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Crystal and molecular structures of two triorganophosphinegold(I) 2-amino-cyclopent-1-ene-1-carbodithioates
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Soo Yei Ho
Published/Copyright:
September 25, 2009
Abstract
The molecular structures of Ph3PAu · (S2CC5H6NH2-2) and (4-MeOC6H4)3PAu(S2CC5H6NH2-2) · CH2Cl2 display the expected linear S-Au-P coordination geometries. The hydrogen-bonding functionality in the 1,1-dithiolate ligands, i.e., —NH2 groups, allows for the formation of hydrogen-bonded, i.e., N—H…S, mediated chains in the respective crystal structures.
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Published Online: 2009-9-25
Published in Print: 2004-8-1
© 2004 Oldenbourg Wissenschaftsverlag GmbH
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Articles in the same Issue
- Shadowing and absorption corrections of single-crystal high-pressure data
- Orthotetrahedral crystal structures My(TO4)z (T = Si, Ge, P, As, S, Se, Cl, Br, I): geometrical-topological analysis, quasi-binary representation, and comparison with the AyXz compounds by the method of coordination sequences
- Synthesis, crystal structure and thermal decomposition of potassium-doped carbonated hydroxyapatite
- Solid state miscibility in the pseudo-binary TiO2—(FeSb)O4 system at 1373 K
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- Crystal and molecular structures of two triorganophosphinegold(I) 2-amino-cyclopent-1-ene-1-carbodithioates
