The crystal structure of synthetic Tl3SbS4
Abstract
The crystal structure of a new synthetic sulfosalt, Tl3SbS4, has been determined. Synthetic Tl3SbS4 crystallizes in the triclinic space group P1 with a = 6.285(1) Å, b = 6.364(1) Å, c = 11.647(1) Å, α = 94.61(1)°, β = 98.51(2)°, γ = 103.93(1)°, Z = 2. The structure was determined by three dimensional Patterson synthesis and refined to a final R-value of 0.07 for all observed reflections.
The six independent Tl atoms in the Tl3SbS4 structure are surrounded by six, seven or eight S atoms in form of an irregular polyhedron. The two Sb atoms are coordinated by four S atoms in form of an almost ideal tetrahedron. The SbS4 tetrahedra are isolated. The structure is built up on a three dimensional network of Tl polyhedra and SbS4 tetrahedra.
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Articles in the same Issue
- X-Ray and neutron diffraction study of alums
- Complex ion centres in heavily doped NaBr: Tl phosphors
- Distortions of octahedra and octahedral sheets in 1 M micas and the relation to their stability
- Structure of 2-hydroxybenzimidazole
- Structural investigations of synthetic fairchildite, K2Ca(CO3)2
- The crystal and molecular structure of [Co(PO4)(NH3)4] · 3 H2O
- The crystal structure of Benzoic Acid: a redetermination with X-rays at room temperature; a summary of neutron-diffraction work at temperatures down to 5 K
- Modulated structure of a plagioclase An52: Theory and structure determination
- Die Kristallstruktur des Dilithium tetrahydroxo-di-μ-peroxodiborats(Lithiumperoxoborats), Li2[B2(O2)2(OH)4]
- Über Wirkungsbereichsteilungen von kubischer Symmetrie II. Die Typen von Wirkungsbereichspolyedern in den symmorphen kubischen Raumgruppen
- Kristallstrukturen komplexer Alkali-Nickel-Azidhydrate
- Röntgentopographische Untersuchungen an CdTe-Einkristallen
- The crystal structure of synthetic Tl3SbS4
