Home Two organically-templated vanadium arsenate phases: V4As6O30H6 · 2 N2C6H14 · 4 H2O and V4As6O30H8 · 2 N(CH3)4 · 5.33 H2O
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Two organically-templated vanadium arsenate phases: V4As6O30H6 · 2 N2C6H14 · 4 H2O and V4As6O30H8 · 2 N(CH3)4 · 5.33 H2O

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 209 Issue 11

Abstract

Two organically templated vanadium arsenate phases have been synthesized and characterized by single X-ray diffraction and thermogravimetric analyses. Both are comprised of clusters of vanadium arsenate anions that are held together by hydrogen bonding with the included species.

The V4As6O30H6 · 2 N2C6H14 · 4 H2O [VAs-Dab] (Mr = 1439.76) crystal is monoclinic, space group P21/c (No. 14), with a = 9.247(3) Å, b = 13.932(3) Å, c = 16.105(8) Å, β = 106.31(4)°, V = 1991.26 Å3 and Z = 2. Final residuals of R = 3.71% and Rw = 4.17% were obtained for 3044 observed reflections with I > 3σ(I). The crystalline compounds is comprised of clusters H-bonded to the organic and water molecules.

The V4As6O30H8 · 2 N(CH3)4 · 5.33 H2O [VAs-TMA](Mr = 346.43) crystal is orthorhombic, space group Cmca (No. 64), with a = 18.742(5) Å, b = 12.208(3) Å, c = 17.689(6) Å, V = 4047.24 Å3 and Z = 16. Final residuals of R = 3.89% and Rw = 4.13% were obtained for 1756 observed reflections with I > 3σ(I). The crystalline compound contains one dimensional channels, surrounded by the H-bonded clusters, containing the water molecules and tetramethyl ammonium cations.

Published Online: 2010-7-28
Published in Print: 1994-11-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Articles in the same Issue

  1. Thermal dependence of the Pb5Al3F19 lattice parameters in phases I–IV
  2. Crystal growth and crystal structure of arsenicv ditelluroidide semihydrate, AsTe2I · 0.5 H2O
  3. Submicroscopic twinning and chemical inhomogeneity of ilvaite, a mixed-valence iron sorosilicate HCaFe22 + Fe3 + Si2O9
  4. Substitutional disorder in the system Mg1 − xCu2 + xO3: Cu2+ in a compressed octahedral environment
  5. A crystal structure determination of HgC2O4 from synchrotron X-ray and neutron powder diffraction data
  6. Crystal and molecular structure of 5-(3-methylbut-2-enyloxy)-7-methoxy-8-(3-methylbut-2-enyl)-2 H-[1]-benzopyran-2-one (Sesibiricin)
  7. Structural studies on oxalatotriorganostannates. Crystal structure of trimethylsulfonium catena-O,O′-oxalatotriphenylstannate
  8. Crystal and molecular structures of P,P-dicyclohexyl-N-methyl-phosphinylthioformamide, P,P-dicyclohexyl-N-phenyl-phosphinylthioformamide, P,P-dicyclohexyl-N-methyl-thiophosphinylthioformamide, and P,P-dicyclohexyl-N-phenyl-thiophosphinylthioformamide
  9. Two organically-templated vanadium arsenate phases: V4As6O30H6 · 2 N2C6H14 · 4 H2O and V4As6O30H8 · 2 N(CH3)4 · 5.33 H2O
  10. Crystal structure of manganese ultraphosphate, MnP4O11
  11. Crystal structure of c-6-[N,N-bis(trimethylsilyl)amino]-5,6-dihydro-r-4-[(1′-hydroxy-1′-methyl)ethyl]-t-5-methyl-3-phenyl-4H-1,2-oxazine, ONC(CH)(CH)(CH)(C6H5)C(OH)(CH3)2(CH3)NSi(CH3)3Si(CH3)3
  12. Crystal structure of 2-methyl-6-phenyl-pyridin-3-al, (C6H5)C(CH)2CCNCHO(CH3)
  13. Crystal structure of 3-O-(5,6-dihydro-5-methyl-3-phenyl-4H-1,2-oxazin-6-yl)-1,2:5,6-di-O-isopropyliden-α-D-glucofuranose, O(CH)4OCO(CH3)2CHCH2OCO(CH3)2OCHCHCH2CNO(CH3)(C6H5)
  14. Crystal structure of 1,3-bis(3-trifluoromethylphenyl)-2,2,4,4-tetramethyl-1,3-diaza-2,4-disila-cyclobutane, (F3C(C6H4)NSi(CH3)2)2
  15. Crystal structure of 5-ethyl-2′-deoxyuridine, C11H16N2O5
  16. Crystal structure of 3,6-dimethyl-5-methylthio-thieno[3,2-b]-thiophen-2-carbaldehyde, C10H10OS3
  17. Crystal structure of anti-5,13-di-tert-butyl-8,16-difluoro-[2.2]metacyclophane, C24H30F2
  18. Crystal structure of 1-(3,5-difluoro-2,6-di(trans-stilbenyl)phenyl)-2-phenyl-diazene, (C6H5)NN(C6F2H(C(C6H5)CH(C6H5))2)
  19. Crystal structure of di(bis(1,1-dimethylethyl)phosphinic amide) hydrobromide,((C4H9)2(NH2)PO)2(HBr)
  20. Crystal structure of bis(lignocainium) dioxotrichloronitratouranate(IV), (C14H22ON2)2(UO2(NO3)Cl3)
  21. Crystal structure of bis(lignocainium) tetrathiocyanatocobaltate(II) hydrate, (C14H22ON2)2 Co(NCS)4 (H2O)
  22. Crystal structure of bis(lignocainium) tetrabromocuprate(II), (C14H22ON2)2CuBr4
  23. Crystal structure of terbium chromium aluminium, Tb6Cr4+xAl43−x (x = 1.6), erbium chromium aluminium, Er6Cr4+xAl43−x (x = 1.96), holmium chromium aluminium, Ho6Cr4+xAl43−x (x = 1.6), and lutetium chromium aluminium, Lu6Cr4+xAl43−X (x = 2.76)
https://doi.org/10.1524/zkri.1994.209.11.892

