Article
Licensed
Unlicensed
Requires Authentication
Correlation of Adiabatic States between Perturbed Rotor and Renner-Teller Limits for a Closed-Shell Ion + Open Shell Diatom System
-
E.I. Dashevskaya
Published/Copyright:
April 16, 2008
The adiabatic channel interaction potentials for a system charge + dipole-open-shell-quadrupole linear rotor are calculated in the perturbed rotor and slightly anharmonic Renner-Teller limits. In both cases, first order charge-dipole and charge-quadrupole interactions are not additive; this leads to novel expressions for the energy levels. The result can be used in the construction of the adiabatic correlation diagrams between free rotor states with account for the Λ-doubling of a diatom and the linear anharmonic Renner-Teller triatomic system.
Published Online: 2008-04-16
Published in Print: 2000-08
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Correlation of Adiabatic States between Perturbed Rotor and Renner-Teller Limits for a Closed-Shell Ion + Open Shell Diatom System
- Testing Intermolecular Potentials with Scattering Experiments: He-CO Rotationally Inelastic Collisions
- Collision-Induced Dissociation Dynamics of the [OCS · C2H2]+ Complex. A Combined Experimental and Theoretical Study
- Temperature Dependence of Collisional Energy Transfer in Highly Excited Aromatics Studied by Classical Trajectory Calculations
- Coupling Across Bonds: Ab Initio Calculations for the Anharmonic Vibrational Resonance Dynamics of the Coupled OH and CH Chromophores in Trans Formic Acid HCOOH
- A Saturated LIF Study on the High Pressure Limiting Rate Constant of the Reaction CN + NO + M → NCNO + M between 200 and 600 K
- High Resolution Electron Ionization of N2O Clusters: Appearance Energies
- Direct Measurements of the Reaction NH2 + H2 → NH3 + H at Temperatures from 1360 to 2130 K
Articles in the same Issue
- Correlation of Adiabatic States between Perturbed Rotor and Renner-Teller Limits for a Closed-Shell Ion + Open Shell Diatom System
- Testing Intermolecular Potentials with Scattering Experiments: He-CO Rotationally Inelastic Collisions
- Collision-Induced Dissociation Dynamics of the [OCS · C2H2]+ Complex. A Combined Experimental and Theoretical Study
- Temperature Dependence of Collisional Energy Transfer in Highly Excited Aromatics Studied by Classical Trajectory Calculations
- Coupling Across Bonds: Ab Initio Calculations for the Anharmonic Vibrational Resonance Dynamics of the Coupled OH and CH Chromophores in Trans Formic Acid HCOOH
- A Saturated LIF Study on the High Pressure Limiting Rate Constant of the Reaction CN + NO + M → NCNO + M between 200 and 600 K
- High Resolution Electron Ionization of N2O Clusters: Appearance Energies
- Direct Measurements of the Reaction NH2 + H2 → NH3 + H at Temperatures from 1360 to 2130 K
