Startseite Technik Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
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Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC

Paper presented at “International Conference on Science and Engineering of Materials” (ICSEM), 6–8 January 2014, Sharda University, Greater Noida, India.
  • Prabhakar Singh Raghvendra
Veröffentlicht/Copyright: 12. Mai 2015
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 106 Heft 5

Abstract

We report our investigations on structural, thermal and electrical behavior of 10 mol.% dysprosia stabilized zirconia (DySZr) and 2 mol.% Bi2O3-doped dysprosia stabilized zirconia (2BiDySZr) prepared via a solid state ceramic route. Addition of 2 mol.% of Bi2O3 decreased the sintering temperature of DySZr, promoted the growth of zirconia grains and also improved the density. This also supports stabilizing the cubic phase at room temperature. The electrical conductivity was found to increase on account of bismuth doping in DySZr. The activation energies for conduction in DySZr and 2BiDySZr systems were found to be 1.11 and 1.15 eV, respectively in the measured temperature range, indicating the oxygen ion conductivity in the system. The thermal expansion coefficient of the Bi2O3-doped DySZr system was found to match with the other component materials for solid oxide fuel cells.

Keywords: Zirconia; Dysprosia; Bismuth oxide; SOFC; Electrical conductivity
* Correspondence address, Dr. Prabhakar Singh, Department of Physics, Indian Institute of Technology (BHU), Varanasi-221005, India, Tel.: +91-542-6701916, Fax: +91-542-2368428, E-mail:

References

[1] S.P.S.Badwal: Solid State Ionics52 (1992) 23. 10.1016/0167-2738(92)90088-7Suche in Google Scholar

[2] D.P.F.De Souza, A.L.Chinelatto, M.F.De Souza: J. Mater. Sci.30 (1995) 4355. 10.1007/BF00361517Suche in Google Scholar

[3] Y.Arachi, H.Sakai, O.Yamamoto, Y.Takeda, N.Imanishai: Solid State Ionics121 (1999) 133. 10.1016/S0167-2738(98)00540-2Suche in Google Scholar

[4] M.Hirano, T.Oda, K.Ukai, Y.Mizutani: Solid State Ionics158 (2003) 215. 10.1016/S0167-2738(02)00912-8Suche in Google Scholar

[5] Raghvendra, R.K. Singh, P.Singh: J. Alloys Compd.549 (2013) 238. 10.1016/j.jallcom.2012.09.059Suche in Google Scholar

[6] M.Pastor, S.Maiti, A.Pandey, K.Biswas, I.Manna: Mater. Chem. Phys.125 (2011) 202. 10.1016/j.matchemphys.2010.09.007Suche in Google Scholar

[7] R.Punn, A.M.Feteira, D.C.Sinclair, C.Greaves: J. Am. Chem. Soc.128 (2006) 15386. 10.1021/ja065961dSuche in Google Scholar PubMed

[8] K.Sood, K.Singh, O.P.Pandey: Ionics16 (2010) 549. 10.1007/s11581-010-0429-ySuche in Google Scholar

[9] V.Gil, C.Moure, P.Durán, J.Tartaj: Solid State Ionics178 (2007) 359. 10.1016/j.ssi.2006.10.024Suche in Google Scholar

[10] Raghvendra, P. Singh: J. Eur. Ceram. Soc.35 (2015) 1485. 10.1016/j.jeurceramsoc.2014.12.002Suche in Google Scholar

[11] I.C.Cosentino, R.Muccilo: J. Mater. Sci. Lett.12 (1993) 1022. 10.1007/BF00420205Suche in Google Scholar

[12] P.M.Abdala, M.C.A.Fantini, A.F.Craievich, D.G.Lamas: Phys. Chem. Chem. Phys.12 (2010) 2822. 10.1039/b922541bSuche in Google Scholar PubMed

[13] B.D.Cullity, S.R.Stock: Elements of X-Ray Diffraction, 3rd Ed., Prentice-Hall Inc. (2001) p. 167.Suche in Google Scholar

[14] A.K.Jonscher: Nature276 (1977) 673. 10.1038/267673a0Suche in Google Scholar

[15] P.Singh, Raghvendra, O.Parkash, D.Kumar: Phys. Rev. B84 (2011) 174306. 10.1103/PhysRevB.84.052401Suche in Google Scholar

[16] D.J.Kim: J. Am. Ceram. Soc.72 (1989) 1415. 10.1111/j.1151-2916.1989.tb07647.xSuche in Google Scholar

[17] F.Tietz: Ionics5 (1999) 129. 10.1007/BF02375916Suche in Google Scholar

Received: 2014-03-31
Accepted: 2015-01-12
Published Online: 2015-05-12
Published in Print: 2015-05-13

© 2015, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic description of the Ti–O system
  5. Influence of MgO on the phase equilibria in the CuOx–FeOy–MgO–SiO2 system in equilibrium with copper alloy – Part I: methodology and liquidus in the tridymite primary phase field
  6. Experimental phase diagram of the V–Si–Ho ternary system
  7. Experimental study of the phase relationships in the Al-rich corner of the Al–Si–Fe–Cr quaternary system at 700 °C
  8. Effect of quench–ageing treatment on the microstructure and properties of Zn-15Al-3Cu alloy
  9. Grain growth and thermal stability in nanocrystalline Fe–B alloys prepared by melt spinning
  10. Microatmosphere sintering of Fe-3.2Mn-1.5Si-0.5C steel in flowing technical nitrogen
  11. Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
  12. Effect of Mo/B atomic ratio on the properties of Mo2NiB2-based cermets
  13. Improving the stoichiometry of RF-sputtered amorphous alumina thin films by thermal annealing
  14. Assessment on the contact factors of a sandwich soft finger model – An experimental investigation
  15. Reducing debinding time in thick components fabricated by powder injection molding
  16. Short Communications
  17. Rapid synthesis of Ag nanoparticles and Ag@SiO2 core–shells
  18. Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
  19. People
  20. Prof. Dr.-Ing. Lorenz Singheiser on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
https://doi.org/10.3139/146.111204
Schlagwörter für diesen Artikel
Zirconia; Dysprosia; Bismuth oxide; SOFC; Electrical conductivity

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic description of the Ti–O system
  5. Influence of MgO on the phase equilibria in the CuOx–FeOy–MgO–SiO2 system in equilibrium with copper alloy – Part I: methodology and liquidus in the tridymite primary phase field
  6. Experimental phase diagram of the V–Si–Ho ternary system
  7. Experimental study of the phase relationships in the Al-rich corner of the Al–Si–Fe–Cr quaternary system at 700 °C
  8. Effect of quench–ageing treatment on the microstructure and properties of Zn-15Al-3Cu alloy
  9. Grain growth and thermal stability in nanocrystalline Fe–B alloys prepared by melt spinning
  10. Microatmosphere sintering of Fe-3.2Mn-1.5Si-0.5C steel in flowing technical nitrogen
  11. Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
  12. Effect of Mo/B atomic ratio on the properties of Mo2NiB2-based cermets
  13. Improving the stoichiometry of RF-sputtered amorphous alumina thin films by thermal annealing
  14. Assessment on the contact factors of a sandwich soft finger model – An experimental investigation
  15. Reducing debinding time in thick components fabricated by powder injection molding
  16. Short Communications
  17. Rapid synthesis of Ag nanoparticles and Ag@SiO2 core–shells
  18. Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
  19. People
  20. Prof. Dr.-Ing. Lorenz Singheiser on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
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