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Natural occurrence of keatite precipitates in UHP clinopyroxene from the Kokchetav Massif: A TEM investigation
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Tina R. Hill
Published/Copyright:
March 7, 2015
Abstract
We report the first natural occurrence of keatite, also known as silica K, discovered as a precipitate in the core of ultrahigh-pressure (UHP) clinopyroxene (Cpx) within garnet pyroxenite from the Kokchetav Massif, Kazakhstan. High-resolution transmission electron microscopy and electron diffraction demonstrate that sub-micrometer and nano-scale keatite precipitates have a definite crystallographic relationship with the host pyroxene (diopside = ~Di90) Cpx (100) || keatite (100) and Cpx (010) || keatite (001). Clinopyroxene provides a template for keatite nucleation due to the close structural relationship and excellent lattice match between the diopside and keatite. We propose that keatite micro-precipitates are formed in localized low-pressure micro-environments produced as a result of exsolution of extra silica and vacancies held within UHP host diopside and stabilized by the pyroxene lattice. Low-density metastable keatite and its relationship to the host pyroxene likely reflects the important influence of pyroxene/precipitate interfacial energy on the micro- and nano-scales in controlling the nature of exsolved phases in exhumed UHP minerals.
Received: 2012-3-8
Accepted: 2012-8-14
Published Online: 2015-3-7
Published in Print: 2013-1-1
© 2015 by Walter de Gruyter Berlin/Boston
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Keywords for this article
HRTEM;
ultrahigh pressure (UHP);
diopside;
keatite;
silica exsolution;
epitaxial growth
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