Abstract
The Zn-rich corner of the 450 °C isothermal section of the Zn–Fe–Co system was experimentally determined. ζ-FeZn13 and ζ-CoZn13 were found to form a continuous solid solution. As a result, the liquid and the ζ phases form a subbinary system at the Zn-rich corner of the ternary system. In addition to the ternary extensions of the binary d-FeZn10 and d-CoZn10 phases, a ternary compound, designated as T phase in the present study, has been identified. X-ray powder diffraction studies suggest that the T phase is isomorphous with Γ′-Fe5Zn21 (cF408). The limits of the solid solubility of Fe and Co in their counter δ phases are appreciable, being 3.1 and 4.2 at.%, respectively.
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The authors would like to thank Mrs. A. M. Prskalo for editorial assistance in the preparation of the manuscript. The phase diagram was drawn by Mr. A. B. Filc.
References
[1] B. Notowidjojo, A.L. Wingrove, N.F. Kennon: Mater. Forum 13 (1989) 153.Search in Google Scholar
[2] Z.W. Chen, N.F. Kennon, J.B. See, M.A. Barter: J. Metals 44 (1992) 22.Search in Google Scholar
[3] X.P. Su, N.-Y. Tang, J.M. Toguri: Canad. Metall. Quart. (2001) 377.10.1179/cmq.2001.40.3.377Search in Google Scholar
[4] N.-Y. Tang, X.P. Su, J.M. Toguri: CALPHAD 25 (2001) 262.Search in Google Scholar
[5] N.-Y. Tang, X.P. Su: Unpublished project research work, Teck Cominco Metals Ltd., Ontario (2001).Search in Google Scholar
[6] N.-Y. Tang, X.P. Su: Mater. Metall. Trans. A 33 (2002) 1559.10.1007/s11661-002-0078-5Search in Google Scholar
[7] J. Schramm: Z. Metallkd. 32 (1938) 10.Search in Google Scholar
[8] J. Schramm: Z. Metallkd. 30 (1938) 131.Search in Google Scholar
[9] J. Schramm: Z. Metallkd. 33 (1941) 46.Search in Google Scholar
[10] J. Schramm: Z. Metallkd. 30 (1938) 122.Search in Google Scholar
[11] F. Götzl, F. Halla, J. Schramm: Z. Metallkd. 33 (1941) 375.Search in Google Scholar
[12] P.J. Brown: Acta Cryst. 15 (1962) 608.10.1107/S0365110X62001528Search in Google Scholar
[13] D.G. Pettifor: J. Phys. C: Solid State Phys. 19 (1986) 285.10.1088/0022-3719/19/3/002Search in Google Scholar
© 2003 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Articles/Aufsätze
- Formation of nanoscale particles and their effect on properties of alloys
- The application of gallium as a liquid metal lubricant
- Phase diagram of the Al–Cu–Fe quasicrystal-forming alloy system
- Phase diagram of the Al–Cu–Fe quasicrystal-forming alloy system
- Phase diagram of the Al–Cu–Fe quasicrystal-forming alloy system
- The Zn-rich corner of the Zn–Fe–Co system at 450°C
- Study on the thermal fatigue of NiTi wires
- Dispersion strengthening of copper by internal oxidation of rapidly solidified Cu–RE alloys
- High-temperature oxidation of Cu–Ti-based rapidly solidified alloys
- Simulation of solidification and heat treatment of nickel-base superalloy SC16
- Contribution of SiC particles to the formation of the structure of Mg-3 wt.% RE cast composites
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Articles in the same Issue
- Frontmatter
- Articles/Aufsätze
- Formation of nanoscale particles and their effect on properties of alloys
- The application of gallium as a liquid metal lubricant
- Phase diagram of the Al–Cu–Fe quasicrystal-forming alloy system
- Phase diagram of the Al–Cu–Fe quasicrystal-forming alloy system
- Phase diagram of the Al–Cu–Fe quasicrystal-forming alloy system
- The Zn-rich corner of the Zn–Fe–Co system at 450°C
- Study on the thermal fatigue of NiTi wires
- Dispersion strengthening of copper by internal oxidation of rapidly solidified Cu–RE alloys
- High-temperature oxidation of Cu–Ti-based rapidly solidified alloys
- Simulation of solidification and heat treatment of nickel-base superalloy SC16
- Contribution of SiC particles to the formation of the structure of Mg-3 wt.% RE cast composites
- Notifications/Mitteilungen
- Personal/Personelles
- Books/Bücher
- Gesellschaftsnachricht
- DGM Conferences