Article
Licensed
Unlicensed
Requires Authentication
Stabilization of peracetic acid with aspartic acid diethoxy succinate (AES)
-
Evgeny Popov
Published/Copyright:
August 8, 2007
Abstract
Stabilization of peracetic acid (PAA) by aspartic acid diethoxy succinate (AES) was studied by electron spin resonance, UV/Vis spectroscopy, electrospray ionization time-of-flight mass spectrometry and oxygen evolution measurements. The results indicate that Mn(II)-AES complexes may exist in both monomeric and dimeric forms. Dimerization is proposed to proceed via formation of an oxygen bridge between two Mn(II)-AES complexes. The equilibrium between these two forms depends strongly on pH, the monomeric form being favored under acidic conditions, while conditions close to neutral pH favor the dimeric form. In the presence of PAA, the dimer form was oxidized and finally yielded MnO2. Oxygen evolution measurements were carried out to demonstrate the efficiency of AES in stabilizing PAA solutions containing small amounts of Mn(II) impurities under acidic conditions.
Keywords: dimer of aspartic acid diethoxy succinate (AES); Mn(II); Mn(IV); oxygen bridge; peracetic acid (PAA); stabilization
Received: 2007-2-6
Accepted: 2007-5-29
Published Online: 2007-08-08
Published in Print: 2007-8-1
©2007 by Walter de Gruyter Berlin New York
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Meetings
- Chemical composition of 36 Brazilian Amazon forest wood species
- Characterization of non-cellulosic glucans in Eucalyptus globulus Labill. wood and kraft pulp
- Study of the phenolic compounds formed during pretreatment of sugarcane bagasse by wet oxidation and steam explosion
- Determination of the accessible hydroxyl groups in heat-treated Styrax tonkinensis (Pierre) Craib ex Hartwich wood by hydrogen-deuterium exchange and 2H NMR spectroscopy
- Lignin modification in the initial phase of softwood kraft pulp delignification with polyoxometalates (POMs)
- Synthesis of light-colored rosin glycerol ester
- Studies on fluorescence of cellulosics
- Fluorescence spectroscopy for chromophore studies on bleached kraft pulps
- Influence of surface structure on wetting of coated offset papers
- Fundamental study of the interaction of Ti atoms with spruce surfaces
- Surface analysis of groundwood paper treated by diffuse coplanar surface barrier discharge (DCSBD) type atmospheric plasma in air and in nitrogen
- Ultrastructural aspects of fibre development during the stone groundwood process: New insights into derived pulp properties
- Stabilization of peracetic acid with aspartic acid diethoxy succinate (AES)
- Stabilization of H2O2 in the presence of Fe(II) and Mn(II) impurities under alkaline conditions
- Viscoelastic properties of green wood across the grain measured by harmonic tests in the range 0–95°C: Hardwood vs. softwood and normal wood vs. reaction wood
- Thermoforming of wood veneer composite sheets
- A revised multi-Fickian moisture transport model to describe non-Fickian effects in wood
- Novel experimental approach for longitudinal-radial stiffness characterisation of clear wood by a single test
- Fracture characterisation of yew (Taxus baccata L.) and spruce (Picea abies [L.] Karst.) in the radial-tangential and tangential-radial crack propagation system by a micro wedge splitting test
- Determination of Young's modulus and shear modulus by means of deflection curves for wood beams obtained in static bending tests
- Insecticidal activity of essential oil from Chamaecyparis formosensis Matsum
- Knotwood as a window to the indirect measurement of the decay resistance of Scots pine heartwood
- Field assessment of wood stake decomposition in forest soil
Keywords for this article
dimer of aspartic acid diethoxy succinate (AES);
Mn(II);
Mn(IV);
oxygen bridge;
peracetic acid (PAA);
stabilization
Articles in the same Issue
- Meetings
- Chemical composition of 36 Brazilian Amazon forest wood species
- Characterization of non-cellulosic glucans in Eucalyptus globulus Labill. wood and kraft pulp
- Study of the phenolic compounds formed during pretreatment of sugarcane bagasse by wet oxidation and steam explosion
- Determination of the accessible hydroxyl groups in heat-treated Styrax tonkinensis (Pierre) Craib ex Hartwich wood by hydrogen-deuterium exchange and 2H NMR spectroscopy
- Lignin modification in the initial phase of softwood kraft pulp delignification with polyoxometalates (POMs)
- Synthesis of light-colored rosin glycerol ester
- Studies on fluorescence of cellulosics
- Fluorescence spectroscopy for chromophore studies on bleached kraft pulps
- Influence of surface structure on wetting of coated offset papers
- Fundamental study of the interaction of Ti atoms with spruce surfaces
- Surface analysis of groundwood paper treated by diffuse coplanar surface barrier discharge (DCSBD) type atmospheric plasma in air and in nitrogen
- Ultrastructural aspects of fibre development during the stone groundwood process: New insights into derived pulp properties
- Stabilization of peracetic acid with aspartic acid diethoxy succinate (AES)
- Stabilization of H2O2 in the presence of Fe(II) and Mn(II) impurities under alkaline conditions
- Viscoelastic properties of green wood across the grain measured by harmonic tests in the range 0–95°C: Hardwood vs. softwood and normal wood vs. reaction wood
- Thermoforming of wood veneer composite sheets
- A revised multi-Fickian moisture transport model to describe non-Fickian effects in wood
- Novel experimental approach for longitudinal-radial stiffness characterisation of clear wood by a single test
- Fracture characterisation of yew (Taxus baccata L.) and spruce (Picea abies [L.] Karst.) in the radial-tangential and tangential-radial crack propagation system by a micro wedge splitting test
- Determination of Young's modulus and shear modulus by means of deflection curves for wood beams obtained in static bending tests
- Insecticidal activity of essential oil from Chamaecyparis formosensis Matsum
- Knotwood as a window to the indirect measurement of the decay resistance of Scots pine heartwood
- Field assessment of wood stake decomposition in forest soil
