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Synthesis, crystal structure and electrochemical behaviour of water soluble Schiff bases

  • Leyla Tatar , Hasan Nazır , Mine Gümüşer , Cansen Kale and Orhan Atakol
Published/Copyright: September 25, 2009

Abstract

Four water soluble Schiff bases were prepared from the reaction of salicylaldehyde and 2-hydroxy-1-naphtaldehyde with 2-amino-2-methyl-1,3-dihydroxy propane and 2-amino-2-methoxy-1,3-dihydroxy propane. Two of the Schiff bases were characterized using elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In addition cyclic voltammetric studies were performed. The Schiff bases C11H5NO4 (II) and C15H17NO3 (III) crystalize in monoclinic space group P21/c with unit cell dimensions a = 10.499(2), b = 8.725(2), c = 12.635(10) Å, β = 101.649(11); a = 14.579(8), b = 9.834(13), c = 9.542(5) Å, β = 107.559(5) respectively.

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Published Online: 2009-9-25
Published in Print: 2005-7-1

© by Oldenbourg Wissenschaftsverlag, München

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