Article
Licensed
Unlicensed
Requires Authentication
An experimental study of trace-element partitioning between Ti-Al-clinopyroxene and melt: Equilibrium and kinetic effects including sector zoning
-
Gary E. Lofgren
,
Gary R. Huss
Published/Copyright:
March 31, 2015
Abstract
Equilibrium and dynamic crystallization experiments were used to determine distribution coefficients (D-values) for the REE and the trace elements Sc, V, Rb, Sr, Y, Zr, Nb, Ba, Hf, Th, and U between Ti-Al-clinopyroxene and melt. Equilibrium values for D correlate well with previous studies where values have been determined. The D-values were also studied as a function of cooling rate. Increased cooling rates produce higher growth rates. At growth rates that exceed the diffusion rates in the crystals, the D-values increase to near unity and the HREE D-values exceed unity only at the most rapid crystal growth rates. The increase in D-values is the result of the inclusion of components into the growing pyroxene from the boundary layer that develops at the crystal-melt interface because of the disparity between the growth and diffusion rates. The origin of sector zoning is best explained as an interplay of primarily crystallographic control with kinetic effects.
Keywords: Partitioning of trace elements; clinopyroxene-melt; equilibrium experiments; rare earth elements; dynamic crystallization experiments; distribution coefficients
Received: 2005-9-28
Accepted: 2006-4-5
Published Online: 2015-3-31
Published in Print: 2006-10-1
© 2015 by Walter de Gruyter Berlin/Boston
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Orbicular oxides in carbonatitic kimberlites
- Fluid-mediated polymetamorphism related to Proterozoic collision of Archean Wyoming and Superior provinces in the Black Hills, South Dakota
- Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota
- Identifying the effects of petrologic processes in a closed basaltic system using trace- element concentrations in olivines and glasses: Implications for comparative planetology
- Tectonic implications of diverse igneous blocks in Franciscan mélange, Northern California and southwestern Oregon
- The petrogenesis of the Apollo 14 high-Al mare basalts
- Experimental insights on crystal chemistry of high-Ti garnets from garnet-melt partitioning of rare-earth and high-field-strength elements
- The atomic arrangement of merrillite from the Fra Mauro Formation, Apollo 14 lunar mission: The first structure of merrillite from the Moon
- The behavior of Li and B in lunar mare basalts during crystallization, shock, and thermal metamorphism: Implications for volatile element contents of martian basalts
- Pyroxene europium valence oxybarometer: Effects of pyroxene composition, melt composition, and crystallization kinetics
- Comparative planetary mineralogy: Pyroxene major- and minor-element chemistry and partitioning of vanadium between pyroxene and melt in planetary basalts
- Crystal chemistry of lunar merrillite and comparison to other meteoritic and planetary suites of whitlockite and merrillite
- An experimental study of trace-element partitioning between Ti-Al-clinopyroxene and melt: Equilibrium and kinetic effects including sector zoning
- Minor- and trace-element sector zoning in synthetic enstatite
- Insights into the redox history of the NWA 1068/1110 martian basalt from mineral equilibria and vanadium oxybarometry
- Transformations of Mg- and Ca-sulfate hydrates in Mars regolith
- An experimental study of the oxidation state of vanadium in spinel and basaltic melt with implications for the origin of planetary basalt
- Valence state partitioning of vanadium between olivine-liquid: Estimates of the oxygen fugacity of Y980459 and application to other olivine-phyric martian basalts
- Identification of relict forsterite grains in forsterite-rich chondrules from the Mokoia CV3 carbonaceous chondrite
- Formation of spinel-, hibonite-rich inclusions found in CM2 carbonaceous chondrites
- Deep metastable eutectic condensation in Al-Fe-SiO-H2-O2 vapors: Implications for natural Fe-aluminosilicates
- α-PbO2-type nanophase of TiO2 from coesite-bearing eclogite in the Dabie Mountains, China–Comment
- α-PbO2-type nanophase of TiO2 from coesite-bearing eclogite in the Dabie Mountains, China–Reply
- Rietveld structure refinement of perovskite and post-perovskite phases of NaMgF3 (Neighborite) at high pressures
- Letter. Si vacancies in the 10-Å phase
Articles in the same Issue
- Orbicular oxides in carbonatitic kimberlites
- Fluid-mediated polymetamorphism related to Proterozoic collision of Archean Wyoming and Superior provinces in the Black Hills, South Dakota
- Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota
- Identifying the effects of petrologic processes in a closed basaltic system using trace- element concentrations in olivines and glasses: Implications for comparative planetology
- Tectonic implications of diverse igneous blocks in Franciscan mélange, Northern California and southwestern Oregon
- The petrogenesis of the Apollo 14 high-Al mare basalts
- Experimental insights on crystal chemistry of high-Ti garnets from garnet-melt partitioning of rare-earth and high-field-strength elements
- The atomic arrangement of merrillite from the Fra Mauro Formation, Apollo 14 lunar mission: The first structure of merrillite from the Moon
- The behavior of Li and B in lunar mare basalts during crystallization, shock, and thermal metamorphism: Implications for volatile element contents of martian basalts
- Pyroxene europium valence oxybarometer: Effects of pyroxene composition, melt composition, and crystallization kinetics
- Comparative planetary mineralogy: Pyroxene major- and minor-element chemistry and partitioning of vanadium between pyroxene and melt in planetary basalts
- Crystal chemistry of lunar merrillite and comparison to other meteoritic and planetary suites of whitlockite and merrillite
- An experimental study of trace-element partitioning between Ti-Al-clinopyroxene and melt: Equilibrium and kinetic effects including sector zoning
- Minor- and trace-element sector zoning in synthetic enstatite
- Insights into the redox history of the NWA 1068/1110 martian basalt from mineral equilibria and vanadium oxybarometry
- Transformations of Mg- and Ca-sulfate hydrates in Mars regolith
- An experimental study of the oxidation state of vanadium in spinel and basaltic melt with implications for the origin of planetary basalt
- Valence state partitioning of vanadium between olivine-liquid: Estimates of the oxygen fugacity of Y980459 and application to other olivine-phyric martian basalts
- Identification of relict forsterite grains in forsterite-rich chondrules from the Mokoia CV3 carbonaceous chondrite
- Formation of spinel-, hibonite-rich inclusions found in CM2 carbonaceous chondrites
- Deep metastable eutectic condensation in Al-Fe-SiO-H2-O2 vapors: Implications for natural Fe-aluminosilicates
- α-PbO2-type nanophase of TiO2 from coesite-bearing eclogite in the Dabie Mountains, China–Comment
- α-PbO2-type nanophase of TiO2 from coesite-bearing eclogite in the Dabie Mountains, China–Reply
- Rietveld structure refinement of perovskite and post-perovskite phases of NaMgF3 (Neighborite) at high pressures
- Letter. Si vacancies in the 10-Å phase
