present evaluation is limited to the inorganic halogen family of atmospherically important reactions. The work has been carried out by the authors under the auspices of the IUPAC Subcommittee on Gas Phase Kinetic Data Evaluation for Atmospheric Chemistry. Data sheets have been prepared for 102 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each thermal reaction, a preferred value of the rate coefficient at 298 K is given, together with a temperature dependence where possible. The selection of the preferred value is discussed, and esti-mates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction.

For each photochemical reaction, the data sheets list the preferred values of the photoabsorption cross sections and the quantum yields of the photochemical reactions, together with comments on how they were selected.

The data sheets are intended to provide the basic physical chemical data needed as input for calculations that model atmospheric chemistry. A table summarizing the preferred rate data is provided, together with an appendix listing the available values of enthalpies of formation of the reactant and product species.

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Published Online: 2009-09-01
Published in Print: 2000-09

© 2014 by Walter de Gruyter GmbH & Co.

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https://doi.org/10.1515/ci.2000.22.5.150a

Articles in the same Issue

  1. Polyaniline: Recommendations for Preparation of Conducting Polymer and Its Colloidal Form
  2. An Outlook for Chemistry in Chile in 2000
  3. Winners of the 2000 Prize
  4. Announcement of the 2001 Prize
  5. Procedures for the 2001 Prize
  6. Air Quality in Denmark
  7. e-news from www.iupac.org
  8. Reports from IUPAC-Sponsored Symposia
  9. Round-Robin Test on the Molecular Characterization of Epoxy Resins by Liquid Chromatography
  10. Polyaniline: Recommendations for Preparation of Conducting Polymer and Its Colloidal Form
  11. Solubility Phenomena–Applications for Environmental Improvement
  12. Structure and Properties of Cyclic Olefin Copolymers
  13. Terminology of Polymers with Ionizable Groups and Polymers Containing Ions
  14. Glossary of Terms Relating to Polymeric Gels and Networks, Hybrid Inorganic Polymeric Materials, and the Processing Thereof
  15. New www.royalsoc.ac.uk
  16. Academies to Provide Science Advice to World Leaders
  17. Ronald Breslow Elected to Royal Society
  18. New Books from IUPAC
  19. Technical Reports and IUPAC Recommendations Published in 1999 Issues of Pure and Applied Chemistry (PAC) and Elsewhere
  20. New Publications from the American Chemical Society and the American Institute of Physics
  21. Macromolecular Division. Commission on Macromolecular Nomenclature – Generic Source-Based Nomenclature for Polymers
  22. Analytical Chemistry Division. Commission on Separation Methods in Analytical Chemistry – The Hold-Up Volume Concept in Column Chromatography
  23. Analytical Chemistry Division. Commission on Separation Methods in Analytical Chemistry – Retention Parameters in Gas Chromatography
  24. Commission on Food–VI.5
  25. International Symposium on Green Chemistry, 10–13 January 2001, Delhi, India
  26. 4th Annual UNESCO School and South African IUPAC Conference on Macromolecules and Materials Science, 9–11 April 2001, Johannesburg, South Africa
  27. 2nd International Workshop on Thermochemical, Thermodynamic, and Transport Properties of Halogenated Hydrocarbons and Mixtures, 9–11 April 2001, Paris, France
  28. 3rd International Symposium on Free-Radical Polymerization: Kinetics and Mechanisms, 3–8 June 2001, Il Ciocco, Lucca, Tuscany (Castelvecchio Pascoli), Italy
  29. 15th Bratislava International Conference on Polymers: Preparation of Nonconventional Polymer Dispersions, 25–28 June 2001, Smolenice, Slovak Republic
  30. 15th International Symposium on Plasma Chemistry (ISPC-15), 9–13 July 2001, Orléans, France
  31. 4th International Symposium on Ionic Polymerization, 22–26 October 2001, Crete, Greece
  32. 7th International Symposium on Hyphenated Techniques in Chromatography and Hyphenated Chromatographic Analyzers (HTC-7), 6–8 February 2002, Bruges, Belgium
  33. 5th Annual UNESCO School and South African IUPAC Conference on Macromolecules and Materials Science, 6–10 February 2002, Stellenbosch, South Africa
  34. IUPAC World Polymer Congress 2002–39th International Symposium on Macromolecules, 7–12 July 2002, Beijing, China
  35. 14th International Conference on Organic Synthesis (ICOS-14), 14–19 July 2002, Christchurch, New Zealand
  36. 17th IUPAC Conference on Chemical Thermodynamics, 28 July–2 August 2002, Rostock, Germany
  37. 10th IUPAC International Congress on the Chemistry of Crop Protection, 4–9 August 2002, Basel, Switzerland
  38. Conference Calendar
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