Home A thermodynamic description of the Ce–La–Mg system
Article
Licensed
Unlicensed Requires Authentication

A thermodynamic description of the Ce–La–Mg system

  • Cuiping Guo , Zhenmin Du and Changrong Li
Published/Copyright: June 11, 2013
Become an author with De Gruyter Brill
Author Information
International Journal of Materials Research
From the journal International Journal of Materials Research Volume 101 Issue 11

Abstract

The thermodynamic optimization of the Ce–La and Ce–La–Mg systems has been carried out using the CALPHAD technique. The solution phases (liquid, bcc, fcc, hcp and dhcp) were described with a substitutional solution model. The isostructural compounds MgCe in the Ce–Mg system and MgLa in the La–Mg system with B2 structure form a continuous range of solid solution in the Ce–La–Mg system. The order–disorder transition between the solutions with A2 structure and compounds with B2 structure in the system has been taken into account and thermodynamically modeled. The other isostructural compounds Mg12Ce and Mg12La, Mg17Ce2 and Mg17La2, Mg41Ce5 and Mg41La5, Mg3Ce and Mg3La, and Mg2Ce and Mg2La were described as such formula Mg12(Ce, La), Mg17(Ce, La)2, Mg41(Ce, La)5, Mg3(Ce, La, Mg), Mg2(Ce, La), respectively. A set of self-consistent thermodynamic description of the Ce–La–Mg system was obtained.

Keywords: Thermodynamic modeling; CALPHAD technique; Ce–La–Mg system; Order–disorder transition

References

[1] G.Cacciamani, G.Borzone, R.Ferro, in: I.Ansara, A. T.Dinsdale, M. H.Rand, (Eds.), COST507, Thermochemical database for light metal alloys, European Commission, Luxembourg (1998) 137–140.Search in Google Scholar

[2] C.Guo, Z.Du: Int. J. Mater. Res.99 (2008) 650–668.10.3139/146.101685Search in Google Scholar

[3] C.Guo, Z.Du: J. Alloys Compd.385 (2004) 109–113. 10.1016/j.jallcom.2004.04.105Search in Google Scholar

[4] Z.Du, C.Guo, C.Li, W.Zhang: Rare Metals25 (2006) 492–500. 10.1016/S1001-0521(06)60090-9Search in Google Scholar

[5] R.Vogel, H.Klose: Z. Metallkd.45 (1954) 633–638.Search in Google Scholar

[6] E. M.Savitskii, V. F.Terekhova: Zhur. Neorg. Khim.3 (1958) 756.Search in Google Scholar

[7] V. F.Terekhova: Metalloved. Term. Obrab. Metal.8 (1963) 47.Search in Google Scholar

[8] K. A.GschneidnerJr., F. W.Calderwood: Bull. Alloy Phase Diagrams2 (1982) 445–447. 10.1007/BF02876156Search in Google Scholar

[9] L. M.Roberts, J. M.Lock: Philos. Mag.2 (1957) 811. 10.1080/14786435708241032Search in Google Scholar

[10] E. I.Nikulin, Y. B.Patrikeev: Fiz. Tverd. Tela13 (1971) 1824.Search in Google Scholar

[11] H. V.Culbert, A. S.Edelstein: Solid State Comm.15 (1974) 1633. 10.1016/0038-1098(74)91200-9Search in Google Scholar

[12] L. L.Rokhlin, N. R.Bochvar: Izv. Akad. Nauk SSSR, Metally2 (1972) 193–197.Search in Google Scholar

[13] G. V.Raynor: Int. Met. Rev.22 (1977) 65–90.10.1179/095066077791100507Search in Google Scholar

[14] N.Bochvar, Y.Liberov, in: G.Effenberg, F.Aldinger, P.Rogl, (Eds.), Ternary Alloys, A Comprehensive Compendium of Evaluated Consitutional Data and Phase Diagrams, MSI, Stuttgart, Vol. 17 (2000) 135–141.Search in Google Scholar

[15] A. A.Nayeb-Hashemi, J. B.Clark: Bull. Alloys Phase Diagrams9 (1988) 162–172.10.1007/BF02890557Search in Google Scholar

[16] A. A.Nayeb-Hashemi, J. B.Clark: Bull. Alloys Phase Diagrams9 (1988) 172–178.10.1007/BF02890558Search in Google Scholar

[17] A. T.Dinsdale: SGTE pure elements (unary) database, Version 4.5 (2006).Search in Google Scholar

