Home On the role of alloying elements in the formation of serrated grain boundaries in Ni-based alloys
Article
Licensed
Unlicensed Requires Authentication

On the role of alloying elements in the formation of serrated grain boundaries in Ni-based alloys

  • Mathieu Terner , Hyun-Uk Hong , Je-Hyun Lee and Baig-Gyu Choi
Published/Copyright: February 26, 2016
Become an author with De Gruyter Brill

Abstract

Ni-based model alloys were used to study the effect of alloying elements, namely Cr, Mo, C and Zr on the occurrence of grain boundary serration. The model alloys were free of aluminum to exclude precipitation of second-phase γ′. Similarly, the carbon content was very low, when present, to prevent precipitation of carbides. A special heat treatment involving slow cooling was used to promote grain boundary serration. No significant sign of serration was observed for Ni-10Cr-10Mo, Ni-20Cr-10Mo and Ni-10Cr-10Mo-0.05C model alloys. However, substantial serration was observed for Ni-10Cr-10Mo-0.5Zr and Ni-20Cr-0.5Zr model alloys. Serrated grain boundaries were observed in the absence of either γ′ or carbides. Zirconium-rich precipitates were recognized at serrated grain boundaries though their involvement in the occurrence of serration was doubtful. A mechanism of grain boundary serration formation is proposed.


*Correspondence address, Prof. Hyun-Uk Hong, Department of Materials Science and Engineering, Changwon National University, 20 Changwondaehak-ro, Uichang-gu, Changwon, Gyeongnam 641-773, Republic of Korea. Tel.: +82-55-213-3699, Fax: +82-55-261-7017, E-mail:

References

[1] J.M.Larson, S.Floreen: Metall. Trans.8A (1977) 51. 10.1007/BF02677263Search in Google Scholar

[2] H. LoyerDanflou, M.Marty, A.Walter: Superalloys (1992) 63.Search in Google Scholar

[3] J.G.Yoon, H.W.Jeong, Y.S.Yoo, H.U.Hong: Mater. Charact.10 (2015) 49. 10.1016/j.matchar.2015.01.002Search in Google Scholar

[4] A.Wisniewski, J.Beddoes: Mater. Sci. Eng. A510–511 (2009) 266. 10.1016/j.msea.2008.04.130Search in Google Scholar

[5] H.U.Hong, I.S.Kim, B.G.Choi, C.Y.Jo, Y.S.Yoo, H.W.Jeong, S.M.Seo: US Patent Application Serial No. 12/484,597 (2009).Search in Google Scholar

[6] J.W.Lee, D.J.Kim, H.U.Hong: Mater. Sci. Eng. A625 (2015) 164. 10.1016/j.msea.2014.12.010Search in Google Scholar

[7] J.L.W.Carter, N.Zhou, J.M.Sosa, P.A.Shade, A.L.Pilchak, M.W.Kuper, Y.Wang, H.L.Fraser, M.D.Uchic, M.J.Mills: Superalloys 2012: 12th International Symposium on Superalloys (2012) 43.10.1002/9781118516430.ch5Search in Google Scholar

[8] J.M.Larson: Metall. Trans.7A (1976) 1497. 10.1007/BF02656391Search in Google Scholar

[9] A.K.Koul, R.Thamburaj: Metall. Trans.16A (1985) 17. 10.1007/BF02656707Search in Google Scholar

[10] A.K.Koul, G.H.Gessinger: Acta Metall.31 (1983) 1061. 10.1016/0001-6160(83)90202-XSearch in Google Scholar

[11] H. LoyerDanflou, M.Macia, T.H.Sanders, T.Khan: Superalloys (1996) 119.Search in Google Scholar

[12] M.F.Henry, Y.S.Yoo, D.Y.Yoon, J.Choi: Metall. Trans.24A (1993) 1733. 10.1007/BF02657848Search in Google Scholar

[13] R.J.Mitchell, H.Y.Li, Z.W.Huang: J. Mater. Process. Technol.209 (2009) 1011. 10.1016/j.jmatprotec.2008.03.008Search in Google Scholar

[14] H.U.Hong, I.S.Kim, B.G.Choi, M.Y.Kim, C.Y.Jo: Mater. Sci. Eng. A517 (2009) 125. 10.1016/j.msea.2009.03.071Search in Google Scholar

[15] Y.S.Lim, D.J.Kim, S.S.Hwang, H.P.Kim, S.W.Kim: Mater. Charact.96 (2014) 28. 10.1016/j.matchar.2014.07.008Search in Google Scholar

