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Efficiency Boosting in Technical Grade Sugar Surfactant Based Microemulsions Using Pluronics

  • Sebastian Hoehn , Christoph Schulreich und Thomas Hellweg
Veröffentlicht/Copyright: 1. Mai 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 51 Heft 1

Abstract

The high amount of surfactant needed to formulate a bicontinuous microemulsion is a limiting factor for industrial usage of these systems. Commercially available triblock copolymers can be obtained in high amounts. Here, we show the influence of size and composition of different poly(ethyleneoxide)-poly(propyleneoxide)-poly(ethyleneoxide) triblock copolymer surfactants (Pluronics) on a technical grade sugar surfactant microemulsion. The so-called efficiency boosting can also be realized in such technical grade systems. The resulting efficiency boosting is studied systematically with regard to the impact of the polymer size and the composition of the system.

Kurzfassung

Häufig steht der industriellen Nutzung von Mikroemulsionen der hohe Bedarf an Tensid im Wege, der zur Ausbildung stabiler bikontinuierlicher Mikroemulsionen notwendig ist. Kommerziell erhältliche Triblockcopolymere stehen in großen Mengen zur Verfügung. In dieser Arbeit wird der Einfluss verschiedener Pluronic Triblockcopolymere auf das Phasenverhalten einer auf technischen Zuckertensiden basierenden Mikroemulsion gezeigt. In solchen technischen Systemen kann eine sog. Effizienzsteigerung erzielt werden. Die auftretende Effizienzsteigerung der Tenside wird systematisch auf den Einfluss der Polymergröße und Zusammensetzung des Systems hin untersucht.

Key words: Pluronic; block copolymers; microemulsion; efficiency boosting; sugar surfactant
Stichwörter: Pluronic; Blockcopolymere; Mikroemulsion; Effizienzsteigerung; Zuckertensid
Correspondence address Prof. Dr. Thomas Hellweg, Universität Bielefeld, Fakultät für Chemie, Physikalische und Biophysikalische Chemie (PC III), Universitätsstr. 25, 33615 Bielefeld, Germany, Tel.: +4 95 21-1 06-68 88, E-Mail:

Sebastian Hoehn studied chemistry and received his diploma from Friedrich Alexander University Erlangen-Nürnberg in 2009. Also in 2009 he started to work on his PhD thesis in the Hellweg group at Bayreuth University.

Christoph Schulreich studied chemistry and biology to become a teacher for secondary schools and received his first degree from Bayreuth University in 2011. In 2011 he started to work on his PhD thesis in the Hellweg group at Bielefeld University.

Thomas Hellweg received his diploma in chemistry from Bielefeld University in 1991 and finished his PhD in 1995 at the same university in the group of T. Dorfmüller. From 1996 to 1998 he was a postdoctoral fellow at the CRPP in Bordeaux in the groups of D. Langevin and D. Roux. In 1998 he started his habilitation at the TU Chemnitz in the physics department. In 2001 he moved to the Technical University of Berlin, where he finished his habilitation in 2005 at the Iwan-N.-Stranski-Laboratory. From 2007 to 2010 he has been professor for physical and colloid chemistry at the University of Bayreuth. Since October 2010 he has the chair for physical and biophysical chemistry at Bielefeld University. He is elected member and vice-chairman of the German committee for neutron research.

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Received: 2013-07-26
Accepted: 2013-10-27
Published Online: 2013-05-01
Published in Print: 2014-01-20

© 2014, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Enhancing the Surface Properties of Some Amine Alginate Salts with Cationic Surfactant
  7. Method Development
  8. Transmission Measurements as Tool to Study Phase Transitions of Liquid Mixtures
  9. Novel Surfactant
  10. Synthesis and Surface Active Properties of Dimeric Gemini Sulfonate Surfactants
  11. Physical Chemistry
  12. Efficiency Boosting in Technical Grade Sugar Surfactant Based Microemulsions Using Pluronics
  13. Impact of Surfactants on the Performance of “Green Additives” as Calcium Carbonate Inhibitors for Aqueous Systems
  14. Study of Surfactant (Benzyldimethylhexadecylammonium Chloride) Effect on Selected Properties of Hydrogels
  15. Physicochemical Properties of Quaternary Ammonium Surfactants with Hydroxyethyl Groups
  16. Environmental Chemistry
  17. Removal of Basic Red 5 on Calcined Kaolinite – Characterization and Adsorption Kinetics
  18. Conference and Meeting Report
  19. Emulsions and Dispersions, Trends in Detergency, Cleaning and Hygiene, Sustainability and Product Safety, Forum for Innovations
https://doi.org/10.3139/113.110283
Schlagwörter für diesen Artikel
Pluronic; block copolymers; microemulsion; efficiency boosting; sugar surfactant

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Enhancing the Surface Properties of Some Amine Alginate Salts with Cationic Surfactant
  7. Method Development
  8. Transmission Measurements as Tool to Study Phase Transitions of Liquid Mixtures
  9. Novel Surfactant
  10. Synthesis and Surface Active Properties of Dimeric Gemini Sulfonate Surfactants
  11. Physical Chemistry
  12. Efficiency Boosting in Technical Grade Sugar Surfactant Based Microemulsions Using Pluronics
  13. Impact of Surfactants on the Performance of “Green Additives” as Calcium Carbonate Inhibitors for Aqueous Systems
  14. Study of Surfactant (Benzyldimethylhexadecylammonium Chloride) Effect on Selected Properties of Hydrogels
  15. Physicochemical Properties of Quaternary Ammonium Surfactants with Hydroxyethyl Groups
  16. Environmental Chemistry
  17. Removal of Basic Red 5 on Calcined Kaolinite – Characterization and Adsorption Kinetics
  18. Conference and Meeting Report
  19. Emulsions and Dispersions, Trends in Detergency, Cleaning and Hygiene, Sustainability and Product Safety, Forum for Innovations
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