The crystal structure of aceto-acetanilide azo-pigments VI. C.I. Pigment Yellow 4, α-(1-hydroxyethylidene) acetanilide-α-azo-(4′-nitrobenzene)
Abstract
The crystal structure of C.I. Pigment Yellow 4, α-(1-hydroxyethylidene) acetanilide-α-azo-(4′nitrobenzene), C16H14O4N4, has been determined by single crystal X-ray diffraction techniques. It crystallises in the triclinic system with cell parameters a = 7.691(2) Å, b = 10.247(2) Å, c = 11.195(2) Å, α = 109.00(2)°, β = 73.80(2)°, γ = 112.21(2)°. The space group is P[unk] and there are two molecules per unit cell. The structure was solved by direct methods and least-squares refinement has been completed on three-dimensional data, 2716 reflections (CuKα radiation). The hydrogen atoms have been found and included in the refinement but only those associated with the methyl group have been independently refined. The final residual is 5.4%. The molecule exists as the hydrazone tautomer. It is approximately planar due partly to intramolecular hydrogen bonds and partly due to steric hinderence. The molecules are packed in layers parallel to the ([unk]11) plane with the length parallel to [011] and in columns approximately parallel to a*. Alternate molecules within the columns are in antiparallel. The molecules are linked by van der Waals forces.
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Articles in the same Issue
- KLiO:Ein Oxid mit dreifach koordiniertem Lithium
- The crystal structure of aceto-acetanilide azo-pigments VI. C.I. Pigment Yellow 4, α-(1-hydroxyethylidene) acetanilide-α-azo-(4′-nitrobenzene)
- The crystal structure of aceto-acetanilide azo-pigments VII. A polymorph (α) of C.I. Pigment Yellow 5, α-(1-hydroxyethylidene) acetanilide-α-azo-(2′-nitrobenzene)
- The Cu2Sb and related structures
- The modulated structure of niobium tetratelluride NbTe4
- Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on the 4.6.12 and (4.6.10)4 (6.6.10): 2D nets
- Dehydration and phase transformation in sepiolite
- Elektrostatische Berechnungen an Karbonaten mit aplanaren Karbonatgruppen
- Ein Phenyl-,,azo“-Derivat des Aeetessigsäureanilids mit zwei unterschiedlichen Konformeren im Kristallverband
- Structure and C–Cl bond in 1-Cl-3-NO2C6H4
- Crystal data on Zn3Rb2(P2O7)2 and Co3Rb2(P2O7)2
- The crystal structure of L(+)-glutamic acid hydroiodide, l-C5H9NO4 · HI
- Bleihalogenide ungewöhnlicher Zusammensetzung und Struktur1: Iodid von Wells K2PbI4/2I2 · 2 H2O · xKI3 · yH2O (x = 0,237, y = 0,37)
- A neutron diffraction study of the bonding of zeolitic water in scolecite at 20 K *
- Structure refinement of Gysinite La0.16Nd1.18Pb0.66(CO3)2(OH)1.34 · 0.66 H2O
Articles in the same Issue
- KLiO:Ein Oxid mit dreifach koordiniertem Lithium
- The crystal structure of aceto-acetanilide azo-pigments VI. C.I. Pigment Yellow 4, α-(1-hydroxyethylidene) acetanilide-α-azo-(4′-nitrobenzene)
- The crystal structure of aceto-acetanilide azo-pigments VII. A polymorph (α) of C.I. Pigment Yellow 5, α-(1-hydroxyethylidene) acetanilide-α-azo-(2′-nitrobenzene)
- The Cu2Sb and related structures
- The modulated structure of niobium tetratelluride NbTe4
- Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on the 4.6.12 and (4.6.10)4 (6.6.10): 2D nets
- Dehydration and phase transformation in sepiolite
- Elektrostatische Berechnungen an Karbonaten mit aplanaren Karbonatgruppen
- Ein Phenyl-,,azo“-Derivat des Aeetessigsäureanilids mit zwei unterschiedlichen Konformeren im Kristallverband
- Structure and C–Cl bond in 1-Cl-3-NO2C6H4
- Crystal data on Zn3Rb2(P2O7)2 and Co3Rb2(P2O7)2
- The crystal structure of L(+)-glutamic acid hydroiodide, l-C5H9NO4 · HI
- Bleihalogenide ungewöhnlicher Zusammensetzung und Struktur1: Iodid von Wells K2PbI4/2I2 · 2 H2O · xKI3 · yH2O (x = 0,237, y = 0,37)
- A neutron diffraction study of the bonding of zeolitic water in scolecite at 20 K *
- Structure refinement of Gysinite La0.16Nd1.18Pb0.66(CO3)2(OH)1.34 · 0.66 H2O
