Home Effect of climatic variables on chromated copper arsenate (CCA) leaching during above-ground exposure
Article
Licensed
Unlicensed Requires Authentication

Effect of climatic variables on chromated copper arsenate (CCA) leaching during above-ground exposure

  • James L. Taylor and Paul A. Cooper
Published/Copyright: July 1, 2005
Become an author with De Gruyter Brill
Holzforschung
From the journal Volume 59 Issue 4

Abstract

Until recently, most research on the leaching of preservatives from treated wood was conducted in the laboratory. Although these studies have contributed to the understanding of leaching, the data generated under controlled conditions often do not apply to leaching during natural exposure and weathering. In addition, little is known about the effects of climatic variables and long-term emission rates. This paper examines leaching of chromated copper arsenate (CCA) from lumber exposed above ground to 685 mm of precipitationduring 351 days of natural weathering. Stepwise multiple regression analysis revealed relationships between leaching and a number of treatment and climatic variables, including: species of wood, initial preservative loading, amount of precipitation, average air temperature, average light intensity, pH and duration of rain event. Regression models explained approximately 30% of the variation in chromium and arsenic leaching and 44% of the variation in copper leaching.

:

Corresponding author. University of Toronto, Faculty of Forestry, 33 Willcocks Street, Toronto, ON M5S 3B3, Canada

References

Cockroft, R., Laidlaw R.A. (1978) Factors affecting leaching of preservatives in practice. IRG/WP/3113. International Research Group on Wood Preservation, Stockholm, Sweden.Search in Google Scholar

Cooper, P.A. (2003) Leaching of CCA – facts and contradictions. Proc. Am. Wood Preserv. Assoc.99:28.Search in Google Scholar

Evans, F.G. (1987) Leaching from CCA-impregnated wood to food, drinking water and silage. IRG/WP/3433. International Research Group on Wood Preservation, Stockholm, Sweden.Search in Google Scholar

Hingston, J.A., Collins C.D., Murphy R.J., Lester J.N. (2001) Leaching of chromated copper arsenate wood preservatives: a review. Environ. Pollut.111:53–66.10.1016/S0269-7491(00)00030-0Search in Google Scholar

Kazi, F., Cooper, P.A., Chen, J. (2000) Kinetic model of CCA reaction in wood – Part 2. The main reaction zone. Wood Fiber Sci.32(4):442–449.Search in Google Scholar

Kennedy, M.J. (2004) Depletion of copper-based preservatives from pine decking and impacts on soil-dwelling invertebrates. In: Proceedings of Environmental Impacts of Preservative-Treated Wood Conference, Feb. 8–11, 2004, Orlando, Florida. Florida Center for Environmental Solutions Gainesville, FL. pp. 124–145.Search in Google Scholar

Lebow, S. (1996) Leaching of wood preservative components and their mobility in the environment. Summary of pertinent literature. General Technical Report FPL-GTR-93. Forest Products Laboratory, United States Department of Agriculture, Forest Service. p. 36.Search in Google Scholar

Lebow, S., Williams, S.R., Lebow, P. (2003) Effect of simulated rainfall and weathering on release of preservative ele-ments from CCA treated wood. Environ. Sci. Technol.37:4077–4082.10.1021/es0343048Search in Google Scholar PubMed

Lebow, S., Cooper, P., Lebow, P. (2004) Variability in evaluating environmental impacts of treated wood. In: Proceedings of Environmental Impacts of Preservative-Treated Wood Conference, Feb. 8–11, 2004, Orlando, Florida. Florida Center for Environmental Solutions Gainesville, FL. pp. 1–14.10.2737/FPL-RP-620Search in Google Scholar

Taylor, J.L., Cooper, P.A. (2003) Leaching of CCA from lumber exposed to natural rain above ground. Forest Prod. J.53(9):81–86.Search in Google Scholar

Van Eetvelde, G., Stevens, M., Vander Mijnsbrugge, L. (1994) Comparative study on leaching of CCA from treated timber: modelling of emission data. IRG/WP/94-50027. International Research Group on Wood Preservation, Stockholm, Sweden.Search in Google Scholar

Van Eetvelde, G., Orsler, R., Holland, G., Stevens, M. (1995a) Effect of leaching temperature and water acidity on the loss of metal elements from CCA-treated timber in aquatic applications. Part 1. Laboratory-scale investigation. IRG/WP/95-40046. International Research Group on Wood Preservation, Stockholm, Sweden.Search in Google Scholar

Van Eetvelde, G., Homan, J.W., Militz, H., Stevens, M. (1995b) Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2. Semi-industrial investigation. IRG/WP/95-50040. International Research Group on Wood Preservation, Stockholm, Sweden.Search in Google Scholar

Waldron, L., Cooper, P., Ung, T. (2004) Modeling of wood preservative leaching in service. In: Proceedings of Environmental Impacts of Preservative-Treated Wood Conference, Feb. 8–11, 2004, Orlando, Florida. Florida Center for Environmental Solutions, Gainesville, FL. pp. 81–97.Search in Google Scholar

Published Online: 2005-07-01
Published in Print: 2005-07-01

© Walter de Gruyter Berlin New York

Articles in the same Issue

  1. Chemical changes in silver birch (Betula pendula Roth) wood caused by hydrogen peroxide bleaching and monitored by color measurement (CIELab) and UV-Vis, FTIR and UVRR spectroscopy
  2. Hydrophobisation and densification of wood by different chemical treatments
  3. Functionalisation of wood by reaction with 3-isocyanatopropyltriethoxysilane: Grafting and hydrolysis of the triethoxysilane end groups
  4. Isolation and fractionation of lignosulfonates by amine extraction and ultrafiltration: A comparative study
  5. Bioactive phenolic substances in industrially important tree species. Part 4: Identification of two new 7-hydroxy divanillyl butyrolactol lignans in some spruce, fir, and pine species
  6. Characterization of physiological functions of sapwood IV: Formation and accumulation of lignans in sapwood of Cryptomeria japonica (L.f.) D. Don after felling
  7. X-ray scattering studies of thermally modified Scots pine (Pinus sylvestris L.)
  8. Differences in acoustic velocity by resonance and transit-time methods in an anisotropic laminated wood medium
  9. Parallel-plate rheology of latex films bonded to wood
  10. An assessment of the feasibility of ultrasound as a defect detector in lumber
  11. Vibrational properties of green wood in high-temperature water vapor
  12. The stiffness modulus in Norway spruce as a function of year ring
  13. Strain analysis in bulk forming of wood
  14. Decay fungi from playground wood products in service using 28S rDNA sequence analysis
  15. Effect of climatic variables on chromated copper arsenate (CCA) leaching during above-ground exposure
  16. Protic ionic liquids with organic anion as wood preservative
Downloaded on 6.11.2025 from https://www.degruyterbrill.com/document/doi/10.1515/HF.2005.077/html?lang=en
Scroll to top button