Startseite Study of the Compatibilizer Effect on Blends Prepared from Waste Poly(ethylene-terephthalate) and High Density Polyethylene
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Study of the Compatibilizer Effect on Blends Prepared from Waste Poly(ethylene-terephthalate) and High Density Polyethylene

  • L. Kratofil , Z. Hrnjak-Murgić , J. Jelencć , B. Andricć , T. Kovacć und V. Merzel
Veröffentlicht/Copyright: 26. März 2013
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Abstract

In this work mechanical recycling of waste poly(ethylene-terephthalate) (PET) in the presence of high density polyethylene (HDPE) was studied. The fraction of HDPE in PET/HDPE blends was 3, 5, 6 and 10 wt.%. Isocyanate HI compatibilizer was first synthesized and then added to the blends at a fraction of 5 wt.%. Ethylene-propylene-diene masterbatch (EPDM-M) was prepared by mixing and added in fraction of 15, 30 and 50 wt.%. All PET/HDPE blends studied were characterized by scanning electron microscopy SEM, differential scanning calorimetry DSC and melt flow rate (MFR). Blends prepared with isocyanate HI compatibilizer were also studied by FTIR spectroscopy. Appearance of new vibrations in the FTIR spectra confirms that during the blending reactions between isocyanate HI compatibilizer and blend components appear. Results show that used compatibilizers significantly improved compatibility of polymers in studied blends. From the results it is obvious that immiscibility of PET and HDPE can be overcome.


Mail address: Z. Hrnjak-Murgić, University of Zagreb, Faculty of Chemical Engineering and Technology, P.O.Box 177, HR-10001 Zagreb, Croatia. E-mail:

References

1 1 Scheirs, J.: Incineration of Plastic Waste with Energy Recovery in: Polymer Recycling, Science, Technology and Applications. Scheirs, J. (Ed.), John Wiley & Sons, New York (1998)Suche in Google Scholar

2 2 Paul, D. R., Barlow, J. W., Keskkula, H.: Polymer Blends in: Encyclopedia of Polymer Science and Engineering. Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., (Eds.) John Wiley & Sons, New York (1985)Suche in Google Scholar

3 3 Park, H. D., Park, K. O., Cho, W. J., Ha, C. S., Kwon, S. K.: Polym. Recycling2, p. 283 (1996)Suche in Google Scholar

4 4 Xanthos, M.: Polym. Eng. Sci. 28, p. 1392 (1988)10.1002/pen.760282108Suche in Google Scholar

22 22 Molau, G. E.: Block Copolymers. Aggarwal, S. L. (Ed.), Plenum Press, New York (1970)Suche in Google Scholar

6 6 Fayt, R., Jerome, R., Teyssie, P.: J. Polym. Sci. Polym. Phys. Ed. 20, p. 2209 (1982)10.1002/pol.1982.180201204Suche in Google Scholar

7 7 Demir, T., Tincer, T.: J. Appl. Polym. Sci. 79, p. 827 (2001)10.1002/1097-4628(20010131)79:5<827::AID-APP70>3.0.CO;2-4Suche in Google Scholar

8 8 Stewart, M. E., George, S. E., Miller, R. L.: Polym. Eng. Sci. 33, p. 675 (1993)10.1002/pen.760331104Suche in Google Scholar

9 9 Lee, P. C., Kuo, W. F., Chang, F. C.: Polymer35, p. 5641 (1994)10.1016/S0032-3861(05)80038-2Suche in Google Scholar

10 10 Akkapeddi, M. K., Vanbuskirk, B.: Polym. Mater. Sci. Eng. 67, p. 317 (1992)Suche in Google Scholar

11 11 Yoon, K. H., Lee, H. W., Park, O. O.: J. Appl. Polym. Sci. 70, p. 389 (1998)10.1002/(SICI)1097-4628(19981003)70:2<389::AID-APP20>3.0.CO;2-ZSuche in Google Scholar

12 12 Pawlak, A., Perkins, W. G., Massey, F. L., Hiltner, A., Baer, E.: J. Appl. Polym. Sci. 73, p. 203 (1999)10.1002/(SICI)1097-4628(19990711)73:2<203::AID-APP7>3.0.CO;2-9Suche in Google Scholar

13 13 Park, S. H., Park, K. Y., Suh, K. D.: J. Appl. Polym. Sci. 36, p. 447 (1998)10.1002/(SICI)1099-0488(199802)36:3<447::AID-POLB7>3.0.CO;2-OSuche in Google Scholar

14 14 Kim, D. H., Park, K. Y., Kim, J. Y., Suh, K. D.: J. Appl. Polym. Sci. 78, p. 1017 (2000)10.1002/1097-4628(20001031)78:5<1017::AID-APP110>3.0.CO;2-6Suche in Google Scholar

15 15 Pracella, M., Rolla, L., Chionna, D., Galeski, A.: Macromol. Chem. Phys. 203, p. 1473 (2002)10.1002/1521-3935(200207)203:10/11<1473::AID-MACP1473>3.0.CO;2-4Suche in Google Scholar

16 16 Fox, D. W., Allen, R. B.: Compatibility, in: Encyclopedia of Polymer Science and Engineering. Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G. (Eds.), John Wiley & Sons, New York (1985)Suche in Google Scholar

17 17 Dreyfuss, P., Quirk, R. P.: Graft Copolymers, in. Encyclopedia of Polymer Science and Engineering. Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G. (Eds.), John Wiley & Sons, New York (1988)Suche in Google Scholar

18 18 Allen, N. S., Edge, M., Mohammadian, M., Jones, K.: Polym. Degrad. Stab. 41, p. 191 (1993)10.1016/0141-3910(93)90043-ISuche in Google Scholar

19 19 Berzin, F., Vergnes, B., Delamare, L.: J. Appl. Polym. Sci. 80, p. 1243 (2001)10.1002/app.1210Suche in Google Scholar

20 20 Rosales, C., Perere, R., Ichazo, M., Gonzalez, J., Rojas, H., Sanchez, A., Barrias, A. D.: J. Appl. Polym. Sci. 70, p. 161 (1998)10.1002/(SICI)1097-4628(19981003)70:1<161::AID-APP16>3.0.CO;2-ASuche in Google Scholar

21 21 Grassie, N., Bain, D. R.: J. Polym. Sci. Part I8, p. 2653 (1970)10.1002/pol.1970.150080930Suche in Google Scholar

22 22 Hrnjak-Murgić, Z., Kratofil, L., Jelčvic, Ž., Jelenčic, J., Janović, Z.: Int. Polym. Process. 19, p. 139 (2004)10.3139/217.1817Suche in Google Scholar

23 23 Brandrup, I., Immergut, E. H.: Polymer Handbook, John Wiley & Sons, New York (1975)Suche in Google Scholar

24 24 Pluta, M., Bartczak, Z., Pawlak, A., Galeski, A., Pracella, A.: J. Appl. Polym. Sci. 82, p. 1423 (2001)10.1002/app.1980Suche in Google Scholar

Received: 2005-10-27
Accepted: 2005-12-30
Published Online: 2013-03-26
Published in Print: 2006-07-01

© 2006, Hanser Publishers, Munich

Heruntergeladen am 30.10.2025 von https://www.degruyterbrill.com/document/doi/10.3139/217.0123/pdf
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