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Effects of fixation temperature and environment on copper speciation in ACQ treated red pine
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Cihat Tascioglu
Published/Copyright:
January 18, 2008
Abstract
Red pine (Pinus resinosa Ait.) sapwood samples treated with alkaline (amine) copper quaternary (ACQ) were conditioned at different temperatures and under wet or dry conditions to evaluate the stability of copper (Cu) to leaching and conversion of divalent copper (Cu-II) to monovalent copper (Cu-I). Significant Cu-II was reduced to Cu-I during post-treatment stabilization, especially at elevated temperatures (105°C and 120°C). The percent conversion to Cu-I was higher at lower retentions; in some cases, at low retentions and high fixation temperatures, all of the cupric Cu was reduced to Cu-I, raising the possibility of reduced activity of Cu as a biocide when high temperature conditions are used to fix ACQ treated wood. However, exposure of wood to a leaching procedure (rewetting, re-drying) generally resulted in a significant component of the Cu-I in wood being oxidized back to Cu-II. Steaming of weathered ACQ treated wood at 120°C also converted significant amounts of Cu-II to Cu-I.
Keywords: alkaline (amine) copper quaternary (ACQ); 2,2′-biquinoline; copper speciation; Cu-I; fixation; ion coupled plasma spectroscopy; UV-visible
Received: 2007-7-31
Accepted: 2007-10-29
Published Online: 2008-01-18
Published Online: 2008-01-18
Published in Print: 2008-05-01
©2008 by Walter de Gruyter Berlin New York
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Keywords for this article
alkaline (amine) copper quaternary (ACQ);
2,2′-biquinoline;
copper speciation;
Cu-I;
fixation;
ion coupled plasma spectroscopy;
UV-visible
Articles in the same Issue
- Meetings
- Original Papers
- Topochemical investigation on tension wood fibres of Acer spp., Fagus sylvatica L. and Quercus robur L.
- Developing environmentally benign and effective organic wood preservatives by understanding the biocidal and non-biocidal properties of extractives in naturally durable heartwood
- Assessment of biodeterioration for the screening of new wood preservatives: Calculation of stiffness loss in rapid decay testing
- Degradation of thermo-hygro-mechanically (THM)-densified wood by soft-rot fungi
- FT-NIR spectroscopy in predicting the decay resistance related characteristics of solid Scots pine (Pinus sylvestris L.) heartwood
- Effects of fixation temperature and environment on copper speciation in ACQ treated red pine
- Fixation of copper(II)-protein formulation in wood: Part 1. Influence of tannic acid on fixation of copper in wood
- Fixation of copper-protein formulation in wood: Part 2. Molecular mechanism of fixation of copper(II) in cellulose, lignin and wood studied by EPR
- 1-Alkoxymethyl-X-dimethylaminopyridinium-base ionic liquids in wood preservation
- Short Note
- Synthesis and evaluation of phosphortriamidates in wood for thermal and fungal decay protection
- Original Papers
- 3D magnetic resonance microscopy of a wounded beech branch
- Sorption of corn cob and oat spelt arabinoxylan onto softwood kraft pulp
- Effects of thermomechanical refining conditions on the morphology and thermal properties of wheat straw fibre
- Extractive composition and summative chemical analysis of thermally treated eucalypt wood
- Analysis of cell wall swelling on the basis of a cylindrical model
- Swelling of larch wood in organic liquids
- Determination of the thermal conductivity of wood by the hot plate method: The influence of morphological properties of fir wood (Abies alba Mill.) to the contact thermal resistance
- Short Note
- Study of the retarding mechanism of citric acid during gypsum particleboard manufacturing
- Obituary
- William Edwin (Ted) Hillis (1921–2008)
