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Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets

Published/Copyright: August 25, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 175 Issue 1-2

Abstract

Insertion of a 2-connected vertex into alternate edges of a 2D net leads to a new family of 3D nets. The simplest operation is conversion of 2-connected vertices of adjacent parallel 2D nets into a square-planar vertex. Relative rotation of tetrahedral vertices above and below each square-planar vertex converts it into a tetrahedral vertex. The simpler nets of each type are enumerated for the 63, 3.122, 4.82 and 4.6.12 2D nets; these nets have higher symmetry and less geometrical distortion than the infinity of nets which are not listed. A further set of nets is obtained by applying a sigma transformation in the plane of each original 2D net. The structures of the beryl and milarite groups of minerals are based on 3D nets obtained from the 63 net, and that of steacyite from the 4.82 net.

Published Online: 2010-8-25
Published in Print: 1986-1-1

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Articles in the same Issue

  1. New family of silicate phases with the pollucite structure
  2. The crystal structure of cis-3-hydroxy-4a,9,10,10a-tetrahydro-1,4a-ethanophenanthren-2(1H)-one (2-one phenanthrene)
  3. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets
  4. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on double-bifurcated chains and the 4.82 and 4.6.12 3-connected plane nets
  5. Formation of the high temperature phase in vacuum deposited SnSe thin films
  6. Correlation of angular and bond length distortions in TO4 units in crystals
  7. Die Kristallstrukturen von drei Modifikationen des Cu(SeO3)
  8. Crystal structures of N-parabromobenzoyl-α-aminoisobutyric acid and two derivatives
  9. Crystal and molecular structures of N2-dimethylthiosalicylohydrazide, (C6H4)CSNHOHN(CH3)2
  10. Studies on clathrasils. IX*
  11. Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3
  12. Crystal structure of barium nitrite, Ba(NO2)2
  13. Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
  14. Structure of a high-pressure phase Ba9Ge23O53(OH)4
  15. The molecular structure of trans 3,6-dimethyl-6-phenyltetrahydro-2-pyrone in the crystal
  16. Crystal structure of W-type SrZn2Fe16O27, a refinement
  17. Structure of thallium(I) dideuteriumphosphate, TlD2PO4
  18. Crystal structure of bis(3,5-dimethyl-l-guanyl pyrazole) copper(II) nitrate
  19. Crystal growth and physical properties of monoclinic betaine fluoroborate monohydrate, (CH3)3NCH2COO HBF4 · H2O
https://doi.org/10.1524/zkri.1986.175.1-2.15

Articles in the same Issue

  1. New family of silicate phases with the pollucite structure
  2. The crystal structure of cis-3-hydroxy-4a,9,10,10a-tetrahydro-1,4a-ethanophenanthren-2(1H)-one (2-one phenanthrene)
  3. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets
  4. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on double-bifurcated chains and the 4.82 and 4.6.12 3-connected plane nets
  5. Formation of the high temperature phase in vacuum deposited SnSe thin films
  6. Correlation of angular and bond length distortions in TO4 units in crystals
  7. Die Kristallstrukturen von drei Modifikationen des Cu(SeO3)
  8. Crystal structures of N-parabromobenzoyl-α-aminoisobutyric acid and two derivatives
  9. Crystal and molecular structures of N2-dimethylthiosalicylohydrazide, (C6H4)CSNHOHN(CH3)2
  10. Studies on clathrasils. IX*
  11. Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3
  12. Crystal structure of barium nitrite, Ba(NO2)2
  13. Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
  14. Structure of a high-pressure phase Ba9Ge23O53(OH)4
  15. The molecular structure of trans 3,6-dimethyl-6-phenyltetrahydro-2-pyrone in the crystal
  16. Crystal structure of W-type SrZn2Fe16O27, a refinement
  17. Structure of thallium(I) dideuteriumphosphate, TlD2PO4
  18. Crystal structure of bis(3,5-dimethyl-l-guanyl pyrazole) copper(II) nitrate
  19. Crystal growth and physical properties of monoclinic betaine fluoroborate monohydrate, (CH3)3NCH2COO HBF4 · H2O
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