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Experimental and Modelling Study of 1-Pentene Combustion at Fuel-Rich Conditions

  • G. González Alatorre , H. Böhm , Burak Atakan and Katharina Kohse-Höinghaus
Published/Copyright: September 25, 2009
Zeitschrift für Physikalische Chemie
From the journal Volume 215 Issue 8

A fuel-rich, non-sooting (C/O = 0.773) 1-pentene/oxygen/argon flame is studied experimentally at 50 mbar. The results are compared to computations. The calculations show satisfactory agreement with the data obtained from the measurements. The main channels for 1-pentene decomposition are presented and discussed in view of previous data for a propene flame at similar experimental conditions. Special emphasis is directed towards the formation of the first aromatic ring and the further growth of small aromatic hydrocarbons. By reaction flow analysis, it is found that the major reaction channel for benzene formation results from the recombination of propargyl radicals. Furthermore, the major reaction channels for naphthalene formation are presented.

Published Online: 2009-09-25
Published in Print: 2001-08

Articles in the same Issue

  1. Experimental and Modelling Study of 1-Pentene Combustion at Fuel-Rich Conditions
  2. An Experimental and Modelling Study of Ignition Delays in Shock-Heated Ethane-Oxygen-Argon Mixtures Inhibited by 2H-Heptafluoropropane
  3. Initial Observations of Ketene in Flow Reactor Kinetic Studies
  4. Prospects for Molecular Spectroscopy at High Spatial Resolution
  5. The CH + N2 Association Reaction at Low Temperatures: Ab Initio MO/VRRKM-Theory Analysis of Temperature and Pressure Effects
  6. Rate Constants Deduced by Ab-Initio Calculations for Decomposition Reactions of CH3OCH2, C4H9OCH2 and C4H8OCH3 Radicals
  7. Density of Loosely Bound States in a Triatomic Molecule: The Role of Long Range Interactions
  8. Book Reviews
https://doi.org/10.1524/zpch.2001.215.8.981

Articles in the same Issue

  1. Experimental and Modelling Study of 1-Pentene Combustion at Fuel-Rich Conditions
  2. An Experimental and Modelling Study of Ignition Delays in Shock-Heated Ethane-Oxygen-Argon Mixtures Inhibited by 2H-Heptafluoropropane
  3. Initial Observations of Ketene in Flow Reactor Kinetic Studies
  4. Prospects for Molecular Spectroscopy at High Spatial Resolution
  5. The CH + N2 Association Reaction at Low Temperatures: Ab Initio MO/VRRKM-Theory Analysis of Temperature and Pressure Effects
  6. Rate Constants Deduced by Ab-Initio Calculations for Decomposition Reactions of CH3OCH2, C4H9OCH2 and C4H8OCH3 Radicals
  7. Density of Loosely Bound States in a Triatomic Molecule: The Role of Long Range Interactions
  8. Book Reviews
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