Scandian actinolite from Jordanów Śląski, Lower Silesia, Poland: Compositional evolution, crystal structure, and genetic Implications
-
Adam Pieczka
, Marcin Stachowicz
, Bżena Gołębiowska
, Jakub Kotowski
and Krzysztof Woźniak
Abstract
Scandian actinolite evolving to scandio-winchite (up to 5.45 wt% Sc2O3) has been found in chloritedominant xenoliths incorporated into marginal portion of a granitic pegmatite. The pegmatite intruded a blackwall schist zone developed around rodingite-type rocks exposed in a serpentinite quarry at Jordanów Śląski near Sobótka, ~30 km south of Wrocław, Lower Silesia, Poland. The amphiboles form irregular overgrowths around cascandite and represent a complex solid-solution series among actinolite and scandio-winchite end-members, with a trace contribution of “scandio-magnesio-hornblende.” Structural studies of a scandian actinolite crystal with composition A[□0.995(2)K0.005(2)]Σ1B[Na0.24(5)Ca1.73(4)]Σ1.98(1)
References cited
Abdel Wahed, M. (1999) The Ślęża ophiolite (SW Poland): Petrological and structural evolution. 302 p. Ph.D. thesis, University of Wrocław.Search in Google Scholar
Awdankiewicz, M., Kryza, R., Turniak, K., Ovtcharova, M., and Schaltegger, U. (2021) The Central Sudetic Ophiolite (European Variscan Belt): Precise U-Pb zircon dating and geotectonic implications. Geological Magazine, 158, 555–566, https://doi.org/10.1017/S0016756820000722Search in Google Scholar
Ballirano, P., Celata, B., Pacella, A., and Bosi, F. (2021) Recommended X-ray single-crystal structure refinement and Rietveld refinement procedure for tremolite. Acta Crystallographica, 77, 537–549, https://doi.org/10.1107/S2052520621004844Search in Google Scholar
Bergstøl, S. and Juve, G. (1988) Scandian ixiolite, pyrochlore and bazzite in granite pegmatite in Tordal, Telemark, Norway. A contribution to the mineralogy and geochemistry of scandium and tin. Mineralogy and Petrology, 38, 229–243, https://doi.org/10.1007/BF01167090Search in Google Scholar
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H. (2009) OLEX2: A complete structure solution, refinement and analysis program. Journal of Applied Crystallography, 42, 339–341, https://doi.org/10.1107/S0021889808042726Search in Google Scholar
Dubińska, E. (1995) Rodingites of the eastern part of the Jordanów-Gogołów ser-pentinite massif, Lower Silesia, Poland. Canadian Mineralogist, 33, 585–608.Search in Google Scholar
Dubińska, E. and Szafranek, D. (1990) On the origin of layer silicates from Jordanów (Lower Silesia, Poland). Archiwum Mineralogiczne, 46, 19–36.Search in Google Scholar
Dubińska, E. and Wiewióra, A. (1988) Layer silicates in the contact zone between granite and serpentinite, Jordanów, Lower Silesia, Poland. Clay Minerals, 23, 459–470, https://doi.org/10.1180/claymin.1988.023.4.12Search in Google Scholar
Dubińska, E., Bylina, P., Kozłowski, A., Dörr, W., Nejbert, K., Schastok, J., and Kulicki, C. (2004) U-Pb dating of serpentinization: Hydrothermal zircon from a metasomatic rodingite shell (Sudetic ophiolite, SW Poland). Chemical Geology, 203, 183–203, https://doi.org/10.1016/j.chemgeo.2003.10.005Search in Google Scholar
Floyd, P.A., Kryza, R., Crowley, Q.G., Winchester, J.A., and Abdel Wahed, M. (2002) Ślęża ophiolite: Geochemical features and relationship to Lower Palaeozoic rift magmatism in the Bohemian Massif. In J.A. Winchester, T.C. Pharaoh, and J. Verniers, Eds., Palaeozoic Amalgamation of Central Europe. Geological Society of London, Special Publications, 201, 197–215.Search in Google Scholar
Foord, E.E., Birmingham, S.D., Demartin, F., Pilati, T., Gramaccioli, C.M., and Lichte, F.E. (1993) Thortveitite and associated Sc-bearing minerals from Ra-valli County, Montana. Canadian Mineralogist, 31, 337–346, https://doi.org/10.3749/1499-1276-31.2.337Search in Google Scholar
Gagné, O.C. and Hawthorne, F.C. (2015) Comprehensive derivation of bond-valence parameters for ion pairs involving oxygen. Acta Crystallographica, 71, 562–578, https://doi.org/10.1107/S2052520615016297Search in Google Scholar
