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Tubular Film Extrusion Stability of Metallocene Linear Low Density Polyethylene

  • K. Kim and H. J. Kang
Published/Copyright: March 1, 2013
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Abstract

The bubble stability of tubular film extrusion in metallocene linear low density polyethylene(m-LLDPE) and metallocene linear low density polyethylene/linear low density polyethylene(m-LLDPE/LLDPE) blend was investigated. Unstable bubble characteristics in m-LLDPE were found at low draw down ratio (DR) with a symmetric periodic bubble instability at low blow up ratio (BUR) and a helical instability at high blow up ratio. However, m-LLDPE showed better operation windows in tubular film extrusion than that of LLDPE, especially in bubble instability at low BUR. Both bubble instability and helical instability in LLDPE tubular film extrusion were enhanced by the blending with m-LLDPE. m-LLPE possesses higher melt elasticity as compared to m-LLDPE and LLDPE due to the long chain branching introduced by 1-octene co-monomer during polymerization. Blending resulted in broadening of molecular weight distribution (MWD) and thus increase in activation energy.


2 Mail address: H.-J. Kang, Dept. of Polymer Sci. & Eng, #8 Yongsan-Ku, Hannam-dong, Seoul 140-714, Korea E-mail:

References

1 Inoue, M.: Proceeding Polymer Processing Society 14th Annual Conference, p.152(1998).Search in Google Scholar

2 Kashiwa, N.: Metallocenes as Promising Catalysts for New Generation of Polyolefins, CMC, Tokyo, p.25(1993).Search in Google Scholar

3 Fraser, W. A., Foster, G. N., Sagar, V. R.: Proceeding Metallocenes Europe '98, Düsseldorf, Germany(1998).Search in Google Scholar

4 Nakamura, S.: Catalysis Surveys from Japan, 2, p.107(1998).10.1023/A:1019009904613Search in Google Scholar

5 Sanden, P. V., Halle, R. W.: SPE ANTEC Tech. Papers, p.154(1992).Search in Google Scholar

6 Hatzmann, G.: Proceeding Int. Congr. Mak. Polymer, p.34(1995).Search in Google Scholar

7 Wigosky, V.: Plastic Eng.17, p.51(1995).10.1016/S0262-1762(99)80951-1Search in Google Scholar

8 Chun, P. S., Cao, C. I., Knight, G. W.: Plastic Eng.51, p.21(1995).Search in Google Scholar

9 Koch, K. C., Volkenburgh, B. V.: SPE ANTEC Tech. Papers, p.1879(1995).Search in Google Scholar

10 Han, C. D., Park, J. Y.: J. Appl. Polym. Sci., 19, p.3291(1975).Search in Google Scholar

11 Han, C. D., Shetty, R.: Ind. Eng. Chem. Fund., 16, p.49(1977).10.1021/i160061a012Search in Google Scholar

12 Kanai, T., White, J. L.: Polym. Eng. Sci., 24, p.1185(1984).10.1002/pen.760241508Search in Google Scholar

13 Minoshima, W., White, J. L.: J. Non Newt. Fluid Mech., 19, p.275(1986).Search in Google Scholar

14 Minoshima, W.: Ph. D. Dissertation, University of Tennessee, Knoxville(1983).Search in Google Scholar

15 Yamane, H., White, J. L.: Nihon Reoriji Gakkaishi, 15, p.131(1987).Search in Google Scholar

16 Shule, H., Wolff, R.: Kunststoffe, 77, p.744(1987).Search in Google Scholar

17 Utracki, L. A.: Polymer Alloys and Blends, Hanser Publishers, Munich, Vienna, New York, p.201(1989).Search in Google Scholar

18 Rohse, N., Bailey, P., Ohlsson, S.: Kunststoffe, 87, p.1374(1977).Search in Google Scholar

19 Davridis, H.: Proceeding World Polymer Congress, p.585(1999).Search in Google Scholar

Received: 2005-06-12
Accepted: 2006-01-26
Published Online: 2013-03-01
Published in Print: 2006-03-01

© 2006, Hanser Publishers, Munich

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