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Wetting Ability in Aqueous Mixtures of Amine Oxide with Anionic and Nonionic Surfactants

  • Ruitao Wang and Yunling Li
Published/Copyright: May 1, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 51 Issue 3

Abstract

The wetting abilities of amine oxide surfactants (dodecyl dimethylamine oxide, DDMAO and dihydroxyethyl dodecylamine oxide, DDEAO), alcohol ether sulfate (AES), ethoxylated alcohols with different number of ethylene oxide units (AEOn, n = 3, 5, 7, 9) and mixtures of amine oxides with AES and AEOn were measured according to the canvas descending method. The effect of surfactant concentration, surfactant type, number of ethylene oxide unit and temperature on the wetting ability of mixed systems has been analyzed. The results show that the wetting abilities of DDEAO and DDMAO are better than those of AES, AEO9 and AEO3, and similar to those of AEO5 and AEO7. For all mixed systems, the optimum wetting ability appears at equal weight mixtures in the weight ratio range investigated. These mixtures show a synergistic effect. Higher temperatures imply higher wetting ability in aqueous mixtures of DDMAO with AES and AEO3 at weight ratio = 1 : 1.

Kurzfassung

Das Benetzungsvermögen von Aminoxidtensiden (Dodecyldimethylaminoxid (DDMAO) und Dihydroxyethyldodecylaminoxid (DDEAO)), von Alkoholethersulfat (AES), ethoxilierten Alkoholen mit unterschiedlicher Anzahl an Ethylenoxideinheiten (AEOn, n = 3, 5, 7, 9) sowie von Mischungen aus Aminoxiden mit AES und AEOn wurde mit der Leinwandabsinkmethode gemessen. Der Einfluss der Tensidkonzentrationen, der Tensidart, der Anzahl der EO-Einheiten und der Temperatur auf das Benetzungsvermögen der Mischungen wurde analysiert. Die Ergebnisse zeigen, dass das Benetzungsvermögen von DDMAO und DDEAO besser ist als das von AES, AEO9 und AEO3. Dem von AEO5 und AEO7 ist es ähnlich. Bei allen Mischsystemen tritt im untersuchten Mischungsbereich bei gleichen Massenanteilen in der Mischung eine optimale Benetzung auf. Die Mischungen zeigten einen synergistischen Effekt. Höhere Temperaturen bedeuten ein höheres Benetzungsvermögen für Mischungen aus DDMAO und AES bzw. AEO3 bei einem Mischungsverhältnis von 1 : 1.

Key words: Wetting ability; amine oxides; alcohol ether sulfate; ethoxylated alcohols
Stichwörter: Benetzungsvermögen; Aminoxid; Alkoholethersulfat; ethoxilierte Alkohole
* Correspondence address Mr. Yunling Li, 34# Wenyuan Str. Taiyuan, Shanxi Province, 030001, P. R. China, Tel.: 0 86-03 51-4 04 68 27, Fax: 0 86-03 51-4 04 08 02, E-Mail:

Ruitao Wang received a B. Sc. in chemical engineering and technology from Baoji university of arts and sciences, P. R. China in 2011 and is currently an M. Sc. Student in Applied Chemistry, China Research Institute of Daily Chemical Industry, P. R. China. He is involved in synthesis and applications of surfactants.

Yunling Li received a Ph. D in Applied Chemistry from the Shanxi University, P. R. China and is currently a professor of engineering in the China Research Institute of Daily Chemical Industry, P. R. China. Her research interests include surfactants and industrial catalysis.

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Received: 2013-08-07
Revised: 2013-09-16
Published Online: 2013-05-01
Published in Print: 2014-05-15

© 2014, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110302
Keywords for this article
Wetting ability; amine oxides; alcohol ether sulfate; ethoxylated alcohols

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Review Article
  6. Arginine Based Novel Cationic Surfactants: A Review
  7. Application
  8. Selection of Surfactants on the Basis of Foam and Emulsion Properties to Obtain the Fire Fighting Foam and the Degreasing Agent
  9. Negative Synergistic Effect on Foaming in Body Care Products with Silicone Oil and the Needle-Like Crystal of Ethylene Glycol Distearate
  10. Technical Chemistry
  11. Wetting Ability in Aqueous Mixtures of Amine Oxide with Anionic and Nonionic Surfactants
  12. Environmental Chemistry
  13. Validation of an HPLC Method for Determining log Pow Values of Surfactants
  14. Removal of Lead From Aqueous Media Using Carbonized and Acid Treated Orange Peel
  15. Corrosion and Scale Inhibition Properties by Phosphate-free and Nitrogen-free Scale Inhibitor in Cooling Water System
  16. Preparation and Application of Fluorescent-tagged Inhibitor for Calcium Phosphate and Iron(III) Hydroxide Scales in Industrial Cooling Water Systems
  17. Novel Surfactants
  18. Effect of Tuned Head Polarity of Cetyl Trimethyl Ammonium Bromide on their Physicochemical Properties
  19. Physical Chemistry
  20. Aggregation Behavior of PEO-PPO-PEO Tri-Block Copolymer (Pluronic®L64) in Nonionic Surfactant Additives Environment
  21. Surfactant Processing
  22. Solidification of Surfactants and Detergents to Dust-Free Free Flowing Pastilles
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