Gil, G. (2013) Petrographic and microprobe study of nephrites from Lower Silesia (SW Poland). Geological Quarterly, 57, 395–404, https://doi.org/10.7306/gq.1101Search in Google Scholar
Gil, G., Barnes, J.D., Boschi, C., Gunia, P., Szakmány, G., Bendõ, Z., Raczynski, P., and Péterdi, B. (2015) Origin of serpentinite-related nephrite from Jordanów and adjacent areas (SW Poland) and its comparison with selected nephrite occurrences. Geological Quarterly, 59, 457–472, https://doi.org/10.7306/gq.1228Search in Google Scholar
Gil, G., Bagiński, B., Gunia, P., Madej, S., Sachanbiński, M., Jokubauskas, P., and Belka, Z. (2020) Comparative Fe and Sr isotope study of nephrite deposits hosted in dolomitic marbles and serpentinites from the Sudetes, SW Poland: Implications for Fe-As-Au-bearing skarn formation and post-obduction evolution of the oceanic lithosphere. Ore Geology Reviews, 118, 103335, https://doi.org/10.1016/j.oregeorev.2020.103335Search in Google Scholar
Gion, A.M., Piccoli, P.M., Fei, Y., Candela, P.A., and Ash, R.D. (2021) Experimental constraints on the formation of pegmatite-forming melts by anatexis of amphibolite: A case study from Evje-Iveland, Norway. Lithos, 398-399, 106342, https://doi.org/10.1016/j.lithos.2021.106342Search in Google Scholar
Gramaccioli, C.M., Diella, V., and Demartin, F. (2000) The formation of scandium minerals as an example of the role of complexes in the geochemistry of rare earths and HFS elements. European Journal of Mineralogy, 12, 795–808, https://doi.org/10.1127/ejm/12/4/0795Search in Google Scholar
Hatert, F. and Burke, E.A.J. (2008) The IMA-CNMNC dominant-constituent rule revisited and extended. Canadian Mineralogist, 46, 717–728, https://doi.org/10.3749/canmin.46.3.717Search in Google Scholar
Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., and Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist, 97, 2031–2048, https://doi.org/10.2138/am.2012.4276Search in Google Scholar
Heflik, W. (1967) Studium mineralogiczno-petrograficzne leukokratycznej strefy przeobrażonej okolic Jordanowa Śląskiego (Dolny Śląsk). Prace Mineralog-iczne PAN, 10. Wydawnictwa Geologiczne (in Polish).Search in Google Scholar
Hreus, S., Výravský, J., Cempírek, J., Breiter, K., Vašinová Galiová, M., Krátký, O., Šešulka, V., and Škoda, R. (2021) Scandium distribution in the world-class Li-Sn-W Cínovec greisen-type deposit: Result of a complex magmatic to hydrothermal evolution, implications for scandium valorization. Ore Geology Reviews, 139, 104433, https://doi.org/10.1016/j.oregeorev.2021.104433Search in Google Scholar
Kryza, R. (2011) Early Carboniferous (~337 Ma) granite intrusion in Devonian (~400 Ma) ophiolite of the Central-European Variscides. Geological Quarterly, 55, 213–222.Search in Google Scholar
Kryza, R. and Pin, C. (2010) The Central-Sudetic ophiolites (SW Poland): Pet-rogenetic issues, geochronology and palaeotectonic implications. Gondwana Research, 17, 292–305, https://doi.org/10.1016/j.gr.2009.11.001Search in Google Scholar
Lebda, E.M. (1995) Petrology and mineral chemistry of serpentinite rocks of the Gogołów-Jordanów Massif, SW Poland, 189 p. Ph.D. thesis, Archive of the University of Wrocław, Poland.Search in Google Scholar
Lis, J. and Sylwestrzak, H. (1981) Nowy zespól mineralny w leukokratycznej strefie Jordanowa k. Sobótki jego znaczenie genetyczne. Przegląd Geologiczny, 29, 67–71 (in Polish).Search in Google Scholar
Locock, A.J. (2014) An Excel spreadsheet to classify chemical analyses of amphi-boles following the IMA 2012 recommendations. Computers & Geosciences, 62, 1–11, https://doi.org/10.1016/j.cageo.2013.09.011Search in Google Scholar
Majerowicz, A. (1984) Petrography and genesis of rodingites in serpentinites of the Ślęża ophiolitic group. Geologia Sudetica, 18, 109–132 (in Polish with English summary).Search in Google Scholar
Mellini, M. and Merlino, S. (1982) The crystal structure of cascandite, CaScSi3O8(OH). American Mineralogist, 67, 604–609.Search in Google Scholar
