Einführung in eine anorganische Strukturchemie
Abstract
A systematic description and classification of inorganic structure types is proposed on the basis of homogeneous or heterogeneous point configurations (Bauverbände) described by invariant lattice complexes and coordination polyhedra; subscripts or matrices explain the transformation of the complexes in respect (M) to their standard setting; the value of the determinant of the transformation matrix defines the order of the complex. The Bauverbände (frameworks) may be described by three-dimensional networks or two-dimensional nets explicitely shown with structures types of the I- and F-family. Examples of structure types of different orders are listed for the homogeneous or pseudohomogeneous I-, P-, F-, Y**-, S-, +Y-, Q- and C-families and for the heterogeneous [I + W]-, [D + T]- and [Y(31) + Dx]-families. Homeotypic are those structure types, which replace their points of the configurations by polyhedra like dumb-bell (21), triangle (31), tetrahedron (4t), octahedron (6o), cuboctahedron (12co), icosahedron (12i) etc. forming the I[polyhedra]- P[polyhedra]- etc. families. Furthermore, layer descriptions are applied with two-dimensional nets of H, G, N, N[43243] and N[6434] with different stacking sequences and in combination with other nets. The system is proposed after the study of the cubic inorganic structure types and the structures of intermetallic compounds with tetragonal symmetry.
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Artikel in diesem Heft
- Crystal structure refinement of K2HfF6
- High-temperature transformation of tridymite single crystals to cristobalite*
- Crystal structure of potassium pentafluorozirconate monohydrate, KZrF5 · H2O
- The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
- Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
- The crystal structure of U2NiC3
- The crystal structure of Zr3AlN
- Crystal structure of tris (glycine) calcium(II) dichloride
- Einführung in eine anorganische Strukturchemie
- The crystal structure refinement of a natural mordenite
- Characterization of lattice defects by means of a double crystal diffractometer
- Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
- The crystal structures of Na2TiF6 and Na2SiF6
- The crystal structure of ethyl 5-methyl-l,2,3-triazino [5,4-b]-indole 4-carboxylate N(3)-oxide
- Die Kristallstruktur der orientierungsfehlgeordneten kubischen Hochtemperaturphase des Silberperchlorats AgClO4
- The shortest known interpolyhedral O – O distance in a silicate
- Crystal structure and optical lattice vibrations of SbSBr crystals
Artikel in diesem Heft
- Crystal structure refinement of K2HfF6
- High-temperature transformation of tridymite single crystals to cristobalite*
- Crystal structure of potassium pentafluorozirconate monohydrate, KZrF5 · H2O
- The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
- Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
- The crystal structure of U2NiC3
- The crystal structure of Zr3AlN
- Crystal structure of tris (glycine) calcium(II) dichloride
- Einführung in eine anorganische Strukturchemie
- The crystal structure refinement of a natural mordenite
- Characterization of lattice defects by means of a double crystal diffractometer
- Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
- The crystal structures of Na2TiF6 and Na2SiF6
- The crystal structure of ethyl 5-methyl-l,2,3-triazino [5,4-b]-indole 4-carboxylate N(3)-oxide
- Die Kristallstruktur der orientierungsfehlgeordneten kubischen Hochtemperaturphase des Silberperchlorats AgClO4
- The shortest known interpolyhedral O – O distance in a silicate
- Crystal structure and optical lattice vibrations of SbSBr crystals