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Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
Veröffentlicht/Copyright:
25. August 2010
Abstract
Mr = 460.36, monoclinic. P21/c, a = 13.718(1), b = 11.090(1), c = 14.985(1) Å, β = 98.162(2)°, V = 2256.67(9) Å3, Z = 4, Dx = 1.355 Mgm−3, μ = 0.933 mm−1, F(000) = 968, room temperature, final R = 0.047 (Rw = 0.048) for 3184 [I ⩾ 3 σ(I)] observed reflections. The title compound has the “three-legged piano stool” geometry, i.e. the coordination geometry of the iron can be regarded as a distorted octahedron with aη5 – C5Me5 group occupying three coordination sites. Like its nonmethylated analogue it contains an unusually monodentate dithiophosphate ester ligand.
Published Online: 2010-8-25
Published in Print: 1986-2-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Artikel in diesem Heft
- Crystal structure refinement of K2HfF6
- High-temperature transformation of tridymite single crystals to cristobalite*
- Crystal structure of potassium pentafluorozirconate monohydrate, KZrF5 · H2O
- The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
- Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
- The crystal structure of U2NiC3
- The crystal structure of Zr3AlN
- Crystal structure of tris (glycine) calcium(II) dichloride
- Einführung in eine anorganische Strukturchemie
- The crystal structure refinement of a natural mordenite
- Characterization of lattice defects by means of a double crystal diffractometer
- Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
- The crystal structures of Na2TiF6 and Na2SiF6
- The crystal structure of ethyl 5-methyl-l,2,3-triazino [5,4-b]-indole 4-carboxylate N(3)-oxide
- Die Kristallstruktur der orientierungsfehlgeordneten kubischen Hochtemperaturphase des Silberperchlorats AgClO4
- The shortest known interpolyhedral O – O distance in a silicate
- Crystal structure and optical lattice vibrations of SbSBr crystals
Artikel in diesem Heft
- Crystal structure refinement of K2HfF6
- High-temperature transformation of tridymite single crystals to cristobalite*
- Crystal structure of potassium pentafluorozirconate monohydrate, KZrF5 · H2O
- The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
- Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
- The crystal structure of U2NiC3
- The crystal structure of Zr3AlN
- Crystal structure of tris (glycine) calcium(II) dichloride
- Einführung in eine anorganische Strukturchemie
- The crystal structure refinement of a natural mordenite
- Characterization of lattice defects by means of a double crystal diffractometer
- Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
- The crystal structures of Na2TiF6 and Na2SiF6
- The crystal structure of ethyl 5-methyl-l,2,3-triazino [5,4-b]-indole 4-carboxylate N(3)-oxide
- Die Kristallstruktur der orientierungsfehlgeordneten kubischen Hochtemperaturphase des Silberperchlorats AgClO4
- The shortest known interpolyhedral O – O distance in a silicate
- Crystal structure and optical lattice vibrations of SbSBr crystals
