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The Ternary Ga–Ni–Sb System: Invariant Reactions and Liquidus Surface

  • Kornelia Micke , Klaus W. Richter and Herbert Ipser EMAIL logo
Published/Copyright: December 21, 2021
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 92 Issue 1

Abstract

The phase relationships for Ga–Ni–Sb alloys were determined by means of differential thermal analyses along ten selected isopleths through the ternary system. From these the sequence of invariant reactions involving the liquid phase was derived in terms of a Scheil diagram. Furthermore, a projection of the liquidus surface was constructed for the entire composition range. It contains a total of nine invariant four-phase reactions, seven of the transition type and two of the eutectic type. Together with the isothermal sections at 900, 600, and 500 °C that were presented earlier this results in a full description of the phase equilibria in the ternary Ga–Ni–Sb system as a function of composition and temperature.

Abstract

Die Phasengleichgewichte für Ga–Ni–Sb–Legierungen wurden mittels Differenzthermoanalyse entlang zehn ausgewählter Schnitte durch das ternäre System bestimmt. Daraus wurde die Folge von invarianten Reaktionen unter Beteiligung der flüssigen Phase als Scheil-Diagramm abgeleitet. Weiters wurde eine Projektion der Liquidus-Oberfläche für den gesamten Konzentrationsbereich erstellt. Sie enthält neun invariante Vierphasen-Reaktionen, sieben vom übergangstyp und zwei vom eutektischen Typ. Zusammen mit den isothermen Schnitten bei 900, 600 und 500 °C, die bereits friiher vorgestellt wurden, ergibt sich damit eine vollständige Beschreibung der Phasengleichgewichte im ternären System Ga–Ni–Sb in Abhängigkeit von Zusammensetzung und Temperatur.

Keywords: Ga–Ni–Sb System; Thermal Analysis; Ga–Ni–Sb: Phase diagram; Ga–Ni–Sb: Scheil diagram; Ga–Ni–Sb: Liquidus projection
H. Ipser Institute of Inorganic Chemistry Währingerstr. 42 A-1090 Wien, Austria Fax: +43 1 4277 9526

Dedicated to Professor Dr. Dr. h. c. Hein Peter Stüwe on the occasion of his 70th birthday

  1. Financial support of this investigation by the Austrian Science Foundation (“Fonds zur Förderung der wissenschaftlichen Forschung”) under Project No. P10739-CHE is gratefully acknowledged.

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Received: 2000-08-10
Published Online: 2021-12-21

© 2001 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial
  4. Aufsätze
  5. Metalle und Zeit – eine oft vergessene Problematik
  6. Precipitate Size Distribution in Alloys with and without Lattice Misfit
  7. The Ternary Ga–Ni–Sb System: Invariant Reactions and Liquidus Surface
  8. Thermodynamic Calculation of Al-Gd and Al-Gd-Mg Phase Equilibria Checked by Key Experiments
  9. Assessment of Diffusional Mobilities of Cr, Ni, and Si in fcc Cr–Ni–Si Alloys
  10. Quantitative Dilatometric Analysis of the Isothermal Decomposition of Hypereutectoid Fe–C Austenite
  11. The Excess Enthalpies of Liquid Ag-Sb-Te and Ag-Bi-Te Alloys
  12. Temperature Dependent Surface Tension of Binary Alloys: A Simple Model
  13. Micro-hardness Measurements to Evaluate Composition Gradients in Metal-Based Functionally Graded Materials
  14. Temperature Dependence of Lattice Parameter, Misfit and Thermal Expansion Coefficient of Matrix, γ′ Phase and Superalloy
  15. Einfluss der Umformgeschwindigkeit und -temperatur auf die Versagensgrenze von Aluminium AA7075
  16. Phenomenological and Microscopical Description of Scattering on Different Dislocation Arrangements
  17. Creep and Dislocation Structure in Copper Single Crystals Compressed in Directions [010], [110] and [111]
  18. Analysis of Average Orientation Distribution in Sheet Materials with Through-Thickness Texture Gradient
  19. Instructions to Authors/Hinweise für Autoren
  20. Instructions to authors
  21. Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
  22. Personen
  23. Buchbesprechung
  24. Tagungskalender
https://doi.org/10.3139/ijmr-2001-0004
Keywords for this article
Ga–Ni–Sb System; Thermal Analysis; Ga–Ni–Sb: Phase diagram; Ga–Ni–Sb: Scheil diagram; Ga–Ni–Sb: Liquidus projection

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial
  4. Aufsätze
  5. Metalle und Zeit – eine oft vergessene Problematik
  6. Precipitate Size Distribution in Alloys with and without Lattice Misfit
  7. The Ternary Ga–Ni–Sb System: Invariant Reactions and Liquidus Surface
  8. Thermodynamic Calculation of Al-Gd and Al-Gd-Mg Phase Equilibria Checked by Key Experiments
  9. Assessment of Diffusional Mobilities of Cr, Ni, and Si in fcc Cr–Ni–Si Alloys
  10. Quantitative Dilatometric Analysis of the Isothermal Decomposition of Hypereutectoid Fe–C Austenite
  11. The Excess Enthalpies of Liquid Ag-Sb-Te and Ag-Bi-Te Alloys
  12. Temperature Dependent Surface Tension of Binary Alloys: A Simple Model
  13. Micro-hardness Measurements to Evaluate Composition Gradients in Metal-Based Functionally Graded Materials
  14. Temperature Dependence of Lattice Parameter, Misfit and Thermal Expansion Coefficient of Matrix, γ′ Phase and Superalloy
  15. Einfluss der Umformgeschwindigkeit und -temperatur auf die Versagensgrenze von Aluminium AA7075
  16. Phenomenological and Microscopical Description of Scattering on Different Dislocation Arrangements
  17. Creep and Dislocation Structure in Copper Single Crystals Compressed in Directions [010], [110] and [111]
  18. Analysis of Average Orientation Distribution in Sheet Materials with Through-Thickness Texture Gradient
  19. Instructions to Authors/Hinweise für Autoren
  20. Instructions to authors
  21. Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
  22. Personen
  23. Buchbesprechung
  24. Tagungskalender
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