Iridium(III) products isolated in a reaction of IrCl3 with phenyl 2-pyridyl ketoxime
-
Małgorzata Hołyńska
Abstract
Synthesis and properties of two iridium(III) complexes (1 and 2) isolated from the same system upon change in organic solvent, are presented. 1 is a mononuclear compound with two bidentate oxime ligands linked by a strong intramolecular hydrogen bond and with two chlorido ligands in the central Ir3+ ion coordination sphere. 2 is a binuclear centrosymmetric anionic complex with two Ir3+ ions double-bridged by chlorido ligands and three terminal chlorido ligands further coordinated to two sodium cations to form a characteristic aggregate with acetonitrile molecules completing coordination spheres of the metal ions. Both 1 and 2 may help to develop a route to products analogous to Co(II) SMMs (Single Molecule Magnets) also as starting materials.
© by Oldenbourg Wissenschaftsverlag, München, Germany
Articles in the same Issue
- The crystal structure of the low-temperature phase of (NO)2SnCl6 and ordering of the NO+ ions
- Solvothermal synthesis, crystal structure and properties of a novel zinc porphyrin
- Iridium(III) products isolated in a reaction of IrCl3 with phenyl 2-pyridyl ketoxime
- Tautomers and polymorphs of pyrazolinone derivatives, generated from reactions of arylhydrazines, ArNHNH2, with 1,3-dicarbonyl compounds
- Synthesis and characterization of Tetrakis-μ-[N-phenylanthranilato](O,O′)-bis[(4-vinylpyridine copper(II)] complex
- Two dimensional cyano-bridged heteropolynuclear complex containing Pd ···π interactions
- The twinning of two closely related phenylisoxazoles interpreted according to order-disorder theory
Articles in the same Issue
- The crystal structure of the low-temperature phase of (NO)2SnCl6 and ordering of the NO+ ions
- Solvothermal synthesis, crystal structure and properties of a novel zinc porphyrin
- Iridium(III) products isolated in a reaction of IrCl3 with phenyl 2-pyridyl ketoxime
- Tautomers and polymorphs of pyrazolinone derivatives, generated from reactions of arylhydrazines, ArNHNH2, with 1,3-dicarbonyl compounds
- Synthesis and characterization of Tetrakis-μ-[N-phenylanthranilato](O,O′)-bis[(4-vinylpyridine copper(II)] complex
- Two dimensional cyano-bridged heteropolynuclear complex containing Pd ···π interactions
- The twinning of two closely related phenylisoxazoles interpreted according to order-disorder theory