Novák, M. and Čech, F. (1995) Scandian columbite and niobian rutile from peg-matites penetrating the Třebíč durbachite massif, western Moravia, Czech Republic. Acta Musei Moraviae. Science and Nature, 80, 3–8.Search in Google Scholar
Novák, M. and Černý, P. (1998) Scandium in columbite-group minerals from LCT pegmatites in the Moldanubicum, Czech Republic. Krystalinikum, 24, 73–89.Search in Google Scholar
Oberti, R., Hawthorne, F.C., Cámara, F., and Raudsepp, M. (1999) Unusual M3+ cations in synthetic amphiboles with nominal fluoro-eckermannite composition: Deviations from stoichiometry and structural effects of the cummingtonite component. American Mineralogist, 84, 102–111, https://doi.org/10.2138/am-1999-1-211Search in Google Scholar
Oliver, G.J.H., Corfu, F., and Krogh, T.E. (1993) U–Pb ages from SW Poland: Evidence for a Caledonian suture zone between Baltica and Gondwana. Journal of the Geological Society, 150, 355–369, https://doi.org/10.1144/gsjgs.150.2.0355Search in Google Scholar
Pezzotta, F., Diella, V., and Guastoni, A. (2005) Scandium silicates from the Baveno and Cuasso al Monte NYF-granites, Southern Alps (Italy): Mineralogy and genetic inferences. American Mineralogist, 90, 1442–1452, https://doi.org/10.2138/am.2005.1478Search in Google Scholar
Pieczka, A., Stachowicz, M., Zelek-Pogudz, S., Gołębiowska, B., Nejbert, K., Kotowski, J., Marciniak-Maliszewska, B., Szuszkiewicz, A., Szełęg, E., Stadnicka, K.M., and others. (2022) Scandio-winchite, IMA 2022-009. CNMNC Newsletter 67. Mineralogical Magazine, 86, 849–853, https://doi.org/10.1180/mgm.2022.56Search in Google Scholar
Pietranik, A., Storey, C., and Kierczak, J. (2013) The Niemcza diorites and monzo-diorites (Sudetes, SW Poland): A record of changing geotectonic setting at ca. 340 Ma. Geological Quarterly, 57, 325–334, https://doi.org/10.7306/gq.1084Search in Google Scholar
Pouchou, J.L. and Pichoir, F. (1991) Quantitative analysis of homogeneous or stratified microvolumes applying the model “PAP”. In K.F.J. Heinrich and D.E. Newbury, Eds., Electron Probe Quantitation, p 31–75. Springer.Search in Google Scholar
Raudsepp, M., Turnock, A., Hawthorne, F.C., Sheriff, B., and Hartman, J.S. (1987a) Characterization of synthetic pargasitic amphiboles NaCa2Mg4M3+Si6Al2O22(OH,F)2; M3+ = Al, Cr, Ga, Sc, In) by infrared spectroscopy, Rietveld structure refinement, and 27Al, 29Si, and 19F MAS-NMR spectroscopy. American Mineralogist, 72, 580–593.Search in Google Scholar
Raudsepp, M., Turnock, A., and Hawthorne, F.C. (1987b) Characterization of cation ordering in synthetic scandium-fluor-eckermannite, indium-fluoreckermannite, and scandium-fluor-nyböite by Rietveld structure refinement. American Mineralogist, 72, 959–964.Search in Google Scholar
Raudsepp, M., Turnock, A., and Hawthorne, F.C. (1991) Amphibole synthesis at low pressure: What grows and what doesn’t. European Journal of Mineralogy, 3, 983–1004, https://doi.org/10.1127/ejm/3/6/0983Search in Google Scholar
Rigaku Oxford Diffraction. (2019) CrysAlisPro Software system, ver. 1.171.40.67a. Rigaku Corporation.Search in Google Scholar
Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, 32, 751–767, https://doi.org/10.1107/S0567739476001551Search in Google Scholar
Shchekina, T.I. and Gramenitskii, E.N. (2008) Geochemistry of Sc in the magmatic process: Experimental evidence. Geochemistry International, 46, 351–366, https://doi.org/10.1134/S0016702908040046Search in Google Scholar
Sheldrick, G.M. (2015a) Crystal structure refinement with SHELXL. Acta Crystal-lographica, C71, 3–8, https://doi.org/10.1107/S2053229614024218Search in Google Scholar
Sheldrick, G.M. (2015b) SHELXT—Integrated space-group and crystal-structure determination. Acta Crystallographica, 71, 3–8, https://doi.org/10.1107/S2053273314026370Search in Google Scholar
Shimazaki, H., Yang, Z., Miyawaki, R., and Shigeoka, M. (2008) Scandium-bearing minerals in the Bayan Obo Nb-REE-Fe deposit, Inner Mongolia, China. Resource Geology, 58, 80–86, https://doi.org/10.1111/j.1751-3928.2007.00045.xSearch in Google Scholar
