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Crystal structure and iron topochemistry of erionite-K from Rome, Oregon, U.S.A.
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Paolo Ballirano
Published/Copyright:
April 1, 2015
Abstract
A complete crystal-chemical characterization of erionite-K from Rome, Oregon, was obtained by combining field emission scanning electron microscopy, laboratory parallel-beam transmission powder diffraction, and 57Fe Mössbauer spectroscopy. Rietveld refinement results evidenced that the most striking difference in comparison with the structure of erionite-Ca is significant K at a K2 site (½, 0, 0), which is empty in erionite-Ca. In addition, site Ca1 shows low occupancy and Ca3 is vacant. The oxidation and coordination state of Fe, whose occurrence was revealed by chemical analysis, have been clarified by exploiting room- and low-temperature 57Fe Mössbauer spectroscopy. The majority of Fe (95%) was attributed to Fe3+-bearing, superparamagnetic, oxide-like nanoparticles with dimensions between 1 and 9 nm, and the remaining 5% was attributed to hematite particles with size ≥10 nm, both located on the crystal surface.
Keywords : Oregon erionite; erionite-K; crystal structure; iron topochemistry; field emission; scanning electron microscopy; laboratory parallel-beam transmission powder diffraction; Rietveld refinement; 57Fe Mössbauer spectroscopy
Received: 2008-12-3
Accepted: 2009-4-27
Published Online: 2015-4-1
Published in Print: 2009-8-1
© 2015 by Walter de Gruyter Berlin/Boston
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