Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate
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Xiaojun Zeng
Abstract
Three polysiloxane bola surfactants containing carbohydrate (ATPS-LA) were synthesized using a two-step method. Structure characterization was performed by infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy (1H NMR). Their surface activities and aggregation properties in aqueous solution were investigated by surface tension measurements and transmission electron microscopy (TEM). The results indicated that these three surfactants have much higher surface activity than those of conventional hydrocarbon bola surfactants, such as sodium eicosanedioate, in aqueous solution, and they can self-assemble into spherical micelles with average diameters in the range from 100 to 600 nm.
Kurzfassung
Drei Polysiloxan-Bolatenside, die Kohlenhydrate enthalten (ATPS-LA) wurden synthetisiert in einem Zweistufenverfahren. Für die Strukturcharakterisierung wurden die FT-IR-Spektroskopie und die 1H-NMR herangezogen. Ihre Oberflächen- und Aggregationseigenschaften wurden mit Hilfe von Messungen der Oberflächenspannung und der Transmissionselektronenmikroskopie (TEM) untersucht. Die Ergebnisse machen deutlich, dass diese drei Tenside eine sehr viel höhere Oberflächenaktivität in wässriger Lösung aufweisen als die konventionellen Kohlenwasserstoff-Bolatenside wie z.B. Natriumeicosandioat. Des Weiteren sind sie imstande, sich in Kugelmizellen mit durchschnittlichen Durchmessern zwischen 100 nm bis 600 nm zu organisieren.
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© 2014, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Special Theme: Green Surfactants – Synthesis, Properties, Performance and Application
- Novel Cationic Gemini Surfactants and Methods for Determination of Their Antimicrobial Activity – Review
- Sophorolipids Synthesized Using Non-Traditional Oils with Glycerol and Studies on Their Surfactant Properties with Synthetic Surfactant
- Rhamnolipids Production by a Pseudomonas eruginosa LBI Mutant: Solutions and Homologs Characterization
- Application of Biosurfactant Surfactin on Copper Ion Removal from Sand Surfaces with Continuous Flushing Technique
- Synthesis and Properties of a Series of CO2 Switchable Gemini Imidazolium Surfactants
- Phase Behavior and Solubilization of Microemulsion Systems Containing Imidazolium Type Surfactant CnmimBr and Butyric Acid as Cosurfactant
- Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate
- Syntheses and Properties of Novel Ionic Twin-tail Trisiloxane Surfactants
- Micellar Encapsulation of Some Polycyclic Aromatic Hydrocarbons by Glucose Derived Non-Ionic Gemini Surfactants in Aqueous Medium
- Environmental Chemistry
- Removal of Non-Ionic Surfactants in an Activated Sludge Sewage Treatment Plant
- Cleaning Technology
- Impact of Artificial UV-Light on Optical and Protective Effects of Cotton After Washing with Detergent Containing Fluorescent Compounds
- Simulating Consumer-Like Air Drying of Dishes via Thermal Drying Process
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Special Theme: Green Surfactants – Synthesis, Properties, Performance and Application
- Novel Cationic Gemini Surfactants and Methods for Determination of Their Antimicrobial Activity – Review
- Sophorolipids Synthesized Using Non-Traditional Oils with Glycerol and Studies on Their Surfactant Properties with Synthetic Surfactant
- Rhamnolipids Production by a Pseudomonas eruginosa LBI Mutant: Solutions and Homologs Characterization
- Application of Biosurfactant Surfactin on Copper Ion Removal from Sand Surfaces with Continuous Flushing Technique
- Synthesis and Properties of a Series of CO2 Switchable Gemini Imidazolium Surfactants
- Phase Behavior and Solubilization of Microemulsion Systems Containing Imidazolium Type Surfactant CnmimBr and Butyric Acid as Cosurfactant
- Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate
- Syntheses and Properties of Novel Ionic Twin-tail Trisiloxane Surfactants
- Micellar Encapsulation of Some Polycyclic Aromatic Hydrocarbons by Glucose Derived Non-Ionic Gemini Surfactants in Aqueous Medium
- Environmental Chemistry
- Removal of Non-Ionic Surfactants in an Activated Sludge Sewage Treatment Plant
- Cleaning Technology
- Impact of Artificial UV-Light on Optical and Protective Effects of Cotton After Washing with Detergent Containing Fluorescent Compounds
- Simulating Consumer-Like Air Drying of Dishes via Thermal Drying Process
