10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents
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Alexander M. Polgar
Abstract
The use of reagents containing bonds between group 14 elements and Se or Te for the self-assembly of polynuclear metal-chalcogen compounds is covered. Background material is briefly reviewed and examples from the literature are highlighted from the period 2007-2017. Emphasis is placed on the different classes of 14-16 precursors and their application in the targeted synthesis of metal-chalcogen compounds. The unique properties arising from the combination of specific 14-16 precursors, metal atoms, and ancillary ligands are also described. Selected examples are chosen to underline the progress in (i) controlled synthesis of heterometallic (ternary) chalcogen clusters, (ii) chalcogen clusters with organic functionalized surfaces, and (iii) crystalline open-framework metal chalcogenides.
Abstract
The use of reagents containing bonds between group 14 elements and Se or Te for the self-assembly of polynuclear metal-chalcogen compounds is covered. Background material is briefly reviewed and examples from the literature are highlighted from the period 2007-2017. Emphasis is placed on the different classes of 14-16 precursors and their application in the targeted synthesis of metal-chalcogen compounds. The unique properties arising from the combination of specific 14-16 precursors, metal atoms, and ancillary ligands are also described. Selected examples are chosen to underline the progress in (i) controlled synthesis of heterometallic (ternary) chalcogen clusters, (ii) chalcogen clusters with organic functionalized surfaces, and (iii) crystalline open-framework metal chalcogenides.
Chapters in this book
- Frontmatter I
- Preface V
- Contents VII
- List of contributing authors XIII
- 1. Introduction of selenium and tellurium into reaction systems 1
- 2. Selenium– and tellurium–halogen reagents 27
- 3. Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes 61
- 4. Selenium– and tellurium–nitrogen reagents 123
- 5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications 151
- 6. Synthesis and coordination chemistry of cyclic seleno- and telluroureas 207
- 7. Selenium and Tellurium Electrophiles in Organic Synthesis 243
- 8. Reagents that Contain Se-H or Te-H Bonds 301
- 9. Zinc-Selenium reagents in organic synthesis 315
- 10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents 331
- 11. Applications of metal selenium/tellurium compounds in materials science 383
- Formula Index of Selenium and Tellurium Reactants 445
Chapters in this book
- Frontmatter I
- Preface V
- Contents VII
- List of contributing authors XIII
- 1. Introduction of selenium and tellurium into reaction systems 1
- 2. Selenium– and tellurium–halogen reagents 27
- 3. Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes 61
- 4. Selenium– and tellurium–nitrogen reagents 123
- 5. Organophosphorus-selenium/tellurium reagents: from synthesis to applications 151
- 6. Synthesis and coordination chemistry of cyclic seleno- and telluroureas 207
- 7. Selenium and Tellurium Electrophiles in Organic Synthesis 243
- 8. Reagents that Contain Se-H or Te-H Bonds 301
- 9. Zinc-Selenium reagents in organic synthesis 315
- 10. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents 331
- 11. Applications of metal selenium/tellurium compounds in materials science 383
- Formula Index of Selenium and Tellurium Reactants 445
