Article
Licensed
Unlicensed
Requires Authentication
Crystal structure of anhydrous potassium O-n-propyldithiocarbonate. Theoretical calculations of O-alkyl dithiocarbonates
-
M. A. Buntine
Published/Copyright:
September 25, 2009
Abstract
The xanthate anion in the structure of K[S2COnPr] displays the expected features, i.e. planar S2CO chromophore and variation in C—S and C—O distances. The K cation exists in a distorted cubic geometry defined by an O2S6 donor set. Cubes are face-shared so as to form a layer structure with cohesion between layers afforded by hydrophobic interactions. A series of theoretical gas-phase structures have been calculated for isolated S2COR anions. These show that there is a remarkable consistency in geometric parameters across the series. This observation indicates that the nature of the R substituent does not influence greatly the electronic structure of the central S2CO chromophore.
:
Published Online: 2009-9-25
Published in Print: 2003-1-1
© 2003 Oldenbourg Wissenschaftsverlag GmbH
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- On the discovery of new low temperature monoclinic phases with Cm and Cc space groups in Pb(Zr0.52Ti0.48)O3: an overview
- Tricalcium silicate Ca3SiO5, the major component of anhydrous Portland cement: on the conservation of distances and directions and their relationship to the structural elements
- Investigation of transition from decagonal to vacancy ordered phase on replacement of Co by Cu in Al70Co15–xCuxNi15
- White beam synchrotron X-ray topography studies of twinning in GdFeO3-type perovskite crystals
- Synthesis, X-ray crystal structure and dielectric measurements of a tetragonal tungsten bronze: Pb0.75K1.80Li1.70Nb5O15
- Ab initio structure determination of In2H2(P2O7)(P4O12) from X-ray powder diffraction data
- EXAFS and XRD investigations of zeunerite and meta-zeunerite
- Crystal and molecular structures of 4-aryl-1,4-dihydropyrimidines: Novel calcium channel antagonists
- Crystal structure of anhydrous potassium O-n-propyldithiocarbonate. Theoretical calculations of O-alkyl dithiocarbonates
- Synthesis and crystal structure of diaquabis(diketohydrindene-diketohydrindamine)manganese(II)
- Ab initio structure determination of cytochrome c6 by combined reciprocal space-real space approach
- Books Received
Articles in the same Issue
- On the discovery of new low temperature monoclinic phases with Cm and Cc space groups in Pb(Zr0.52Ti0.48)O3: an overview
- Tricalcium silicate Ca3SiO5, the major component of anhydrous Portland cement: on the conservation of distances and directions and their relationship to the structural elements
- Investigation of transition from decagonal to vacancy ordered phase on replacement of Co by Cu in Al70Co15–xCuxNi15
- White beam synchrotron X-ray topography studies of twinning in GdFeO3-type perovskite crystals
- Synthesis, X-ray crystal structure and dielectric measurements of a tetragonal tungsten bronze: Pb0.75K1.80Li1.70Nb5O15
- Ab initio structure determination of In2H2(P2O7)(P4O12) from X-ray powder diffraction data
- EXAFS and XRD investigations of zeunerite and meta-zeunerite
- Crystal and molecular structures of 4-aryl-1,4-dihydropyrimidines: Novel calcium channel antagonists
- Crystal structure of anhydrous potassium O-n-propyldithiocarbonate. Theoretical calculations of O-alkyl dithiocarbonates
- Synthesis and crystal structure of diaquabis(diketohydrindene-diketohydrindamine)manganese(II)
- Ab initio structure determination of cytochrome c6 by combined reciprocal space-real space approach
- Books Received
