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Surface Modification of a n-Si(111) Electrode through Aldehyde Grafting and Subsequent Metallization: Theory and Experiment
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Martin Metzler
Published/Copyright:
September 24, 2012
Abstract
Motivated by our previous studies on metallic substrates, in the present work we addressed the functionalization and the subsequent metallization of a hydrogen-terminated n-Si(111) electrode. DFT provides atomistic insights on the grafting mechanism of 4-pyridinecarboxaldehyde (C6H5NO) what encouraged electrochemical investigations, i. e. cyclic voltammetry and in-situ STM, combined with XPS measurements which together provide evidence for a successful transfer of the so far obtained knowledge from metal single crystal to semiconductor surfaces.
Published Online: 2012-9-24
Published in Print: 2012-10-1
© by Oldenbourg Wissenschaftsverlag, München, Germany
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- Preface
- Building versus Structure Elements: Ionic Charge Carriers in Solids
- A Brief Review of Determinism in the Prediction of Localized Corrosion Damage
- La0.6Sr0.4CoO3-δ (LSC) Thin Film Electrodes with Very Fast Oxygen Reduction Kinetics Prepared by a Sol-Gel Route
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- Fundamental Investigation of the HER on a Pt(111) Surface at Temperatures down to 120K
- Impedance Spectra of Pt(100) in Aqueous H2SO4 and HCl Solutions Around the Hydrogen Adsorption-Desorption Peak
- Lifting of Thermally-Induced Surface Reconstruction on Au(100) Electrode by Protonated Molecules of Dopamine
- The Under Potential Deposition of Cu on Au (111) in Nonaqueous Acetonitrile
- Lead Underpotential Deposition on Pt-submonolayer Modified Au(111)
- Adsorption of Solvent Cations on Au(111) and Au(100) in Alkylimidazolium-Based Ionic Liquids – Worm-Like versus Micelle-Like Structures
- Measurements of the Potentials of Zero Free Charge and Zero Total Charge for 1-thio- ± bβ-D-glucose and DPTL Modified Au(111) Surface in Different Electrolyte Solutions
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- Tetrahedral Palladium Nanocrystals: A New Support for Platinum Monolayer Electrocatalysts with High Activity and Stability in the Oxygen Reduction Reaction
- Surface Modification of a n-Si(111) Electrode through Aldehyde Grafting and Subsequent Metallization: Theory and Experiment
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- Adsorption of Additives: Hardness and Softness at Electrified Interfaces
Keywords for this article
Density Functional Theory;
Grafting Mechanism;
Silicon;
Organic Thin Film;
Metallization
Articles in the same Issue
- Preface
- Building versus Structure Elements: Ionic Charge Carriers in Solids
- A Brief Review of Determinism in the Prediction of Localized Corrosion Damage
- La0.6Sr0.4CoO3-δ (LSC) Thin Film Electrodes with Very Fast Oxygen Reduction Kinetics Prepared by a Sol-Gel Route
- Nitrate Reduction on Platinum (111) Surfaces Modifiedl with Bi: Single Crystalsl and Nanoparticles
- Fundamental Investigation of the HER on a Pt(111) Surface at Temperatures down to 120K
- Impedance Spectra of Pt(100) in Aqueous H2SO4 and HCl Solutions Around the Hydrogen Adsorption-Desorption Peak
- Lifting of Thermally-Induced Surface Reconstruction on Au(100) Electrode by Protonated Molecules of Dopamine
- The Under Potential Deposition of Cu on Au (111) in Nonaqueous Acetonitrile
- Lead Underpotential Deposition on Pt-submonolayer Modified Au(111)
- Adsorption of Solvent Cations on Au(111) and Au(100) in Alkylimidazolium-Based Ionic Liquids – Worm-Like versus Micelle-Like Structures
- Measurements of the Potentials of Zero Free Charge and Zero Total Charge for 1-thio- ± bβ-D-glucose and DPTL Modified Au(111) Surface in Different Electrolyte Solutions
- Tert-Pentanol Adsorption on Ag(100) and Ag(110) from an Aqueous Solution and its Comparison with that on Ag(111), Hg, Ga and Bi(001)
- Tetrahedral Palladium Nanocrystals: A New Support for Platinum Monolayer Electrocatalysts with High Activity and Stability in the Oxygen Reduction Reaction
- Surface Modification of a n-Si(111) Electrode through Aldehyde Grafting and Subsequent Metallization: Theory and Experiment
- Ion Transfer Mechanisms Accompanying p-Doping of Poly(3,4-Ethylenedioxythiophene) Films in Deep Eutectic Solvents
- Adsorption of Additives: Hardness and Softness at Electrified Interfaces
