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Properties of Hydrogen-Bonded Liquids at Interfaces

  • Gerd Buntkowsky EMAIL logo , Michael Vogel EMAIL logo and Roland Winter EMAIL logo
Published/Copyright: March 19, 2018
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 232 Issue 7-8

Abstract

Effects of interfaces on hydrogen-bonded liquids play major roles in nature and technology. Despite their importance, a fundamental understanding of these effects is still lacking. In large parts, this shortcoming is due to the high complexity of these systems, leading to an interference of various interactions and effects. Therefore, it is advisable to take gradual approaches, which start from well designed and defined model systems and systematically increase the level of intricacy towards more complex mimetics. Moreover, it is necessary to combine insights from a multitude of methods, in particular, to link novel preparation strategies and comprehensive experimental characterization with inventive computational and theoretical modeling. Such concerted approach was taken by a group of preparative, experimentally, and theoretically working scientists in the framework of Research Unit FOR 1583 funded by the Deutsche Forschungsgemeinschaft (German Research Foundation). This special issue summarizes the outcome of this collaborative research. In this introductory article, we give an overview of the covered topics and the main results of the whole consortium. The following contributions are review articles or original works of individual research projects.

Keywords: aqueous solutions; confinement; hydrogen-bonded liquids; macromolecular crowding; mesoporous silica; proteins; reverse micelles; water

Acknowledgement

Financial support by the Deutsche Forschungsgemeinschaft in the framework of Forschergruppe FOR 1583 through grants Bu-911/18-1/2, Vo-905/8-1/2, Vo-905/9-1/2, Vo-905/10-1/2, and Wi-742/17-1/2 is gratefully acknowledged.

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Received: 2018-01-19
Accepted: 2018-02-16
Published Online: 2018-03-19
Published in Print: 2018-07-26

©2018 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Preface
  3. Editorial: Molecules in Prison
  4. Properties of Hydrogen-Bonded Liquids at Interfaces
  5. Ab-Initio Molecular Dynamics Simulations and Calculations of Spectroscopic Parameters in Hydrogen-Bonding Liquids in Confinement (Project 8)
  6. Liquid Water Confined in Cellulose with Variable Interfacial Hydrophilicity
  7. A Combined Solid-State NMR, Dielectric Spectroscopy and Calorimetric Study of Water in Lowly Hydrated MCM-41 Samples
  8. Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
  9. 2H NMR Studies on Water Dynamics in Functionalized Mesoporous Silica
  10. 2H NMR Studies on the Dynamics of Pure and Mixed Hydrogen-Bonded Liquids in Confinement
  11. Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement
  12. Effects of Cosolvents and Macromolecular Crowding on the Phase Transitions and Temperature-Pressure Stability of Chiral and Racemic Poly-Lysine
  13. Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
  14. Nanoscale Structuring in Confined Geometries using Atomic Layer Deposition: Conformal Coating and Nanocavity Formation
  15. Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
  16. Molecular Dynamics Simulations of Water, Silica, and Aqueous Mixtures in Bulk and Confinement
  17. Monitoring the Process of Nanocavity Formation on a Monomolecular Level
  18. Elastin-like Peptide in Confinement: FT-IR and NMR T1 Relaxation Data
https://doi.org/10.1515/zpch-2018-1110
Keywords for this article
aqueous solutions; confinement; hydrogen-bonded liquids; macromolecular crowding; mesoporous silica; proteins; reverse micelles; water

Articles in the same Issue

  1. Frontmatter
  2. Preface
  3. Editorial: Molecules in Prison
  4. Properties of Hydrogen-Bonded Liquids at Interfaces
  5. Ab-Initio Molecular Dynamics Simulations and Calculations of Spectroscopic Parameters in Hydrogen-Bonding Liquids in Confinement (Project 8)
  6. Liquid Water Confined in Cellulose with Variable Interfacial Hydrophilicity
  7. A Combined Solid-State NMR, Dielectric Spectroscopy and Calorimetric Study of Water in Lowly Hydrated MCM-41 Samples
  8. Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
  9. 2H NMR Studies on Water Dynamics in Functionalized Mesoporous Silica
  10. 2H NMR Studies on the Dynamics of Pure and Mixed Hydrogen-Bonded Liquids in Confinement
  11. Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement
  12. Effects of Cosolvents and Macromolecular Crowding on the Phase Transitions and Temperature-Pressure Stability of Chiral and Racemic Poly-Lysine
  13. Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
  14. Nanoscale Structuring in Confined Geometries using Atomic Layer Deposition: Conformal Coating and Nanocavity Formation
  15. Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
  16. Molecular Dynamics Simulations of Water, Silica, and Aqueous Mixtures in Bulk and Confinement
  17. Monitoring the Process of Nanocavity Formation on a Monomolecular Level
  18. Elastin-like Peptide in Confinement: FT-IR and NMR T1 Relaxation Data
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