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Single crystal refinements of seven Sr1−xCaxCuO2 structures (x = 0–0.573) and of Ca2−ySryCuO3 (y = 0 and 0.134)

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 209 Issue 5

Abstract

Single crystals of Sr1−xCaxCuO2 with x = 0–0.573 have been grown by a modified Bi2O3 flux technique using different ratios of the earth alkali carbonates. Upto x = 0.573 the SrCuO2 structure type was found. The changes of the lattice constants and of the atomic parameters are given. The different temperature dependence of the atomic parameters comparing undoped and doped crystals is discussed.

From reaction mixtures with an excess of Ca (Ca:Sr ≥ 2:1) crystals with the composition Ca1.866Sr0.134 · CuO3 could be obtained. They crystallize in the Ca2CuO3 structure type.

Published Online: 2010-7-28
Published in Print: 1994-5-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Articles in the same Issue

  1. Crystallography with a pulsed neutron source
  2. Feasibility of phase determination in quasicrystals and microcrystals by means of multiple bragg scattering
  3. Physical properties and phase transition of tetragonal X2CuT4 · 2Q2O, X = K, Rb, NH4, ND4, T = C1, Br, Q = H, D
  4. Die Kristallstrukturen des (NH4)2Be4Cl10 und der analogen Alkalimetall-Verbindungen
  5. Vanadium oxide bronzes – the double mixed valence phases Cu[unk]Cu[unk](1−t)V[unk](2−t)V[unk](2−t)O5 A joint XRD and ESCA investigation
  6. Crystal structure of β′-Fe0.33V2O5
  7. Single crystal refinements of seven Sr1−xCaxCuO2 structures (x = 0–0.573) and of Ca2−ySryCuO3 (y = 0 and 0.134)
  8. Structure cristalline et moleculaire du thiophosphotris(enolpyruvate)
  9. Crystal structure of 4-hydroxy-4(3-methyl-5-oxo-4,5-dihydro-1H-pyrazo-4-yl)-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole
  10. Crystal and molecular structure of two Zn–Cu compounds: Zn(NH3)2Cu(CN)3 and [Zn(en)3]6[Cu5(CN)17] · nH2O (n = 8.4) containing novel [Cu2(CN)7]5− ion
  11. Crystal structure of lignocaine hydrochloride – palladium thiocyanate complex
  12. Crystal structure of lignocaine hydrochloride – nickel thiocyanate complex
  13. Crystal structure of diaquabissarcosinatocopper(II)
  14. Polysulphonylamines, XLVIII. Structure of N-trichloroacetyldimesylamine
  15. Neutron diffraction and 35Cl-NQR-T1 measurements of N-[2,6-dichlorophenyl]-2,2,2-trichloroacetamide, 2,6-Cl2C6H3NHCOCCl31
  16. Crystal structure of N-carbobenzoxy-glycine 1
  17. Crystal structure of barium dihydride, BaH2
  18. Crystal structure of [2.2]parabenzeno-(4,7)-1,5-dimethylisatinophane, C20H19NO2
  19. Crystal structure of (E,S)-(-)-(1-methoxyethyl)[(1,3,3-trimethyl-indoline-2-ylidene)-methyl]ketone, C16H21NO2
  20. Crystal structure of tricarbonyl(η6-syn-8,16-difluoro[2.2]-metacyclophane)chromium(0), C19H14CrF2O3
  21. Crystal structure of 6-chloro-5,5-bis(methylcarboxylato)-6-phospha-bicyclo[2.2.1]hept-2-ene, C6H6PCl(COOCH3)2
  22. Crystal structure of methylammonium citrate, C7H13NO7
  23. Crystal structure of 2,8,14,20-tetramethylpentacyclo-[19.3.1.13,7.19,13.115,19]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol, C32H32O8
  24. Crystal structure of 2,8,14,20-tetramethylpentacyclo-[19.3.1.13,7.19,13.115,19]octacosa-1-(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octaethyl ether, C48H64O8
  25. Crystal structure of 2,8,14,20-tetramethylpentacyclo-[19.3.1.13,7.19,13.115,19]octacosa-1-(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octaethyl ether, C48H64O8
https://doi.org/10.1524/zkri.1994.209.5.418

Articles in the same Issue

  1. Crystallography with a pulsed neutron source
  2. Feasibility of phase determination in quasicrystals and microcrystals by means of multiple bragg scattering
  3. Physical properties and phase transition of tetragonal X2CuT4 · 2Q2O, X = K, Rb, NH4, ND4, T = C1, Br, Q = H, D
  4. Die Kristallstrukturen des (NH4)2Be4Cl10 und der analogen Alkalimetall-Verbindungen
  5. Vanadium oxide bronzes – the double mixed valence phases Cu[unk]Cu[unk](1−t)V[unk](2−t)V[unk](2−t)O5 A joint XRD and ESCA investigation
  6. Crystal structure of β′-Fe0.33V2O5
  7. Single crystal refinements of seven Sr1−xCaxCuO2 structures (x = 0–0.573) and of Ca2−ySryCuO3 (y = 0 and 0.134)
  8. Structure cristalline et moleculaire du thiophosphotris(enolpyruvate)
  9. Crystal structure of 4-hydroxy-4(3-methyl-5-oxo-4,5-dihydro-1H-pyrazo-4-yl)-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole
  10. Crystal and molecular structure of two Zn–Cu compounds: Zn(NH3)2Cu(CN)3 and [Zn(en)3]6[Cu5(CN)17] · nH2O (n = 8.4) containing novel [Cu2(CN)7]5− ion
  11. Crystal structure of lignocaine hydrochloride – palladium thiocyanate complex
  12. Crystal structure of lignocaine hydrochloride – nickel thiocyanate complex
  13. Crystal structure of diaquabissarcosinatocopper(II)
  14. Polysulphonylamines, XLVIII. Structure of N-trichloroacetyldimesylamine
  15. Neutron diffraction and 35Cl-NQR-T1 measurements of N-[2,6-dichlorophenyl]-2,2,2-trichloroacetamide, 2,6-Cl2C6H3NHCOCCl31
  16. Crystal structure of N-carbobenzoxy-glycine 1
  17. Crystal structure of barium dihydride, BaH2
  18. Crystal structure of [2.2]parabenzeno-(4,7)-1,5-dimethylisatinophane, C20H19NO2
  19. Crystal structure of (E,S)-(-)-(1-methoxyethyl)[(1,3,3-trimethyl-indoline-2-ylidene)-methyl]ketone, C16H21NO2
  20. Crystal structure of tricarbonyl(η6-syn-8,16-difluoro[2.2]-metacyclophane)chromium(0), C19H14CrF2O3
  21. Crystal structure of 6-chloro-5,5-bis(methylcarboxylato)-6-phospha-bicyclo[2.2.1]hept-2-ene, C6H6PCl(COOCH3)2
  22. Crystal structure of methylammonium citrate, C7H13NO7
  23. Crystal structure of 2,8,14,20-tetramethylpentacyclo-[19.3.1.13,7.19,13.115,19]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol, C32H32O8
  24. Crystal structure of 2,8,14,20-tetramethylpentacyclo-[19.3.1.13,7.19,13.115,19]octacosa-1-(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octaethyl ether, C48H64O8
  25. Crystal structure of 2,8,14,20-tetramethylpentacyclo-[19.3.1.13,7.19,13.115,19]octacosa-1-(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octaethyl ether, C48H64O8
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