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Crystal structure and bonding of bis-(1H-indole-3-ethylene-3′-methoxy-salicylaldimine)copper(II) monohydrate

Published/Copyright: August 25, 2010
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Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 198 Issue 1-2

Abstract

The molecular and crystal structure of the compound Bis-[1H-indole-3-ethylene-3′-methoxy-salicylaldimine]copper(II) monohydrate has been determined. This compound crystallizes in the monoclinic system, C2/c space group, Z = 4, cell dimensions a = 18.657(2), b = 7.194(1), c = 23.932(1) Å, β = 91.92(2)°, V = 3210(1) Å3, Dx = 1.41 Mg/m3, F(000) = 1396. The structure has been refined to R = 0.043 and wR = 0.045 for 3643 independent observed reflections. The structure consists of one molecule of [C18H17N2O2]2Cu and a water molecule not-coordinated to metal. The geometry around the copper atom is planar with the metal lying on a centre of symmetry. The water molecule plays an important role in the formation of inter molecular hydrogen bonding (OW … N(2) 2.900(9) and OW … O(21) (−x + 1, −y, −z) 2.848(3) Å).

Published Online: 2010-08-25
Published in Print: 1992

Articles in the same Issue

  1. Zur kristallchemischen Einordnung von NaSbCl6, NaNbCl6 und NaTaCl6
  2. The symmetry operations for n-dimensional periodic and quasi-periodic structures *
  3. Crystal growth, crystal structure, optical, electro-optic and electrostrictive properties of the complex silver thiocyanates Cs3Sr[Ag2(SCN)7] and Cs3Ba[Ag2(SCN)7]
  4. Beiträge zum thermischen Verhalten wasserfreier Phosphate
  5. Reaction of heptamethyldisilazane with oxo ligands. Crystal structure of Re(NMe)Cl3(PPh3)2 · 0.5 C7H8 and ReO(OSiMe3)Cl2py2
  6. Crystal structure and bonding of bis-(1H-indole-3-ethylene-3′-methoxy-salicylaldimine)copper(II) monohydrate
  7. The superstructure of K3HGe7O16 · 4H2O
  8. The crystal structure of (Mg,Ga)8(Ga,Ge)2O12
  9. On the density of the p31m packing of ellipses
  10. Verfeinerung der Kristallstrukturen von Ta5As4 und monoklinem Nb4.7Te4
  11. Neutron diffraction analysis of positional oxygen and hydrogen disorder in Ba[Fe(CN)5NO] · 3H2O
  12. Crystal structure of hexacarbonyl tungsten, W(CO)6
  13. Crystal structure of indium antimony trisulfide, InSbS3
  14. Crystal structure of N-(2-hydroxyphenyl)-salicylaldiminato-ammine-nickel, NH3NiO(C6H4)CHN(C6H4)O
  15. Crystal structure of methylamin-(N,N′-1,3-propyldisalicylaldiminato)-Ni(II)-bis(N-methylsalicylaldiminato)-Ni(II), CH3NH2O(C6H4)CHNCH2CH2CH2NCH(C6H4)ONi2O(C6H4)CHNCH3O(C6H4)CHNCH3
  16. Crystal structure of N-(2-hydroxyphenyl)salicylaldiminato-diethylamine-nickel, (CH3CH2)2NHNiO(C6H4)NCH(C6H4)O
  17. Crystal structure of N-benzylsalicylaldimine, OH(C6H4)CHNCH2(C6H5)
  18. Crystal structure of benzhydrazide, NH2NHCO(C6H5)
  19. Crystal structure of triphenylphosphine(O-ethyldithiocarbonato)gold(I), (C6H5)3PAu(S2COC2H5)
  20. Crystal structure of (Z)-1-methoxycarbonyl-2-phenyl-1-phthalimidocyclopropane, C19H15NO4
  21. Crystal structure of meso-bis(1,4-dimethylpiperazine-2,5-dione-3-yl), C12H18N4O4
  22. Crystal structure of dichloro(N-methyl-2,2′-bipyridylium)platinum(II), C11H10Cl2N2Pt
  23. Crystal structure of [3′R*, IR*, 4S*, 6S*]-1-(3′-hydroxybut-1′-ynyl)-2,2,6-trimethylcyclohexane-1,4-diol, C13H22O3
  24. Crystal structure of methyl-2-phthalimido-3-methylbut-2-enoate, C14H13N1O4
  25. Crystal structure of chloro(η-cyclopentadienyl)bis(triphenylphosphine)ruthenium, C42H37Cl3P2Ru
  26. Crystal structure of 7H+,16H+-1,4,10,13-tetrathia-7,16-diazacyclooctadecane bis(tetraphenylboronate), (C12H28N2S4)((C6H5)4B)2
  27. Crystal structure of cobalt sulfanilate tetrahydrate, (Co(NH2C6H4SO3)2)(H2O)4
  28. Crystal structure of zinc sulfanilate tetrahydrate, (Zn(NH2C6H4SO3)2)(H2O)4
  29. Crystal structure of hexaaquamagnesium sulfanilate, (Mg(NH2C6H4SO3)2)(H2O)6
  30. Crystal structure of tetragadolinium hexanickel icosatresaluminium, Gd4Ni6Al23 with Y4Ni6Al23 type
  31. Crystal structure of europium dirhodium digermanium, EuRh2Ge2 with ThCr2Si2 type
  32. Crystal structure of ytterbium rhodium germanium, YbRhGe with TiNiSi type
https://doi.org/10.1524/zkri.1992.198.1-2.61