Articles in the same Issue

  1. Thermal dependence of the Pb5Al3F19 lattice parameters in phases I–IV
  2. Crystal growth and crystal structure of arsenicv ditelluroidide semihydrate, AsTe2I · 0.5 H2O
  3. Submicroscopic twinning and chemical inhomogeneity of ilvaite, a mixed-valence iron sorosilicate HCaFe22 + Fe3 + Si2O9
  4. Substitutional disorder in the system Mg1 − xCu2 + xO3: Cu2+ in a compressed octahedral environment
  5. A crystal structure determination of HgC2O4 from synchrotron X-ray and neutron powder diffraction data
  6. Crystal and molecular structure of 5-(3-methylbut-2-enyloxy)-7-methoxy-8-(3-methylbut-2-enyl)-2 H-[1]-benzopyran-2-one (Sesibiricin)
  7. Structural studies on oxalatotriorganostannates. Crystal structure of trimethylsulfonium catena-O,O′-oxalatotriphenylstannate
  8. Crystal and molecular structures of P,P-dicyclohexyl-N-methyl-phosphinylthioformamide, P,P-dicyclohexyl-N-phenyl-phosphinylthioformamide, P,P-dicyclohexyl-N-methyl-thiophosphinylthioformamide, and P,P-dicyclohexyl-N-phenyl-thiophosphinylthioformamide
  9. Two organically-templated vanadium arsenate phases: V4As6O30H6 · 2 N2C6H14 · 4 H2O and V4As6O30H8 · 2 N(CH3)4 · 5.33 H2O
  10. Crystal structure of manganese ultraphosphate, MnP4O11
  11. Crystal structure of c-6-[N,N-bis(trimethylsilyl)amino]-5,6-dihydro-r-4-[(1′-hydroxy-1′-methyl)ethyl]-t-5-methyl-3-phenyl-4H-1,2-oxazine, ONC(CH)(CH)(CH)(C6H5)C(OH)(CH3)2(CH3)NSi(CH3)3Si(CH3)3
  12. Crystal structure of 2-methyl-6-phenyl-pyridin-3-al, (C6H5)C(CH)2CCNCHO(CH3)
  13. Crystal structure of 3-O-(5,6-dihydro-5-methyl-3-phenyl-4H-1,2-oxazin-6-yl)-1,2:5,6-di-O-isopropyliden-α-D-glucofuranose, O(CH)4OCO(CH3)2CHCH2OCO(CH3)2OCHCHCH2CNO(CH3)(C6H5)
  14. Crystal structure of 1,3-bis(3-trifluoromethylphenyl)-2,2,4,4-tetramethyl-1,3-diaza-2,4-disila-cyclobutane, (F3C(C6H4)NSi(CH3)2)2
  15. Crystal structure of 5-ethyl-2′-deoxyuridine, C11H16N2O5
  16. Crystal structure of 3,6-dimethyl-5-methylthio-thieno[3,2-b]-thiophen-2-carbaldehyde, C10H10OS3
  17. Crystal structure of anti-5,13-di-tert-butyl-8,16-difluoro-[2.2]metacyclophane, C24H30F2
  18. Crystal structure of 1-(3,5-difluoro-2,6-di(trans-stilbenyl)phenyl)-2-phenyl-diazene, (C6H5)NN(C6F2H(C(C6H5)CH(C6H5))2)
  19. Crystal structure of di(bis(1,1-dimethylethyl)phosphinic amide) hydrobromide,((C4H9)2(NH2)PO)2(HBr)
  20. Crystal structure of bis(lignocainium) dioxotrichloronitratouranate(IV), (C14H22ON2)2(UO2(NO3)Cl3)
  21. Crystal structure of bis(lignocainium) tetrathiocyanatocobaltate(II) hydrate, (C14H22ON2)2 Co(NCS)4 (H2O)
  22. Crystal structure of bis(lignocainium) tetrabromocuprate(II), (C14H22ON2)2CuBr4
  23. Crystal structure of terbium chromium aluminium, Tb6Cr4+xAl43−x (x = 1.6), erbium chromium aluminium, Er6Cr4+xAl43−x (x = 1.96), holmium chromium aluminium, Ho6Cr4+xAl43−x (x = 1.6), and lutetium chromium aluminium, Lu6Cr4+xAl43−X (x = 2.76)
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