Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 1: Frequency Modulation Spectroscopy
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Gernot Friedrichs
Frequency modulation spectroscopy (FMS) and cavity ringdown spectroscopy (CRDS) are sensitive absorption based detection methods that have found widespread applications in gas phase reaction kinetics. In part 1 of this review, the theoretical foundations of FMS are addressed with a special emphasis on time-resolved quantitative measurements of concentration profiles. A complementary review of CRDS can be found in part 2 (Z. Phys. Chem. 222 (2008) 31–61). Practical aspects, possible pitfalls, attainable sensitivities, and modern trends are discussed. Kinetic studies based on FMS measurements as a time-resolved detection tool are briefly reviewed and a bibliography with more than a hundred entries is included to facilitate the access to the large body of original literature.
© Oldenbourg Wissenschaftsverlag
Articles in the same Issue
- Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 1: Frequency Modulation Spectroscopy
- Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 2: Cavity Ringdown Spectroscopy
- Conductivity Studies of n-Tetrabutylammonium Tetraphenylborate in Acetone and Acetonitrile in the Temperature Range from 283.15 to 303.15K
- Chemical Changes of Evaporated a-C Films upon UV Ashing, Hydration, and Drying
- Nonequilibrium Processes During Fe(CO)5 Pyrolysis in a Shock Wave
- Electrowetting of Ionic Liquids under High Vacuum Conditions
- Comparison of a VOx-TiO2 and a VOx/SbOy-TiO2 Industrial Catalyst in the Oxidative Scission of Methyl Ethyl Ketone and 2-Butanol to Acetic Acid
- Characterization of Water-Soluble Cucurbit[7]uril in Alcohol-Water Mixtures by High-Pressure Studies on the Inclusion Complexation with New Methylene Blue
- Electronic States of the Ultramarine Chromophore S3-
- Effect of Sodium Sulphate on the Volumetric, Rheological and Refractometric Properties of some Disaccharides in Aqueous Solutions at Different Temperatures
- Kinetics of Protein Adsorption at a Poly(Acrylic Acid) Brush Studied by Surface Plasmon Resonance Spectroscopy
- Book Review
- Book Review
Articles in the same Issue
- Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 1: Frequency Modulation Spectroscopy
- Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 2: Cavity Ringdown Spectroscopy
- Conductivity Studies of n-Tetrabutylammonium Tetraphenylborate in Acetone and Acetonitrile in the Temperature Range from 283.15 to 303.15K
- Chemical Changes of Evaporated a-C Films upon UV Ashing, Hydration, and Drying
- Nonequilibrium Processes During Fe(CO)5 Pyrolysis in a Shock Wave
- Electrowetting of Ionic Liquids under High Vacuum Conditions
- Comparison of a VOx-TiO2 and a VOx/SbOy-TiO2 Industrial Catalyst in the Oxidative Scission of Methyl Ethyl Ketone and 2-Butanol to Acetic Acid
- Characterization of Water-Soluble Cucurbit[7]uril in Alcohol-Water Mixtures by High-Pressure Studies on the Inclusion Complexation with New Methylene Blue
- Electronic States of the Ultramarine Chromophore S3-
- Effect of Sodium Sulphate on the Volumetric, Rheological and Refractometric Properties of some Disaccharides in Aqueous Solutions at Different Temperatures
- Kinetics of Protein Adsorption at a Poly(Acrylic Acid) Brush Studied by Surface Plasmon Resonance Spectroscopy
- Book Review
- Book Review
