Synthesis, crystal structure and electrochemical behaviour of water soluble Schiff bases
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Leyla Tatar
Abstract
Four water soluble Schiff bases were prepared from the reaction of salicylaldehyde and 2-hydroxy-1-naphtaldehyde with 2-amino-2-methyl-1,3-dihydroxy propane and 2-amino-2-methoxy-1,3-dihydroxy propane. Two of the Schiff bases were characterized using elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In addition cyclic voltammetric studies were performed. The Schiff bases C11H5NO4 (II) and C15H17NO3 (III) crystalize in monoclinic space group P21/c with unit cell dimensions a = 10.499(2), b = 8.725(2), c = 12.635(10) Å, β = 101.649(11); a = 14.579(8), b = 9.834(13), c = 9.542(5) Å, β = 107.559(5) respectively.
© by Oldenbourg Wissenschaftsverlag, München
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Articles in the same Issue
- Stoichiometric valence versus structural valence: Conclusions drawn from a study of the influence of polyhedron distortion on bond valence sums
- An alternative expression for counting the number of close-packed polytypes
- Calculation of the BO3 triangle to BO4 (PO4) tetrahedron ratio for borates and borophosphates based on the O bond numbers in the anion complexes
- Incommensurate modulation at 165 °C of intermediate tridymite
- The structure of multiple twinned CsMgInF6 and its relationship to other pyrochlore derived fluorides
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- Polymorphs of 2,3-diphenyl maleic acid anhydride and 2,3-diphenyl maleic imide: Synthesis, crystal structures, lattice energies and fluorescence
- Synthesis, crystal structure and electrochemical behaviour of water soluble Schiff bases
- Structure determination without Fourier inversion. Part I. Unique results for centrosymmetric examples
- On sphere packings of arbitrarily low density