[16] K.J.Kim, J.Ginsztler, S.W.Nam: Mater. Lett.59 (2005) 1439. 10.1016/j.matlet.2004.12.050Search in Google Scholar

[17] K.J.Kim, H.U.Hong, S.W.Nam: Mater. Chem. Phys.126 (2011) 480. 10.1016/j.matchemphys.2010.12.025Search in Google Scholar

[18] F.H.Latief, H.U.Hong, T.Blanc, I.S.Kim, B.G.Choi, C.Y.Jo, J.H.Lee: Mater. Chem. Phys.148 (2014) 1194. 10.1016/j.matchemphys.2014.09.047Search in Google Scholar

[19] H.U.Hong, S.W.Nam: Mater. Sci. Eng. A332 (2002) 255. 10.1016/S0921-5093(01)01754-3Search in Google Scholar

[20] C.L.Qiu, P.Andrews: Mater. Charact.76 (2013) 28. 10.1016/j.matchar.2012.11.012Search in Google Scholar

[21] L.Letellier, S.Chambreland, P.Duval, D.Blavette: Appl. Surf. Sci.67 (1993) 305. 10.1016/0169-4332(93)90330-ESearch in Google Scholar

[22] B.Tang, L.Jiang, R.Hu, Q.Li: Mater. Charact.78 (2013) 144. 10.1016/j.matchar.2013.02.006Search in Google Scholar

[23] L.Jiang, R.Hu, H.Kou, J.Li, G.Bai, H.Fu: Mater. Sci. Eng. A536 (2012) 37. 10.1016/j.msea.2011.11.060Search in Google Scholar

[24] H.U.Hong, H.W.Jeong, I.S.Kim, B.G.Choi, Y.S.Yoo, C.Y.Jo: Philos. Mag.92 (2012) 2809. 10.1080/14786435.2012.676212Search in Google Scholar

[25] Y.Murata, K.Suga, N.Yukawa: J. Mater. Sci.21 (1986) 3653. 10.1007/BF02403016Search in Google Scholar

[26] P.Nash, C.S.Jayanth: Bull. Alloy Phase Diagrams5 (1984) 144. 10.1007/BF02868549Search in Google Scholar

[27] J.K.Kim, B.J.Lee, B.H.Lee, Y.H.Kim, K.Y.Kim: Scr. Mater.61 (2009) 1133. 10.1016/j.scriptamat.2009.08.045Search in Google Scholar

[28] J.K.Tien, R.P.Gamble: Metall. Trans.2 (1971) 1663. 10.1007/BF02662660Search in Google Scholar

[29] H.E.Huang, C.H.Koo: Metall. Trans.45 (2004) 554.Search in Google Scholar

[30] R.C.Reed: The superalloys: fundamentals and applications, Cambridge University Press, New York (2006). 10.1017/CBO9780511541285Search in Google Scholar

[31] E.Clementi, D.L.Raimondi: J. Chem. Phys.38 (1963) 2686. 10.1063/1.1733573Search in Google Scholar

[32] X.Pan, Z.Jin: J. Mater. Sci. Technol.18 (2002) 532. 10.1179/026708302225006043Search in Google Scholar

[33] S.J.Luo, C.H.Wang, S.W.Chen: Metall. Mater. Trans.33A (2002) 995. 10.1007/s11661-002-0200-8Search in Google Scholar

[34] C.L.Fu, R.Reed, A.Janotti, M.Krcmar: Superalloys (2004) 867.Search in Google Scholar

[35] D.McLean: Grain boundaries in metals, Oxford University Press, London (1957) 124.Search in Google Scholar

[36] G.Gottstein, D.A.Molodov, L.S.Shvindlerman, D.J.Srolovitz, M.Winning: Curr. Opin. Solid State Mater. Sci.5 (2001) 9. 10.1016/S1359-0286(00)00030-9Search in Google Scholar

[37] G.Gottstein, D.A.Molodov: Interface Sci.6 (1998) 7. 10.1023/A:1008641617937Search in Google Scholar

[38] M.Winning, G.Gottstein, L.S.Shvindlerman: Acta Mater.50 (2002) 353. 10.1016/S1359-6454(01)00343-3Search in Google Scholar

Received: 2015-08-07
Accepted: 2015-10-14
Published Online: 2016-02-26
Published in Print: 2016-03-11

© 2016, Carl Hanser Verlag, München

Downloaded on 4.10.2025 from https://www.degruyterbrill.com/document/doi/10.3139/146.111332/html?lang=en
Scroll to top button