Home Physical Sciences The superstructure of K3HGe7O16 · 4H2O
Article
Licensed
Unlicensed Requires Authentication

The superstructure of K3HGe7O16 · 4H2O

Published/Copyright: August 25, 2010
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 198 Issue 1-2

Abstract

Potassium germanate K3HGe7O16 · xH2O (x ≈ 4) forms a cubic body-centered superstructure with a = 15.418(8) Å at room temperature. A single-crystal refinement of the average structure with aA = 1/2 a in space group P[unk]3m converged to R = 0.077. For the superstructure with eight formula units per unit cell, a model in space group I23, based on two types of twin domains related by a pseudo-mirror plane, was obtained. The relative intensities of the overlapping twin reflections were allocated according to the calculated intensities. The refinement in overall temperature factor mode converged to R = 0.090 for reflections with F0 > 3σ(F0) and R = 0.175 for the superstructure reflections.

The structure is a three-dimensional framework of GeO6 octahedra and GeO4 tetrahedra. Four octahedra form a Ge4O16, and these clusters are connected to one another via the tetrahedra. The superstructure shows a slight distortion of the average framework.

Published Online: 2010-08-25
Published in Print: 1992

Articles in the same Issue

  1. Zur kristallchemischen Einordnung von NaSbCl6, NaNbCl6 und NaTaCl6
  2. The symmetry operations for n-dimensional periodic and quasi-periodic structures *
  3. Crystal growth, crystal structure, optical, electro-optic and electrostrictive properties of the complex silver thiocyanates Cs3Sr[Ag2(SCN)7] and Cs3Ba[Ag2(SCN)7]
  4. Beiträge zum thermischen Verhalten wasserfreier Phosphate
  5. Reaction of heptamethyldisilazane with oxo ligands. Crystal structure of Re(NMe)Cl3(PPh3)2 · 0.5 C7H8 and ReO(OSiMe3)Cl2py2
  6. Crystal structure and bonding of bis-(1H-indole-3-ethylene-3′-methoxy-salicylaldimine)copper(II) monohydrate
  7. The superstructure of K3HGe7O16 · 4H2O
  8. The crystal structure of (Mg,Ga)8(Ga,Ge)2O12
  9. On the density of the p31m packing of ellipses
  10. Verfeinerung der Kristallstrukturen von Ta5As4 und monoklinem Nb4.7Te4
  11. Neutron diffraction analysis of positional oxygen and hydrogen disorder in Ba[Fe(CN)5NO] · 3H2O
  12. Crystal structure of hexacarbonyl tungsten, W(CO)6
  13. Crystal structure of indium antimony trisulfide, InSbS3
  14. Crystal structure of N-(2-hydroxyphenyl)-salicylaldiminato-ammine-nickel, NH3NiO(C6H4)CHN(C6H4)O
  15. Crystal structure of methylamin-(N,N′-1,3-propyldisalicylaldiminato)-Ni(II)-bis(N-methylsalicylaldiminato)-Ni(II), CH3NH2O(C6H4)CHNCH2CH2CH2NCH(C6H4)ONi2O(C6H4)CHNCH3O(C6H4)CHNCH3
  16. Crystal structure of N-(2-hydroxyphenyl)salicylaldiminato-diethylamine-nickel, (CH3CH2)2NHNiO(C6H4)NCH(C6H4)O
  17. Crystal structure of N-benzylsalicylaldimine, OH(C6H4)CHNCH2(C6H5)
  18. Crystal structure of benzhydrazide, NH2NHCO(C6H5)
  19. Crystal structure of triphenylphosphine(O-ethyldithiocarbonato)gold(I), (C6H5)3PAu(S2COC2H5)
  20. Crystal structure of (Z)-1-methoxycarbonyl-2-phenyl-1-phthalimidocyclopropane, C19H15NO4
  21. Crystal structure of meso-bis(1,4-dimethylpiperazine-2,5-dione-3-yl), C12H18N4O4
  22. Crystal structure of dichloro(N-methyl-2,2′-bipyridylium)platinum(II), C11H10Cl2N2Pt
  23. Crystal structure of [3′R*, IR*, 4S*, 6S*]-1-(3′-hydroxybut-1′-ynyl)-2,2,6-trimethylcyclohexane-1,4-diol, C13H22O3
  24. Crystal structure of methyl-2-phthalimido-3-methylbut-2-enoate, C14H13N1O4
  25. Crystal structure of chloro(η-cyclopentadienyl)bis(triphenylphosphine)ruthenium, C42H37Cl3P2Ru
  26. Crystal structure of 7H+,16H+-1,4,10,13-tetrathia-7,16-diazacyclooctadecane bis(tetraphenylboronate), (C12H28N2S4)((C6H5)4B)2
  27. Crystal structure of cobalt sulfanilate tetrahydrate, (Co(NH2C6H4SO3)2)(H2O)4
  28. Crystal structure of zinc sulfanilate tetrahydrate, (Zn(NH2C6H4SO3)2)(H2O)4
  29. Crystal structure of hexaaquamagnesium sulfanilate, (Mg(NH2C6H4SO3)2)(H2O)6
  30. Crystal structure of tetragadolinium hexanickel icosatresaluminium, Gd4Ni6Al23 with Y4Ni6Al23 type
  31. Crystal structure of europium dirhodium digermanium, EuRh2Ge2 with ThCr2Si2 type
  32. Crystal structure of ytterbium rhodium germanium, YbRhGe with TiNiSi type
https://doi.org/10.1524/zkri.1992.198.1-2.67