Articles in the same Issue

  1. Zur kristallchemischen Einordnung von NaSbCl6, NaNbCl6 und NaTaCl6
  2. The symmetry operations for n-dimensional periodic and quasi-periodic structures *
  3. Crystal growth, crystal structure, optical, electro-optic and electrostrictive properties of the complex silver thiocyanates Cs3Sr[Ag2(SCN)7] and Cs3Ba[Ag2(SCN)7]
  4. Beiträge zum thermischen Verhalten wasserfreier Phosphate
  5. Reaction of heptamethyldisilazane with oxo ligands. Crystal structure of Re(NMe)Cl3(PPh3)2 · 0.5 C7H8 and ReO(OSiMe3)Cl2py2
  6. Crystal structure and bonding of bis-(1H-indole-3-ethylene-3′-methoxy-salicylaldimine)copper(II) monohydrate
  7. The superstructure of K3HGe7O16 · 4H2O
  8. The crystal structure of (Mg,Ga)8(Ga,Ge)2O12
  9. On the density of the p31m packing of ellipses
  10. Verfeinerung der Kristallstrukturen von Ta5As4 und monoklinem Nb4.7Te4
  11. Neutron diffraction analysis of positional oxygen and hydrogen disorder in Ba[Fe(CN)5NO] · 3H2O
  12. Crystal structure of hexacarbonyl tungsten, W(CO)6
  13. Crystal structure of indium antimony trisulfide, InSbS3
  14. Crystal structure of N-(2-hydroxyphenyl)-salicylaldiminato-ammine-nickel, NH3NiO(C6H4)CHN(C6H4)O
  15. Crystal structure of methylamin-(N,N′-1,3-propyldisalicylaldiminato)-Ni(II)-bis(N-methylsalicylaldiminato)-Ni(II), CH3NH2O(C6H4)CHNCH2CH2CH2NCH(C6H4)ONi2O(C6H4)CHNCH3O(C6H4)CHNCH3
  16. Crystal structure of N-(2-hydroxyphenyl)salicylaldiminato-diethylamine-nickel, (CH3CH2)2NHNiO(C6H4)NCH(C6H4)O
  17. Crystal structure of N-benzylsalicylaldimine, OH(C6H4)CHNCH2(C6H5)
  18. Crystal structure of benzhydrazide, NH2NHCO(C6H5)
  19. Crystal structure of triphenylphosphine(O-ethyldithiocarbonato)gold(I), (C6H5)3PAu(S2COC2H5)
  20. Crystal structure of (Z)-1-methoxycarbonyl-2-phenyl-1-phthalimidocyclopropane, C19H15NO4
  21. Crystal structure of meso-bis(1,4-dimethylpiperazine-2,5-dione-3-yl), C12H18N4O4
  22. Crystal structure of dichloro(N-methyl-2,2′-bipyridylium)platinum(II), C11H10Cl2N2Pt
  23. Crystal structure of [3′R*, IR*, 4S*, 6S*]-1-(3′-hydroxybut-1′-ynyl)-2,2,6-trimethylcyclohexane-1,4-diol, C13H22O3
  24. Crystal structure of methyl-2-phthalimido-3-methylbut-2-enoate, C14H13N1O4
  25. Crystal structure of chloro(η-cyclopentadienyl)bis(triphenylphosphine)ruthenium, C42H37Cl3P2Ru
  26. Crystal structure of 7H+,16H+-1,4,10,13-tetrathia-7,16-diazacyclooctadecane bis(tetraphenylboronate), (C12H28N2S4)((C6H5)4B)2
  27. Crystal structure of cobalt sulfanilate tetrahydrate, (Co(NH2C6H4SO3)2)(H2O)4
  28. Crystal structure of zinc sulfanilate tetrahydrate, (Zn(NH2C6H4SO3)2)(H2O)4
  29. Crystal structure of hexaaquamagnesium sulfanilate, (Mg(NH2C6H4SO3)2)(H2O)6
  30. Crystal structure of tetragadolinium hexanickel icosatresaluminium, Gd4Ni6Al23 with Y4Ni6Al23 type
  31. Crystal structure of europium dirhodium digermanium, EuRh2Ge2 with ThCr2Si2 type
  32. Crystal structure of ytterbium rhodium germanium, YbRhGe with TiNiSi type
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