Steffenssen, G., Muller, A., Munnik, F., Friis, H., Erambert, M., Kristoffersen, M., and Rosing-Schow, N. (2020) Unusual scandium enrichments of the Tørdal pegmatites, south Norway. Part I: Garnet as Sc exploration pathfinder. Ore Geology Reviews, 126, 103729, https://doi.org/10.1016/j.oregeorev.2020.103729Search in Google Scholar
Tilling, R.I., Greenland, L.P., and Gottfried, D. (1969) Distribution of scandium between coexisting biotite and hornblende in igneous rocks. Geological Society of America Bulletin, 80, 651–668, https://doi.org/10.1130/0016-7606(1969)80[651:DOSBCB]2.0.CO;2Search in Google Scholar
Traube, H. (1885a) Über den Nephrit von Jordansmuhl in Schlesien. Neues Jahrbuch für Mineralogie, Geologie und Paleontologie. Beilage-Band, 3, 412–427.Search in Google Scholar
Traube, H. (1885b) Über den Nephrit von Jordansmühl in Schlesien. Neues Jahrbuch für Mineralogie, Geologie und Paleontologie. Beilage-Band, 2, 91–94.Search in Google Scholar
Wang, Z., Yan Hei Li, M., Ray Liu, Z.R., and Zhou, M.F. (2021) Scandium: Ore deposits, the pivotal role of magmatic enrichment and future exploration. Ore Geology Reviews, 128, 103906, https://doi.org/10.1016/j.oregeorev.2020.103906Search in Google Scholar
Warr, L.N. (2021) IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85, 291–320, https://doi.org/10.1180/mgm.2021.43Search in Google Scholar
Williams-Jones, A.E. and Vasyukova, O.V. (2018) The economic geology of scandium, the runt of the rare earth element litter. Economic Geology, 113, 973–988, https://doi.org/10.5382/econgeo.2018.4579Search in Google Scholar
Wojtulek, P.M., Schulz, B., Klemd, R., Gil, G., Dajek, M., and Delura, K. (2022) The Central-Sudetic ophiolites—remnants of the SSZ-type Devonian oceanic lithosphere in the European part of the Variscan Orogen. Gondwana Research, 105, 343–365, https://doi.org/10.1016/j.gr.2021.09.015Search in Google Scholar
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Articles in the same Issue
- The search for a universal law of crystal growth: The law of proportionate effect?
- Crystal growth according to the law of proportionate effect
- Melt-mediated re-equilibration of zircon produced during meltdown of the Chernobyl reactor
- High-pressure behavior and structural transition of beryl-type johnkoivulaite, Cs(Be2B)Mg2Si6O18
- Subsolidus breakdown of armalcolite: Constraints on thermal effects during shock lithification of lunar regolith
- Melting and melt segregation processes controlling granitic melt composition
- Magmatic degassing controlled the metal budget of the Axi epithermal gold deposit, China
- Formation of mixed-layer sulfide-hydroxide minerals from the Tochilinite-Valleriite group during experimental serpentinization of olivine
- Two discrete gold mineralization events recorded by hydrothermal xenotime and monazite, Xiaoqinling gold district, central China
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- Origin of gem-quality turquoise associated with quartz-barite veins in western Hubei Province, China: Constraints from mineralogical, fluid inclusion, and C-O-H isotopic data
- The 450 nm (2.8 eV) cathodoluminescence emission in quartz and its relation to structural defects and Ti contents
- Correlation between Hinckley index and stacking order-disorder in kaolinite
- Structure and titanium distribution of feiite characterized using synchrotron single-crystal X-ray diffraction techniques
- Enrichment of precious metals associated with chalcopyrite inclusions in sphalerite and pyrite
- An UV/Vis/NIR optical absorption spectroscopic and color investigation of transition-metal-doped gahnite (ZnAl2O4 spinel) crystals grown by the flux method
- Understanding the unique geochemical behavior of Sc in the interaction with clay minerals
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- Characterizing a new type of nelsonite recognized in the Damiao anorthosite complex, North China Craton, with implications for the genesis of giant magmatic Fe-Ti oxide deposits
- Genesis of Mesozoic high-Mg dioritic rocks from the eastern North China Craton: Implications for the evolution of continental lithosphere
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