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Analysis of microwave vs. thermally assisted grafting of poly(methyl-vinyl ether co-maleic acid)-polyethylene glycol to birch kraft pulp
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Published/Copyright:
May 7, 2009
Abstract
Alternative methods of enhancing water absorption of birch pulp fibers by crosslinking poly(methyl vinyl ether-co-maleic acid) and polyethylene glycol are briefly explored. While thermal initiated crosslinking is common, microwave initiated crosslinking of lignocellulosics is less studied. The thermal and microwave initiated crosslinking were compared through water absorption and retention. The microwave conditions were optimized to 105 s at 1600 W, while the thermal samples were placed in a 130°C oven for 6.5 min. Both methods resulted in successfully creating new superabsorbent fibers. The microwave initiated crosslinked fibers absorbed 45–413% more water and the thermal initiated fibers absorbed 210–582% more water than the control fibers (37.3 g/g and 29.4 g/g, respectively). This study demonstrated that it is possible to utilize microwave technology to enhance water absorption properties of lignocellulosics fibers and to reduce reaction times.
Received: 2008-9-3
Accepted: 2009-1-15
Published Online: 2009-05-07
Published Online: 2009-05-07
Published in Print: 2009-07-01
©2009 by Walter de Gruyter Berlin New York
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- Selective enzyme impregnation of chips to reduce specific refining energy in alkaline peroxide mechanical pulping
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- Effects of substrate on laboratory spalting of sugar maple
- Short Notes
- Apigenin derivatives from Paulownia tomentosa Steud. var. tomentosa stem barks
- Forming limits for the bulk forming of solid wood
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Keywords for this article
bleached kraft hardwood pulp;
crosslinking;
microwave;
polycarboxylate;
water absorption
Articles in the same Issue
- Original Papers
- 2D-NMR (HSQC) difference spectra between specifically 13C-enriched and unenriched protolignin of Ginkgo biloba obtained in the solution state of whole cell wall material
- Colour in thermally modified wood of beech, Norway spruce and Scots pine. Part 1: Colour evolution and colour changes
- Colour in thermally modified wood of beech, Norway spruce and Scots pine. Part 2: Property predictions from colour changes
- The relationship found between fibre length and viscosity of three different commercial kraft pulps
- High-yield kraft pulping of Eucalyptus grandis Hill ex Maiden biotreated by Ceriporiopsis subvermispora under two different culture conditions
- Analysis of microwave vs. thermally assisted grafting of poly(methyl-vinyl ether co-maleic acid)-polyethylene glycol to birch kraft pulp
- Selective enzyme impregnation of chips to reduce specific refining energy in alkaline peroxide mechanical pulping
- Radical chain reactions in pyrolytic cleavage of the ether linkages of lignin model dimers and a trimer
- Quantitative chemical indicators to assess the gradation of compression wood
- Comparison of mechanical properties of thermally modified wood at growth ring and cell wall level by means of instrumented indentation tests
- Revisiting the transition between juvenile and mature wood: a comparison of fibre length, microfibril angle and relative wood density in lodgepole pine
- Characterization of the wood quality of pernambuco (Caesalpinia echinata Lam) by measurements of density, extractives content, microfibril angle, stiffness, color, and NIR spectroscopy
- An improved drying model for highly-impermeable hardwoods
- Neutron attenuation coefficients for non-invasive quantification of wood properties
- Topochemical investigations of cell walls in developing xylem of beech (Fagus sylvatica L.)
- Effects of substrate on laboratory spalting of sugar maple
- Short Notes
- Apigenin derivatives from Paulownia tomentosa Steud. var. tomentosa stem barks
- Forming limits for the bulk forming of solid wood
- Meetings
- Meetings
