Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials
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Xiaofen Xu
Abstract
Quaternary ammonium surfactants 3a–d, with diether linkages in the backbone between hydrocarbon chains and the ammonium head groups, were synthesized as potential soft-template agents for the preparation of mesoporous materials. Varying the length of their carbon chains was expected to control the pore sizes of the corresponding mesoporous materials prepared. The critical micelle concentration (CMC) and γcmc (surface tension of the CMC) of these surfactants were measured by surface tension method.
Kurzfassung
Die quaternären Ammoniumtenside 3a–d mit einer Dietherverknüpfung im Gerüst zwischen der Kohlenstoffkette und den Ammoniumkopfgruppen wurde als potenzielle Soft-Template-Mittel für die Herstellung von mesoporösen Materialien synthetisiert. Es wurde angenommen, dass man über die Variation ihrer Kohlenstoffkettenlänge die Porengröße des damit hergestellten mesoporösen Materials kontrollieren kann. Die kritische Mizellenbildungkonzentration (CMC) und die Oberflächenspannung an der CMC (γCMC) dieser Tenside wurden mit einer Oberflächenspannungsmethode bestimmt.
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© 2014, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Application
- Inactivation of Human Norovirus by Common Domestic Laundry Procedures
- Dispersion of Bioactive Glass using Cetyltrimethylammonium Bromide
- Novel/“Green” Surfactants
- Amphiphilic Choline Carboxylates as Demulsifiers of Water-in-Crude Oil Emulsions
- Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co(II), Cu(II), or Sn(II) Chlorides
- Micellar Chemistry
- Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room Temperature
- Physical Chemistry
- Cloud Point Extraction of Polycyclic Aromatic Hydrocarbons in Aqueous Solution with Nonionic Surfactants
- Influence of Alcohols on Micellar and Release Balances of Cationic Surfactant – Carbethopendecinium Bromide (Septonex)
- Synthesis
- Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials
- The Role of Surface Active Agents in Sulfonation of Double Bonds
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Application
- Inactivation of Human Norovirus by Common Domestic Laundry Procedures
- Dispersion of Bioactive Glass using Cetyltrimethylammonium Bromide
- Novel/“Green” Surfactants
- Amphiphilic Choline Carboxylates as Demulsifiers of Water-in-Crude Oil Emulsions
- Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co(II), Cu(II), or Sn(II) Chlorides
- Micellar Chemistry
- Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room Temperature
- Physical Chemistry
- Cloud Point Extraction of Polycyclic Aromatic Hydrocarbons in Aqueous Solution with Nonionic Surfactants
- Influence of Alcohols on Micellar and Release Balances of Cationic Surfactant – Carbethopendecinium Bromide (Septonex)
- Synthesis
- Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials
- The Role of Surface Active Agents in Sulfonation of Double Bonds
