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Valence band spectroscopy on lignin

  • Lothar Klarhöfer , Burkhard Roos , Wolfgang Viöl , Oliver Höfft , Stefan Dieckhoff , Volker Kempter and Wolfgang Maus-Friedrichs
Published/Copyright: November 6, 2008
Holzforschung
From the journal Volume 62 Issue 6

Abstract

The valence band of lignin and sputtered lignin was studied by X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS) and metastable induced electron spectroscopy (MIES). The corresponding spectra were compared with those from fingerprint molecules, representing the various chemical groups of lignin. The results of this analysis show that valence band spectroscopy, in particular a combination of XPS, UPS and MIES, allows an identification of hydroxyl, methoxy and phenyl groups at the lignin surface.


Corresponding author. Institut für Physik und Physikalische Technologien, Technische Universität Clausthal, Leibnizstraße 4, 38678 Clausthal-Zellerfeld, Germany

Received: 2008-3-7
Accepted: 2008-7-24
Published Online: 2008-11-06
Published in Print: 2008-11-01

©2008 by Walter de Gruyter Berlin New York

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  1. Original Papers
  2. Soda–AQ delignification of poplar wood. Part 1: Reaction mechanism and pulp properties
  3. Soda-AQ delignification of poplar wood. Part 2: Further degradation of initially dissolved lignins
  4. Effect of autohydrolysis of Eucalyptus globulus wood on lignin structure. Part 1: Comparison of different lignin fractions formed during water prehydrolysis
  5. Effect of autohydrolysis of Eucalyptus globulus wood on lignin structure. Part 2: Influence of autohydrolysis intensity
  6. Extraction of galactoglucomannan from spruce wood with pressurised hot water
  7. Determination of ethylenic residues in wood and TMP of spruce by FT-Raman spectroscopy
  8. Quantitative assessment of total phenol contents of European oak (Quercus petraea and Quercus robur) by diffuse reflectance NIR spectroscopy on solid wood surfaces
  9. Valence band spectroscopy on lignin
  10. Analysis of acids and degradation products related to iron and sulfur in the Swedish warship Vasa
  11. Fenton-induced degradation of polyethylene glycol and oak holocellulose. A model experiment in comparison to changes observed in conserved waterlogged wood
  12. Towards novel wood-based materials: Chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR
  13. Manufacture of laminated strand veneer (LSV) composite. Part 1: Optimization and characterization of thin strand veneers
  14. Manufacture of laminated strand veneer (LSV) composite. Part 2: Elastic and strength properties of laminate of thin strand veneers
  15. Flexural, in-plane shear and nail shear properties of falcataria-rubberwood laminated veneer board for flooring
  16. Impedance spectroscopy and circuit modeling of Southern pine above 20% moisture content
  17. Sorption and thermodynamic properties of juvenile Pinus sylvestris L. wood after 103 years of submersion
  18. Iron and calcium translocation from pure gypsum and iron-amended gypsum by two brown rot fungi and a white rot fungus
  19. Ribosomal DNA intergenic spacer of indoor wood-decay fungi
  20. Short Notes
  21. Analysis of thermally treated wood samples using dynamic FT-IR-spectroscopy
  22. Observation of the influence of temperature on the mechanical properties of wood adhesives by nanoindentation
  23. Book review
  24. Identification of the timbers of Southeast Asia and the Western Pacific
  25. Personalia
  26. Prof. Dr. Olaf Schmidt retired at 65
  27. Contents Volume 62
  28. Contents Volume 62 (2008)
  29. Meeting
  30. Meetings
  31. Acknowledgement
  32. Acknowledgement
  33. Author index
  34. Author index
  35. Species index (scientific names)
  36. Species index (scientific names)
  37. Subject index
  38. Subject index
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