Articles in the same Issue

  1. Zur kristallchemischen Einordnung von NaSbCl6, NaNbCl6 und NaTaCl6
  2. The symmetry operations for n-dimensional periodic and quasi-periodic structures *
  3. Crystal growth, crystal structure, optical, electro-optic and electrostrictive properties of the complex silver thiocyanates Cs3Sr[Ag2(SCN)7] and Cs3Ba[Ag2(SCN)7]
  4. Beiträge zum thermischen Verhalten wasserfreier Phosphate
  5. Reaction of heptamethyldisilazane with oxo ligands. Crystal structure of Re(NMe)Cl3(PPh3)2 · 0.5 C7H8 and ReO(OSiMe3)Cl2py2
  6. Crystal structure and bonding of bis-(1H-indole-3-ethylene-3′-methoxy-salicylaldimine)copper(II) monohydrate
  7. The superstructure of K3HGe7O16 · 4H2O
  8. The crystal structure of (Mg,Ga)8(Ga,Ge)2O12
  9. On the density of the p31m packing of ellipses
  10. Verfeinerung der Kristallstrukturen von Ta5As4 und monoklinem Nb4.7Te4
  11. Neutron diffraction analysis of positional oxygen and hydrogen disorder in Ba[Fe(CN)5NO] · 3H2O
  12. Crystal structure of hexacarbonyl tungsten, W(CO)6
  13. Crystal structure of indium antimony trisulfide, InSbS3
  14. Crystal structure of N-(2-hydroxyphenyl)-salicylaldiminato-ammine-nickel, NH3NiO(C6H4)CHN(C6H4)O
  15. Crystal structure of methylamin-(N,N′-1,3-propyldisalicylaldiminato)-Ni(II)-bis(N-methylsalicylaldiminato)-Ni(II), CH3NH2O(C6H4)CHNCH2CH2CH2NCH(C6H4)ONi2O(C6H4)CHNCH3O(C6H4)CHNCH3
  16. Crystal structure of N-(2-hydroxyphenyl)salicylaldiminato-diethylamine-nickel, (CH3CH2)2NHNiO(C6H4)NCH(C6H4)O
  17. Crystal structure of N-benzylsalicylaldimine, OH(C6H4)CHNCH2(C6H5)
  18. Crystal structure of benzhydrazide, NH2NHCO(C6H5)
  19. Crystal structure of triphenylphosphine(O-ethyldithiocarbonato)gold(I), (C6H5)3PAu(S2COC2H5)
  20. Crystal structure of (Z)-1-methoxycarbonyl-2-phenyl-1-phthalimidocyclopropane, C19H15NO4
  21. Crystal structure of meso-bis(1,4-dimethylpiperazine-2,5-dione-3-yl), C12H18N4O4
  22. Crystal structure of dichloro(N-methyl-2,2′-bipyridylium)platinum(II), C11H10Cl2N2Pt
  23. Crystal structure of [3′R*, IR*, 4S*, 6S*]-1-(3′-hydroxybut-1′-ynyl)-2,2,6-trimethylcyclohexane-1,4-diol, C13H22O3
  24. Crystal structure of methyl-2-phthalimido-3-methylbut-2-enoate, C14H13N1O4
  25. Crystal structure of chloro(η-cyclopentadienyl)bis(triphenylphosphine)ruthenium, C42H37Cl3P2Ru
  26. Crystal structure of 7H+,16H+-1,4,10,13-tetrathia-7,16-diazacyclooctadecane bis(tetraphenylboronate), (C12H28N2S4)((C6H5)4B)2
  27. Crystal structure of cobalt sulfanilate tetrahydrate, (Co(NH2C6H4SO3)2)(H2O)4
  28. Crystal structure of zinc sulfanilate tetrahydrate, (Zn(NH2C6H4SO3)2)(H2O)4
  29. Crystal structure of hexaaquamagnesium sulfanilate, (Mg(NH2C6H4SO3)2)(H2O)6
  30. Crystal structure of tetragadolinium hexanickel icosatresaluminium, Gd4Ni6Al23 with Y4Ni6Al23 type
  31. Crystal structure of europium dirhodium digermanium, EuRh2Ge2 with ThCr2Si2 type
  32. Crystal structure of ytterbium rhodium germanium, YbRhGe with TiNiSi type
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 7.12.2025 from https://www.degruyterbrill.com/document/doi/10.1524/zkri.1992.198.1-2.67/html
Scroll to top button