Towards systematics of calcite biocrystals: insight from the inside
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Wolfgang W. Schmahl
Abstract
Biocrystals of calcite are frequent as they are employed by many phylae of organisms in shells, eggshells, teeth, spines or sensoric apparatus. The calcite phase in these materials occurs in a range of constitutions, from polycrystalline fabrics to “single-crystals”. We demonstrate systematics of calcite biocrystal architectures, from the hybrid composite mesocrystal fibres of brachiopod and mollusc shells, via the submillimeter-sized hybrid composite crystal aggregates formed by mesocrystal fibres with both morphological co-orientation and lattice co-oriäentation, to more complex purpose-oriented multiplex äcomposite crystals of echinoderm teeth, which feature a high degree of single-crystal-like 3D orientational correlation of microstructural elements of different morphology and composition. These systematics rely on observations by electron backscatter diffraction (EBSD) and TEM.
© by Oldenbourg Wissenschaftsverlag, München, Germany
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- Book Review
Articles in the same Issue
- Elastic stiffness coefficients of thenardite and their pressure and temperature dependence
- Compressibility of microporous materials with CHA topology: 2. ALPO-34
- A Detailed Study of the Dehydration Process in Synthetic Strelkinite, Na[(UO2)(VO4)] · nH2O (n = 0, 1, 2)
- Mixed-ligand coordination of the (UO2)2+ cation and apophyllite topology of uranyl chlorochromate layer in the structure of ((CH3)2CHNH3)[(UO2)(CrO4)Cl(H2O)]
- Synthesis, crystal structure and optical properties of the catena-metaphosphates Ce(PO3)4 and U(PO3)4
- The Solid Solution CeAgxZn11–x (x ≤ 2.5)
- Ruthenate-ferrites AMRu5O11 (A = Sr, Ba; M = Ni, Zn): Distortion of kagome nets via metal–metal bonding
- A Mixed Valent Thioantimonate(III,V): [SbS3]3– and [SbS4]3– as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien)2}2[MnSb2S7]
- Hydrates of the Alkali Trioxidomonosulfidomolybdates and -tungstates: K2[(Mo/W)O3S] · 1.5H2O and (Rb/Cs)2[(Mo/W)O3S] · H2O
- Crystal structure of 1,4-diazoniabicyclo[2.2.2]octane diiodide monohydrate
- Derivation of bond-valence parameters for some cation-oxygen pairs on the basis of empirical relationships between ro and b
- The role of the Pb2+ lone electron pair for bond valence sum analysis in mullite-type PbMBO4 (M = Al, Mn and Fe) compounds
- The role of lone pairs in the ferroelastic phase transition in the palmierite-type lead phosphate-arsenate solid solution
- The role of H2O in controlling bond topology:I. The [6]Mg(SO4)(H2O)n (n = 0–11) structures
- Towards systematics of calcite biocrystals: insight from the inside
- The use of periodic graphs for representing and analysing crystal structures
- Book Review