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Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials

  • Xiaofen Xu , Dongliang Liu and Daoping He
Published/Copyright: July 22, 2014
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 51 Issue 4

Abstract

Quaternary ammonium surfactants 3a–d, with diether linkages in the backbone between hydrocarbon chains and the ammonium head groups, were synthesized as potential soft-template agents for the preparation of mesoporous materials. Varying the length of their carbon chains was expected to control the pore sizes of the corresponding mesoporous materials prepared. The critical micelle concentration (CMC) and γcmc (surface tension of the CMC) of these surfactants were measured by surface tension method.

Kurzfassung

Die quaternären Ammoniumtenside 3a–d mit einer Dietherverknüpfung im Gerüst zwischen der Kohlenstoffkette und den Ammoniumkopfgruppen wurde als potenzielle Soft-Template-Mittel für die Herstellung von mesoporösen Materialien synthetisiert. Es wurde angenommen, dass man über die Variation ihrer Kohlenstoffkettenlänge die Porengröße des damit hergestellten mesoporösen Materials kontrollieren kann. Die kritische Mizellenbildungkonzentration (CMC) und die Oberflächenspannung an der CMC (γCMC) dieser Tenside wurden mit einer Oberflächenspannungsmethode bestimmt.

Key words: Soft-template Agents; diether-linked; mesoporous materials; cationic surfactants
Stichwörter: Soft-Template-Mittel; Dietherverknüpfung; mesoporöses Material; kationische Tenside
* Correspondence address Mr. Dr Dongliang Liu, Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Department of Applied Chemistry, Donghua University, 2999 North Renmin RD, Shanghai, 201620, P.R. China, E-Mail:

Xiaofen Xu was born in 1988. She obtained her Bachelor's Degree from Anhui University of Science & Technology in 2011. She is now taking a master's degree in the synthesis and physical chemistry of surfactants and catalyst preparation at Donghua University.

Dongliang Liu was born in 1974. He obtained a Bachelor's Degree from Dalian University of Technology in 1997 and a Ph.D. from the same university in 2006. Since 2006, He has been teaching and working at Donghua University. His main field of research are organic synthesis and industrial catalysis.

Daoping He was born in 1990. He obtained his Bachelor’ Degree from Anhui Polytechnic University in 2012. He is now taking a master's degree in the synthesis and physical chemistry of surfactants and catalyst preparation at Donghua University.

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Received: 2013-09-02
Revised: 2014-01-30
Published Online: 2014-07-22
Published in Print: 2014-07-15

© 2014, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110309
Keywords for this article
Soft-template Agents; diether-linked; mesoporous materials; cationic surfactants

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Inactivation of Human Norovirus by Common Domestic Laundry Procedures
  7. Dispersion of Bioactive Glass using Cetyltrimethylammonium Bromide
  8. Novel/“Green” Surfactants
  9. Amphiphilic Choline Carboxylates as Demulsifiers of Water-in-Crude Oil Emulsions
  10. Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co(II), Cu(II), or Sn(II) Chlorides
  11. Micellar Chemistry
  12. Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room Temperature
  13. Physical Chemistry
  14. Cloud Point Extraction of Polycyclic Aromatic Hydrocarbons in Aqueous Solution with Nonionic Surfactants
  15. Influence of Alcohols on Micellar and Release Balances of Cationic Surfactant – Carbethopendecinium Bromide (Septonex)
  16. Synthesis
  17. Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials
  18. The Role of Surface Active Agents in Sulfonation of Double Bonds
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