Thermodynamics and Combustion Synthesis of Si–TiC–N and Si–TiO2–N
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Chang-Chun Ge
Abstract
Self-Propagating High-Temperature Synthesis (SHS) of the Si-N2 system is a typical SHS using a gas-solid system to obtain one of the most important advanced ceramics – silicon nitride. For improving the properties and reliability of Si3N4-based ceramics, SHS of Si–TiC–N2 and Si–TiO2–N2 are investigated in this work. Stability diagrams at combustion temperatures are established through thermodynamic calculations. In contrast to the conventional idea of “diluent”, a new idea of “active diluent” is proposed. In these two systems TiC and TiO2 not only act as diluents, but also participate in the reactions during SHS. Two new kinds of in-situ particulate reinforced ceramic composites, Si3N4/SiC/TiCN, Si3N4/Si2N2O/TiN, are developed.
Literature
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© 1998 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Editorial
- Editorial
- Aufsätze
- Schwindungsverhalten von WC–Co Hartmetallen
- Melting Behaviour of (Ti, Mo)C–Co and (Ti, W)C–Co Alloys
- Melting Behaviour of (Ti, Mo)C–Ni and (Ti, W)C–Ni alloys
- Investigation of Swelling Behaviour of Ti–Al Elemental Powder Mixtures During Reaction Sintering
- Mechanical Behaviour of Granular Ceramic Films During Drying
- Grundlagen und neue Anwendungen der Kossel-Technik in der Materialforschung
- Samarium-Cobalt Phase Equilibria Revisited; Relevance to Permanent Magnets
- Dispersion Strengthening of Copper Alloys
- Thermomechanical Treatment of Shape Memory Alloys by Ausforming and Marforming
- High Cycle Fatigue Behaviour of Mo Alloyed Sintered Steel
- The Evolution of a Single Void under Irradiation
- Thermodynamics and Combustion Synthesis of Si–TiC–N and Si–TiO2–N
- Biologisierte Titanwerkstoffe
- Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
- Zeitschrift für
Articles in the same Issue
- Frontmatter
- Editorial
- Editorial
- Aufsätze
- Schwindungsverhalten von WC–Co Hartmetallen
- Melting Behaviour of (Ti, Mo)C–Co and (Ti, W)C–Co Alloys
- Melting Behaviour of (Ti, Mo)C–Ni and (Ti, W)C–Ni alloys
- Investigation of Swelling Behaviour of Ti–Al Elemental Powder Mixtures During Reaction Sintering
- Mechanical Behaviour of Granular Ceramic Films During Drying
- Grundlagen und neue Anwendungen der Kossel-Technik in der Materialforschung
- Samarium-Cobalt Phase Equilibria Revisited; Relevance to Permanent Magnets
- Dispersion Strengthening of Copper Alloys
- Thermomechanical Treatment of Shape Memory Alloys by Ausforming and Marforming
- High Cycle Fatigue Behaviour of Mo Alloyed Sintered Steel
- The Evolution of a Single Void under Irradiation
- Thermodynamics and Combustion Synthesis of Si–TiC–N and Si–TiO2–N
- Biologisierte Titanwerkstoffe
- Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
- Zeitschrift für