[18] I.Ansara, N.Dupin, H. L.Lukas, B.Sundman: J. Alloys Comp.247 (1997) 20–30. 10.1016/S0925-8388(96)02652-7Search in Google Scholar

[19] Y.Kang, A. D.Pelton, P.Chartrand, P.Spencer, C. D.Fuerst: J. Phase Equili. Diff.28 (2007) 342–354. 10.1007/s11669-007-9095-9Search in Google Scholar

[20] A.Saccone, D.Macciò, S.Delfino, F. H.Hayes, R.Ferro: J. Thermal Analysis and Calorimetry66 (2001) 47–57. 10.1023/A:1012427429404Search in Google Scholar

[21] B.Sundman, B.Jansson, J-O.Andersson: Calphad9 (1985) 153–190. 10.1016/0364-5916(85)90021-5Search in Google Scholar

[22] M.Giovannini, A.Saccone, R.Marazza, R.Ferro: Metal. Mater. Trans. A26 (1995) 5–10. 10.1007/BF02669789Search in Google Scholar

Received: 2009-3-31
Accepted: 2010-1-8
Published Online: 2013-06-11
Published in Print: 2010-11-01

© 2010, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. 2nd Sino-German Symposium on Computational Thermodynamics and Kinetics and their Applications to Solidification
  5. Basic
  6. Multiscale simulations on the grain growth process in nanostructured materials
  7. Thermodynamic re-modeling of the Co–Gd system
  8. Microstructure and tribological properties of in-situ Y2O3/Ti-5Si alloy composites
  9. Phase relations in the ZrO2–Nd2O3–Y2O3 system: experimental study and CALPHAD assessment
  10. Phase transition in nanocrystalline iron: Atomistic-level simulations
  11. Thermodynamic assessment of the Cr–Al–Nb system
  12. Experimental investigation and thermodynamic modeling of the Cu–Mn–Zn system
  13. Elastic constants and thermophysical properties of Al–Mg–Si alloys from first-principles calculations
  14. Predicting microsegregation in multicomponent aluminum alloys – progress in thermodynamic consistency
  15. Phase reaction of ceria in LPS–SiC with Al2O3–Y2O3 and AlN–Y2O3 additives
  16. Applied
  17. Phase equilibria in the Fe–Ti–V system
  18. A thermodynamic description of the Ce–La–Mg system
  19. Molar volume calculation of Ga–Bi–X (X=Sn, In) liquid alloys using the general solution model
  20. Microstructural analysis in the vacuum brazing of copper to copper using a phosphor–copper brazing filler metal
  21. Microstructural development of the hot extruded magnesium alloy AZ31 under cyclic testing conditions
  22. DGM News
  23. DGM News
https://doi.org/10.3139/146.110380
Keywords for this article
Thermodynamic modeling; CALPHAD technique; Ce–La–Mg system; Order–disorder transition

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. 2nd Sino-German Symposium on Computational Thermodynamics and Kinetics and their Applications to Solidification
  5. Basic
  6. Multiscale simulations on the grain growth process in nanostructured materials
  7. Thermodynamic re-modeling of the Co–Gd system
  8. Microstructure and tribological properties of in-situ Y2O3/Ti-5Si alloy composites
  9. Phase relations in the ZrO2–Nd2O3–Y2O3 system: experimental study and CALPHAD assessment
  10. Phase transition in nanocrystalline iron: Atomistic-level simulations
  11. Thermodynamic assessment of the Cr–Al–Nb system
  12. Experimental investigation and thermodynamic modeling of the Cu–Mn–Zn system
  13. Elastic constants and thermophysical properties of Al–Mg–Si alloys from first-principles calculations
  14. Predicting microsegregation in multicomponent aluminum alloys – progress in thermodynamic consistency
  15. Phase reaction of ceria in LPS–SiC with Al2O3–Y2O3 and AlN–Y2O3 additives
  16. Applied
  17. Phase equilibria in the Fe–Ti–V system
  18. A thermodynamic description of the Ce–La–Mg system
  19. Molar volume calculation of Ga–Bi–X (X=Sn, In) liquid alloys using the general solution model
  20. Microstructural analysis in the vacuum brazing of copper to copper using a phosphor–copper brazing filler metal
  21. Microstructural development of the hot extruded magnesium alloy AZ31 under cyclic testing conditions
  22. DGM News
  23. DGM News
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 16.11.2025 from https://www.degruyterbrill.com/document/doi/10.3139/146.110380/pdf
Scroll to top button