Synthesis and properties of N1-(1,2,3,6-tetrahydrophthaloyl)semi- and thiosemicarbazides. II. Chiral N-substituted amides of 1-(3-ethylthio-1,2,4-triazol-5-yl)-4-cyclohexene-2-carboxylic acid
-
I. Wawrzycka
The structure of N-phenyl amide of 1-(3-ethylthio-1,2,4-triazol-5-yl)-4-cyclohexene-2-carboxylic acid (IIIe) has been determined by 1H NMR spectroscopy and X-ray crystallography. C17H20N4OS (328.4) is monoclinic, space group P1121/b with unit cell dimensions a = 11.530(1)Å, b = 9.685(4)Å, c = 16.486(2) Å, γ = 111.74(2)°, V = 1710.1(3) Å3, Z = 4, Dcalc. = 1.276 g cm-3. The triazole group and the N-phenyl amide are syn-oriented substituents of the cyclohexene ring. The relative configuration at the cyclohexene C(1´) and C(2´) asymmetric centers of the enantiomeric molecules in the racemic crystal is (1SR, 2RS). Molecules in the crystal structure form ribbons through intermolecular N-H···O and N-H···N hydrogen bonds. Selective interactions between the triazole···triazole and amide···amide fragments of alternatively arranged (R,S) and (S,R) enantiomers are observed.
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
Articles in the same Issue
- Temperature related structural variation of the hydrous components in gypsum
- Modified hydrothermal diamond anvil cells for XAFS analyses of elements with low energy absorption edges in aqueous solutions at sub- and supercritical conditions
- Edgeworth series expansion of the truncated Cauchy function and its effectiveness in the study of atomic heterogeneity
- Intergrowth polytypoids as modulated structures: the example of the cation deficient oxides LaTi1-xO3
- Crystal structure and thermal expansion of β-RbB5O8 from powder diffraction data
- Potassium lithium carbonate, KLiCO3: single-crystal X-ray structure analysis and thermal expansion
- The crystal structures of NaNO3 at 100 K, 120 K and 563 K
- Powder Rietveld refinement of armstrongite, CaZr[Si6O15]·3H2O
- Molecular structures of two indole alkaloids, evodiamine and rutecarpine, from evodia fruit
- Synthesis and properties of N1-(1,2,3,6-tetrahydrophthaloyl)semi- and thiosemicarbazides. II. Chiral N-substituted amides of 1-(3-ethylthio-1,2,4-triazol-5-yl)-4-cyclohexene-2-carboxylic acid
- Books Received
Articles in the same Issue
- Temperature related structural variation of the hydrous components in gypsum
- Modified hydrothermal diamond anvil cells for XAFS analyses of elements with low energy absorption edges in aqueous solutions at sub- and supercritical conditions
- Edgeworth series expansion of the truncated Cauchy function and its effectiveness in the study of atomic heterogeneity
- Intergrowth polytypoids as modulated structures: the example of the cation deficient oxides LaTi1-xO3
- Crystal structure and thermal expansion of β-RbB5O8 from powder diffraction data
- Potassium lithium carbonate, KLiCO3: single-crystal X-ray structure analysis and thermal expansion
- The crystal structures of NaNO3 at 100 K, 120 K and 563 K
- Powder Rietveld refinement of armstrongite, CaZr[Si6O15]·3H2O
- Molecular structures of two indole alkaloids, evodiamine and rutecarpine, from evodia fruit
- Synthesis and properties of N1-(1,2,3,6-tetrahydrophthaloyl)semi- and thiosemicarbazides. II. Chiral N-substituted amides of 1-(3-ethylthio-1,2,4-triazol-5-yl)-4-cyclohexene-2-carboxylic acid
- Books Received
