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Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
Published/Copyright:
August 25, 2010
Abstract
Both, calcium azide and strontium azide, can incorporate dimethyl sulfoxide to form crystals of the composition given in the title. The lattice constants of the isotypic calcium-(strontium-)-compounds are: a = 8.801 (8.978), b = 13.362 (13.511), c = 10.862 (11.347) Å, space group Cmca, Z = 4. The crystal structures were investigated by X-ray single crystal techniques, R = 0.055 (0.060). Calcium (strontium) is octahedrally surrounded by four azide ions and two oxygen atoms of the solvated DMSO. The octahedra are connected through four azide groups to form layers. The DMSO molecules are located between these layers, and they are highly disordered.
Published Online: 2010-8-25
Published in Print: 1986-2-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Crystal structure refinement of K2HfF6
- High-temperature transformation of tridymite single crystals to cristobalite*
- Crystal structure of potassium pentafluorozirconate monohydrate, KZrF5 · H2O
- The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
- Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
- The crystal structure of U2NiC3
- The crystal structure of Zr3AlN
- Crystal structure of tris (glycine) calcium(II) dichloride
- Einführung in eine anorganische Strukturchemie
- The crystal structure refinement of a natural mordenite
- Characterization of lattice defects by means of a double crystal diffractometer
- Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
- The crystal structures of Na2TiF6 and Na2SiF6
- The crystal structure of ethyl 5-methyl-l,2,3-triazino [5,4-b]-indole 4-carboxylate N(3)-oxide
- Die Kristallstruktur der orientierungsfehlgeordneten kubischen Hochtemperaturphase des Silberperchlorats AgClO4
- The shortest known interpolyhedral O – O distance in a silicate
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