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Preparation of chitosan oligomers and characterization: their antifungal activities and decay resistance
-
Ibrar Hussain
,
Tripti Singh
Published/Copyright:
July 30, 2011
Abstract
Chitosan, a polymer of D-glucosamine, is known for its antimicrobial activity. However, the physicochemical properties of chitosan depend upon three principal factors, i.e., source of raw material, molecular weight and degree of deacetylation. Here, synthesis and characterization of chitosan oligomers is reported, which were prepared by the nitrous acid deaminative depolymerization of chitosan obtained from Sigma Aldrich and China (industrial grade). Subsequently, their antifungal activities were evaluated against selected basid-iomycetes. The nutrient medium bioassay results show that chitosans and chitosan oligomers affected mycelial growth to different magnitudes. Nevertheless, two of the low-MW chitosan oligomers completely inhibited the growth of all the tested fungi as compared to high-MW chitosan oligomers. Accordingly, antifungal activity increases by decreasing degree of polymerization of chitosan oligomers, which is divergent to literature data. The wood decay trial confirmed the antifungal activity of chitosan oligomers against basid-iomycetes. Chitosan is leachable by water.
Keywords: chitosan oligomers; CP-MAS 13C NMR; nitrous acid deaminative depolymerization; wood deteriorating fungi.
Received: 2011-1-13
Accepted: 2011-6-24
Published Online: 2011-07-30
Published in Print: 2012-01-01
©2012 by Walter de Gruyter Berlin Boston
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Keywords for this article
chitosan oligomers;
CP-MAS 13C NMR;
nitrous acid deaminative depolymerization;
wood deteriorating fungi.
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- Novel paper sizing agents based on renewables. Part 5: characterization of maleated oleates by ozonolysis
- Polythiophene-cellulose composites: synthesis, optical properties and homogeneous oxidative co-polymerization
- The influence of extended mercerization on some properties of carboxymethyl cellulose (CMC)
- Minimizing the effect of undesirable reactions in ECF bleaching
- A rheological description of the water vapour sorption kinetics behaviour of wood invoking a model using a canonical assembly of Kelvin-Voigt elements and a possible link with sorption hysteresis
- Changes in chemistry, color, dimensional stability and fungal resistance of Pinus radiata D. Don wood with oil heat-treatment
- Improvement of dimensional stability of wood via combination treatment: swelling with maleic anhydride and grafting with glycidyl methacrylate and methyl methacrylate
- Synthesis and properties of resol-type phenol-formaldehyde resins prepared from H2SO4- and HCl-catalyzed phenol-liquefied Cryptomeria japonica wood
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